GB836303A - Lubricating oil compositions - Google Patents
Lubricating oil compositionsInfo
- Publication number
- GB836303A GB836303A GB11043/58A GB1104358A GB836303A GB 836303 A GB836303 A GB 836303A GB 11043/58 A GB11043/58 A GB 11043/58A GB 1104358 A GB1104358 A GB 1104358A GB 836303 A GB836303 A GB 836303A
- Authority
- GB
- United Kingdom
- Prior art keywords
- vinyl
- polymerizable
- nitrogen
- esters
- methacrylate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M1/00—Liquid compositions essentially based on mineral lubricating oils or fatty oils; Their use as lubricants
- C10M1/08—Liquid compositions essentially based on mineral lubricating oils or fatty oils; Their use as lubricants with additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
- C08F20/08—Anhydrides
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
- C10M2203/108—Residual fractions, e.g. bright stocks
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/22—Alkylation reaction products with aromatic type compounds, e.g. Friedel-crafts
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/02—Hydroxy compounds
- C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/40—Fatty vegetable or animal oils
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/40—Fatty vegetable or animal oils
- C10M2207/402—Castor oils
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- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/40—Fatty vegetable or animal oils
- C10M2207/404—Fatty vegetable or animal oils obtained from genetically modified species
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/08—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
- C10M2209/084—Acrylate; Methacrylate
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- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
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- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
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- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
- C10M2215/064—Di- and triaryl amines
- C10M2215/065—Phenyl-Naphthyl amines
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- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/26—Amines
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- C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
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- C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2217/02—Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds
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- C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2217/02—Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2217/022—Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to an amino group
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- C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2217/02—Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2217/022—Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to an amino group
- C10M2217/023—Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to an amino group the amino group containing an ester bond
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- C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2217/02—Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2217/024—Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to an amido or imido group
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- C10M2217/02—Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2217/026—Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a nitrile group
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- C10M2217/02—Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2217/028—Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a nitrogen-containing hetero ring
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- C10M2217/04—Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
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- C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2217/06—Macromolecular compounds obtained by functionalisation op polymers with a nitrogen containing compound
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- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
- C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
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- C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
- C10M2219/046—Overbasedsulfonic acid salts
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- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/06—Thio-acids; Thiocyanates; Derivatives thereof
- C10M2219/062—Thio-acids; Thiocyanates; Derivatives thereof having carbon-to-sulfur double bonds
- C10M2219/066—Thiocarbamic type compounds
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- C10M2219/066—Thiocarbamic type compounds
- C10M2219/068—Thiocarbamate metal salts
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- C10M2219/08—Thiols; Sulfides; Polysulfides; Mercaptals
- C10M2219/082—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms
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- C10M2223/04—Phosphate esters
- C10M2223/045—Metal containing thio derivatives
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- C10M2223/061—Metal salts
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- C10M2229/02—Unspecified siloxanes; Silicones
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- C10N2010/00—Metal present as such or in compounds
- C10N2010/04—Groups 2 or 12
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- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/04—Oil-bath; Gear-boxes; Automatic transmissions; Traction drives
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- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/04—Oil-bath; Gear-boxes; Automatic transmissions; Traction drives
- C10N2040/044—Oil-bath; Gear-boxes; Automatic transmissions; Traction drives for manual transmissions
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/04—Oil-bath; Gear-boxes; Automatic transmissions; Traction drives
- C10N2040/046—Oil-bath; Gear-boxes; Automatic transmissions; Traction drives for traction drives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/135—Steam engines or turbines
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Lubricants (AREA)
Abstract
Lubricating oil compositions, suitable as engine oils, turbine oils or gear oils, comprise a major proportion of a lubricating oil and minor proportions of (1) an oil-soluble, nitrogen-containing polymeric compound, which is a copolymer of at least one polymerizable nitrogen free organic compound containing an oleophilic hydrocarbon chain of at least 8 carbon atoms and at least one polymerizable organic compound containing an acyclic basic nitrogen-containing group or containing a heterocyclic group having one or more nitrogen atoms in the ring, and (2) an oil-soluble, aliphatic, cycloaliphatic or aromatic dithiocarbamate of a Group II divalent metal. The lubricating oil may be a mineral oil, which may be blended with fatty oils (e.g. castor oil or lard oil) and/or with synthetic lubricants (e.g. polymerized olefins, copolymers of alkylene glycols and alkylene oxides, or silicone polymers). The compositions may contain additional ingredients such as metal dithiophosphates (e.g. Zn alkyl dithiophosphates), metal sulphonates (e.g. neutral Ca, Ba or Zn petroleum sulphonates), amines (e.g. phenyl-alpha-naphthylamine or octadecylamine), alkyl phenols, viscosity index improvers and pourpoint depressants (e.g. polymeric "Acryloid" esters), condensation products of chlorinated paraffin wax and naphthalene, extreme pressure agents (e.g. esters, amides or amine salts of trichloromethane phosphinic acid) and organic sulphides. The polymerizable nitrogen-free organic compound employed in preparing ingredient (1) of the composition may be a polymerizable ester, ether or acid or mixtures of these, esters of acrylic, substituted acrylic and fumaric acids, and also vinyl esters, being mentioned. The nitrogen-containing compound employed in preparing ingredient (1) may be an amino-substituted olefin, a vinyl pyridine, a vinyl lactam (e.g. a vinyl pyrrolidone or vinyl piperidone), an ester of an amino alcohol with an unsaturated carboxylic acid, an unsaturated ether of an amino alcohol, an amide of an unsaturated carboxylic acid wherein an amino-containing group is carried on the amide nitrogen atom, or a polymerizable unsaturated amine. In preparing ingredient (1), additional polymerizable components may be copolymerized with the compounds of the types specified above. These additional components may be vinyl or allyl esters, unsaturated hydrocarbons, vinyl or allyl ethers, carboxylic acids, alkyl methacrylates, acrylonitrile or methacrylamide. In the examples, mineral lubricating oil compositions are described containing (i) lauryl methacrylate/N-vinyl pyrrolidone copolymer and zinc or cadmium diamyl dithiocarbamate, or (ii) stearyl methacrylate/lauryl methacrylate/methyl methacrylate/2-methyl - 5 - vinyl - pyridine copolymer and zinc diamyl dithiocarbamate. Specification 799,036 is referred to.ALSO:Oil-soluble nitrogen-containing polymeric compounds, which are copolymers of (a) at least one polymerizable nitrogen-free organic compound containing an oleophilic hydrocarbon chain of at least 8 carbon atoms and (b) at least one polymerizable organic compound containing an acyclic basic nitrogen-containing group or containing a heterocyclic group having one or more nitrogen atoms in the ring, and optionally (c) other polymerizable components, are employed as lubricating oil additives (see Group III). Compound (a) may be a polymerizable ester, ether or acid or mixtures of these, esters of acrylic, substituted acrylic and fumaric acids, and also vinyl esters, being mentioned. Compound (b) may be an amino-substituted olefin, a vinyl pyridine, a vinyl lactam (e.g. a vinyl pyrrolidone or vinyl piperidone), an ester of an aminoalcohol with an unsaturated carboxylic acid, an unsaturated ether of an aminoalcohol, an amide of an unsaturated carboxylic acid wherein an amino-containing group is carried on the amide nitrogen atom, or a polymerizable unsaturated amine. Components (c) mentioned are vinyl or allyl esters, unsaturated hydrocarbons (including dienes), vinyl or allyl ethers, carboxylic acids, alkyl methacrylates, acrylonitrile, and methacrylamide. In the examples, the preparation is described of stearyl or lauryl methacrylate/2-methyl-5-vinyl pyridine; lauryl methacrylate / N - vinyl pyrrolidone; stearyl methacrylate/lauryl methacrylate/methyl methacrylate/2 - methyl - 5 - vinyl pyridine; stearyl methacrylate / lauryl methacrylate / N-vinyl pyrrolidone; lauryl methacrylate/2-methyl-5-vinyl pyridine/styrene; and lauryl methacrylate / methacrylanilide / beta - diethylaminoethyl methacrylate copolymers. Specification 799,036 is referred to.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US651598A US3030303A (en) | 1957-04-09 | 1957-04-09 | Lubricating oil composition |
Publications (1)
Publication Number | Publication Date |
---|---|
GB836303A true GB836303A (en) | 1960-06-01 |
Family
ID=24613480
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB11043/58A Expired GB836303A (en) | 1957-04-09 | 1958-04-08 | Lubricating oil compositions |
Country Status (6)
Country | Link |
---|---|
US (1) | US3030303A (en) |
BE (1) | BE566592A (en) |
DE (1) | DE1063312B (en) |
FR (1) | FR1206669A (en) |
GB (1) | GB836303A (en) |
NL (2) | NL105971C (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3336225A (en) * | 1966-01-17 | 1967-08-15 | Dow Chemical Co | Method and composition for reducing friction on conveyors |
Families Citing this family (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3172856A (en) * | 1965-03-09 | Copolymers of n-alkyl piperazine acry- late and alkyl acrylate and lubricat- ing oils containing them | ||
US3206403A (en) * | 1965-09-14 | Distillate and raffinate | ||
NL251968A (en) * | 1959-05-28 | |||
DE1094392B (en) * | 1959-08-12 | 1960-12-08 | Roehm & Haas Gmbh | Lubricating oil additives |
BE602261A (en) * | 1960-04-06 | |||
NL263937A (en) * | 1960-04-25 | |||
US3116248A (en) * | 1960-12-23 | 1963-12-31 | Shell Oil Co | Lubricating oil composition |
BE611853A (en) * | 1960-12-23 | |||
US3171779A (en) * | 1961-12-27 | 1965-03-02 | Texaco Inc | Plant composition |
US3215632A (en) * | 1962-06-22 | 1965-11-02 | Shell Oil Co | Lubricating compositions |
US3166507A (en) * | 1962-08-13 | 1965-01-19 | Union Carbide Corp | Lubricating oils containing alkyl acrylate-vinylpyridine n-oxide copolymers |
US3224975A (en) * | 1962-12-03 | 1965-12-21 | Ethyl Corp | Lubricating oil compositions |
US3224968A (en) * | 1962-12-03 | 1965-12-21 | Ethyl Corp | Lubricating oil compositions |
US3265619A (en) * | 1963-05-03 | 1966-08-09 | Shell Oil Co | Heavy duty lubricants |
US3397146A (en) * | 1966-08-22 | 1968-08-13 | Union Carbide Corp | Lubricating compositions |
US3462367A (en) * | 1966-10-31 | 1969-08-19 | Shell Oil Co | Lubricating oils containing an antioxidant mixture of zinc and antimony dialkyl dithiocarbamates |
GB1140179A (en) * | 1967-11-27 | 1969-01-15 | Shell Int Research | Lubricant compositions |
US4181618A (en) * | 1974-12-03 | 1980-01-01 | Institut Francais Du Petrole | Grafted copolymers and their use as additives for lubricating oils |
US4178258A (en) * | 1978-05-18 | 1979-12-11 | Edwin Cooper, Inc. | Lubricating oil composition |
US6210696B1 (en) | 1998-04-27 | 2001-04-03 | Rohm And Haas Company | Stable pesticide dispersions |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2450633A (en) * | 1944-10-31 | 1948-10-05 | California Research Corp | Compounded oil |
US2666044A (en) * | 1951-03-09 | 1954-01-12 | Du Pont | Alkyl acrylate/n-hydrocarbon-substituted acrylamide/unsaturated tertiary amino compound copolymers |
DE947186C (en) * | 1951-03-09 | 1956-08-09 | Du Pont | Additive to lubricating oils and heating oils |
US2737496A (en) * | 1952-02-16 | 1956-03-06 | Du Pont | Lubricating oil compositions containing polymeric additives |
GB770771A (en) * | 1953-05-18 | 1957-03-27 | California Research Corp | Copolymeric dispersants and lubricant compositions containing them |
NL91489C (en) * | 1953-05-25 | |||
BE538017A (en) * | 1954-05-10 | |||
BE545478A (en) * | 1955-02-25 | |||
US2839512A (en) * | 1955-12-30 | 1958-06-17 | Shell Dev | Vinylpyridine long chain acrylic ester copolymers and their preparation |
US2825695A (en) * | 1956-06-15 | 1958-03-04 | Shell Dev | Lubricating compositions |
US2866729A (en) * | 1956-07-27 | 1958-12-30 | Shell Dev | Quenching oil compositions |
US2889282A (en) * | 1956-09-17 | 1959-06-02 | Shell Dev | Lubricating oil compositions |
-
0
- BE BE566592D patent/BE566592A/xx unknown
- NL NL226646D patent/NL226646A/xx unknown
- NL NL105971D patent/NL105971C/xx active
-
1957
- 1957-04-09 US US651598A patent/US3030303A/en not_active Expired - Lifetime
-
1958
- 1958-04-08 GB GB11043/58A patent/GB836303A/en not_active Expired
- 1958-04-08 DE DEN14912A patent/DE1063312B/en active Pending
- 1958-04-09 FR FR1206669D patent/FR1206669A/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3336225A (en) * | 1966-01-17 | 1967-08-15 | Dow Chemical Co | Method and composition for reducing friction on conveyors |
Also Published As
Publication number | Publication date |
---|---|
BE566592A (en) | |
NL105971C (en) | |
DE1063312B (en) | 1959-08-13 |
NL226646A (en) | |
US3030303A (en) | 1962-04-17 |
FR1206669A (en) | 1960-02-11 |
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