GB837712A - Improvements in or relating to lubricating compositions - Google Patents

Improvements in or relating to lubricating compositions

Info

Publication number
GB837712A
GB837712A GB21603/57A GB2160357A GB837712A GB 837712 A GB837712 A GB 837712A GB 21603/57 A GB21603/57 A GB 21603/57A GB 2160357 A GB2160357 A GB 2160357A GB 837712 A GB837712 A GB 837712A
Authority
GB
United Kingdom
Prior art keywords
benzene hexachloride
alkyl
iii
mineral oil
benzene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB21603/57A
Inventor
George Herbert Thornley
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
CC Wakefield and Co Ltd
Original Assignee
CC Wakefield and Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to DENDAT1068846D priority Critical patent/DE1068846B/en
Application filed by CC Wakefield and Co Ltd filed Critical CC Wakefield and Co Ltd
Priority to GB21603/57A priority patent/GB837712A/en
Publication of GB837712A publication Critical patent/GB837712A/en
Expired legal-status Critical Current

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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M141/00Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential
    • C10M141/08Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential at least one of them being an organic sulfur-, selenium- or tellurium-containing compound
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    • C10M135/00Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing sulfur, selenium or tellurium
    • C10M135/12Thio-acids; Thiocyanates; Derivatives thereof
    • C10M135/14Thio-acids; Thiocyanates; Derivatives thereof having a carbon-to-sulfur double bond
    • C10M135/18Thio-acids; Thiocyanates; Derivatives thereof having a carbon-to-sulfur double bond thiocarbamic type, e.g. containing the groups
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    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10Petroleum or coal fractions, e.g. tars, solvents, bitumen
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    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02Hydroxy compounds
    • C10M2207/023Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
    • C10M2207/026Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings with tertiary alkyl groups
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    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10Carboxylix acids; Neutral salts thereof
    • C10M2207/12Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/121Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms
    • C10M2207/123Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms polycarboxylic
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    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10Carboxylix acids; Neutral salts thereof
    • C10M2207/12Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/129Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of thirty or more carbon atoms
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    • C10M2207/22Acids obtained from polymerised unsaturated acids
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    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28Esters
    • C10M2207/282Esters of (cyclo)aliphatic oolycarboxylic acids
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    • C10M2209/00Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103Polyethers, i.e. containing di- or higher polyoxyalkylene groups
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    • C10M2209/10Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/105Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing three carbon atoms only
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    • C10M2211/00Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions
    • C10M2211/02Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions containing carbon, hydrogen and halogen only
    • C10M2211/024Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions containing carbon, hydrogen and halogen only aromatic
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    • C10M2211/06Perfluorinated compounds
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    • C10M2215/22Heterocyclic nitrogen compounds
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    • C10M2215/22Heterocyclic nitrogen compounds
    • C10M2215/221Six-membered rings containing nitrogen and carbon only
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    • C10M2215/222Triazines
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    • C10M2215/22Heterocyclic nitrogen compounds
    • C10M2215/223Five-membered rings containing nitrogen and carbon only
    • C10M2215/224Imidazoles
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    • C10M2215/226Morpholines
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    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/044Sulfonic acids, Derivatives thereof, e.g. neutral salts
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    • C10M2219/06Thio-acids; Thiocyanates; Derivatives thereof
    • C10M2219/062Thio-acids; Thiocyanates; Derivatives thereof having carbon-to-sulfur double bonds
    • C10M2219/066Thiocarbamic type compounds
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    • C10M2219/08Thiols; Sulfides; Polysulfides; Mercaptals
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    • C10M2219/083Dibenzyl sulfide
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    • C10M2219/088Neutral salts
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    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/08Resistance to extreme temperature
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/02Bearings
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/04Oil-bath; Gear-boxes; Automatic transmissions; Traction drives
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/04Oil-bath; Gear-boxes; Automatic transmissions; Traction drives
    • C10N2040/042Oil-bath; Gear-boxes; Automatic transmissions; Traction drives for automatic transmissions
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/04Oil-bath; Gear-boxes; Automatic transmissions; Traction drives
    • C10N2040/044Oil-bath; Gear-boxes; Automatic transmissions; Traction drives for manual transmissions
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/04Oil-bath; Gear-boxes; Automatic transmissions; Traction drives
    • C10N2040/046Oil-bath; Gear-boxes; Automatic transmissions; Traction drives for traction drives
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/12Gas-turbines
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/12Gas-turbines
    • C10N2040/13Aircraft turbines
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/135Steam engines or turbines
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • C10N2040/22Metal working with essential removal of material, e.g. cutting, grinding or drilling

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Abstract

A lubricating composition comprises a major proportion of lubricating oil incorporating a minor proportion, e.g. up to 10 wt. per cent, of the gamma isomer of benzene hexachloride (hexachlorocyclohexane) substantially free from the other isomers. The gamma isomer is the lowest melting (113 DEG C.) of the isomers formed by the addition of chlorine to benzene in sunlight and constitutes 13% of the crude product. The lubricating oil may be a mineral oil or a synthetic oil such as a dicarboxylic acid diester, e.g. di(2-ethylhexyl) sebacate; a polyoxyalkylene glycol ether; a glycol ester, e.g. diesters of di- or tri-propylene glycol and n-octoic or pelargonic acid; and blends of diesters with water-insoluble polyoxyalkylene glycol ethers. The composition may also include other additives including organic sulphur or selenium compounds, e.g. <FORM:0837712/III/1> where R1 and R2 are alkyl, aryl or cycloalkyl radicals or may together form part of a ring, R is CH2, R4CH or R4CR5, where R4 and R5 are hydrocarbon radicals, R3 is an alkyl, aryl or cycloalkyl radical, and R1, R2 or R3 may contain halogen substituents, as described in Specification 797,316; dibenzyl-, or mono- or di-chloro dibenzyl-disulphide; compounds of the formula ROOC.CH2-(X)n-CH2.COOR, where X is S or Se, n is 2, 3 or 4 and R may be halogen substituted, as described in Specification 714,497; mercaptobenzothiazole, benzothiazole disulphide or hydroxymethyl sulphide; tetraalkylthiuram disulphides; aromatic hydroxy-substituted polysulphides having a carboxyl or ester substituent such as di(3-carbomethoxy-4-hydroxyphenyl) di-, tri- and tetrasulphides, which may also be mixed with some free sulphur, and the corresponding thio-ethers, as described in Specification 561,898; di(hydroxyaryl) thioethers; dibenzothiazines and dibenzoselenazines; and C20+ dialkyl selenides; heterocyclic nitrogen compounds, e.g. imidazole (glyoxaline); benzimidazole; pyrazole; benzotriazole; or indazole: and organic phosphorus compounds, e.g. zinc dialkyl thiolthionophosphates; the neutral phosphate esters described in Specification 757,241 such as <FORM:0837712/III/2> and <FORM:0837712/III/3> or phosphite esters such as <FORM:0837712/III/4> where R1, R2 and R3 are alkyl, aryl, alkaryl or cycloalkyl radicals and R4 is an alkylene or arylene radical; and phosphite esters of hydroxy-substituted aromatic thioethers such as (RO)2-P-O-Ar-S-Ar-O-P-(OR)2 or (RO)m-P-(O-Ar-S-Ar-OH)n where R represents hydrocarbon radicals which may have ether or ester substituents, Ar represents aromatic radicals which may have alkyl, ether or ester substituents, m is 0, 1 or 2 and n is 1, 2 or 3, m + n being 3. Examples include the following compositions: (1) mineral oil, g -benzene hexachloride, alkylated succinic acid and 2,4 - dimethyl - 6 - tertiary butyl phenol; (2) mineral oil, g -benzene hexachloride, alkylated succinic acid, calcium petroleum sulphonate and n - butyl (dimethyldithiocarbamyl) acetate; (3) di (2 - ethyl hexyl) sebacate, phenothiazine and g - benzene hexachloride; and (4) (a grease) mineral oil, lithium stearate and g -benzene hexachloride. Examples are also given contrasting the effectiveness of the g -isomer of benzene hexachloride with each of the other isomers and a commercial mixture of them all. The compositions disclosed in Specification 738,665 are disclaimed.
GB21603/57A 1957-07-08 1957-07-08 Improvements in or relating to lubricating compositions Expired GB837712A (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
DENDAT1068846D DE1068846B (en) 1957-07-08 lubricant
GB21603/57A GB837712A (en) 1957-07-08 1957-07-08 Improvements in or relating to lubricating compositions

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB21603/57A GB837712A (en) 1957-07-08 1957-07-08 Improvements in or relating to lubricating compositions

Publications (1)

Publication Number Publication Date
GB837712A true GB837712A (en) 1960-06-15

Family

ID=10165695

Family Applications (1)

Application Number Title Priority Date Filing Date
GB21603/57A Expired GB837712A (en) 1957-07-08 1957-07-08 Improvements in or relating to lubricating compositions

Country Status (2)

Country Link
DE (1) DE1068846B (en)
GB (1) GB837712A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1987005622A1 (en) * 1986-03-18 1987-09-24 The Lubrizol Corporation Carbamate additive for low phosphorus or phosphorus free lubricating compositions

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB611152A (en) * 1946-04-23 1948-10-26 Bataafsche Petroleum Anti-mosquito oils

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1987005622A1 (en) * 1986-03-18 1987-09-24 The Lubrizol Corporation Carbamate additive for low phosphorus or phosphorus free lubricating compositions
JPS63502905A (en) * 1986-03-18 1988-10-27 ザ ルブリゾル コ−ポレ−ション Carbamate additives for low or phosphorus-free lubricating compositions
AU599371B2 (en) * 1986-03-18 1990-07-19 Lubrizol Corporation, The Thio carbamate additives in low phosphorus lubricating compositions

Also Published As

Publication number Publication date
DE1068846B (en) 1959-11-12

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