GB853535A - Lubricating oil compositions - Google Patents
Lubricating oil compositionsInfo
- Publication number
- GB853535A GB853535A GB37735/58A GB3773558A GB853535A GB 853535 A GB853535 A GB 853535A GB 37735/58 A GB37735/58 A GB 37735/58A GB 3773558 A GB3773558 A GB 3773558A GB 853535 A GB853535 A GB 853535A
- Authority
- GB
- United Kingdom
- Prior art keywords
- unsaturated
- vinyl
- esters
- oil
- alkyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M161/00—Lubricating compositions characterised by the additive being a mixture of a macromolecular compound and a non-macromolecular compound, each of these compounds being essential
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M129/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen
- C10M129/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen having a carbon chain of less than 30 atoms
- C10M129/16—Ethers
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M135/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing sulfur, selenium or tellurium
- C10M135/08—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing sulfur, selenium or tellurium containing a sulfur-to-oxygen bond
- C10M135/10—Sulfonic acids or derivatives thereof
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M137/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing phosphorus
- C10M137/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing phosphorus having no phosphorus-to-carbon bond
- C10M137/04—Phosphate esters
- C10M137/10—Thio derivatives
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M143/00—Lubricating compositions characterised by the additive being a macromolecular hydrocarbon or such hydrocarbon modified by oxidation
- C10M143/08—Lubricating compositions characterised by the additive being a macromolecular hydrocarbon or such hydrocarbon modified by oxidation containing aliphatic monomer having more than 4 carbon atoms
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M145/00—Lubricating compositions characterised by the additive being a macromolecular compound containing oxygen
- C10M145/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C10M145/06—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to an acyloxy radical of a saturated carboxylic or carbonic acid
- C10M145/08—Vinyl esters of a saturated carboxylic or carbonic acid
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- C10M145/00—Lubricating compositions characterised by the additive being a macromolecular compound containing oxygen
- C10M145/18—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M145/20—Condensation polymers of aldehydes or ketones
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- C10M145/00—Lubricating compositions characterised by the additive being a macromolecular compound containing oxygen
- C10M145/18—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M145/24—Polyethers
- C10M145/26—Polyoxyalkylenes
- C10M145/36—Polyoxyalkylenes etherified
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- C10M149/00—Lubricating compositions characterised by the additive being a macromolecular compound containing nitrogen
- C10M149/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
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- C10M159/00—Lubricating compositions characterised by the additive being of unknown or incompletely defined constitution
- C10M159/12—Reaction products
- C10M159/20—Reaction mixtures having an excess of neutralising base, e.g. so-called overbasic or highly basic products
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- C10M159/12—Reaction products
- C10M159/20—Reaction mixtures having an excess of neutralising base, e.g. so-called overbasic or highly basic products
- C10M159/22—Reaction mixtures having an excess of neutralising base, e.g. so-called overbasic or highly basic products containing phenol radicals
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- C10M159/12—Reaction products
- C10M159/20—Reaction mixtures having an excess of neutralising base, e.g. so-called overbasic or highly basic products
- C10M159/24—Reaction mixtures having an excess of neutralising base, e.g. so-called overbasic or highly basic products containing sulfonic radicals
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- C10M167/00—Lubricating compositions characterised by the additive being a mixture of a macromolecular compound, a non-macromolecular compound and a compound of unknown or incompletely defined constitution, each of these compounds being essential
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/087—Boron oxides, acids or salts
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
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- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
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- C10M2205/028—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers containing aliphatic monomers having more than four carbon atoms
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- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/22—Alkylation reaction products with aromatic type compounds, e.g. Friedel-crafts
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- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/02—Hydroxy compounds
- C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
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- C10M2207/027—Neutral salts thereof
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- C10M2207/028—Overbased salts thereof
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- C10M2207/142—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings polycarboxylic
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- Lubricants (AREA)
Abstract
Ingredients of a lubricating composition (see Group III) are (a) an oil-soluble polymeric compound comprising a straight hydrocarbon chain having attached thereto radicals containing an organic nitrogen group and, indirectly through an oxygen-containing radical, alkyl radicals of at least 8 carbon atoms, each of the radicals being attached to a different carbon atom of the hydrocarbon chain and (b) an oilsoluble, water-insoluble, non-ionic polymeric alcohol containing a plurality of non-acidic oxygen-containing radicals and at least one alkyl group of at least 4 carbon atoms in the molecule or a complex of such an alcohol with a polyvalent metal compound. Ingredient (a) may be a copolymer of (1) one or more polymerizable compounds, having an unsaturated portion in the molecule and, attached thereto through an oxygen-containing radical, an alkyl radical having at least 8 carbon atoms (e.g. alkyl esters of acrylic or methacrylic acid, vinyl esters of fatty acids, dialkyl esters of vinylene dicarboxylic acids, N-alkyl-substituted amides of unsaturated acids, or unsaturated ethers), (2) one or more unsaturated nitrogen-containing compounds (e.g. amino-substituted olefins, esters of amino-alcohols with unsaturated carboxylic acids, unsaturated ethers of amino-alcohols, unsaturated amines, amides of unsaturated carboxylic acids, vinyl pyridines, vinyl pyrrolidones and vinyl piperidones) and optionally (3) other unsaturated monomers (e.g. esters of unsaturated alcohols, unsaturated hydrocarbons, unsaturated carboxylic acids or their esters of amides, unsaturated nitriles or unsaturated ethers). Examples of ingredient (a), whose preparation is described, are stearyl methacrylate/lauryl methacrylate/2-methyl-5-vinyl pyridine; lauryl methacrylate/2-methyl-5-vinyl pyridine; stearyl methacrylate/lauryl methacrylate/methyl methacrylate/2-methyl -5-vinyl pyridine; lauryl methacrylate/N-vinyl pyrrolidone; stearyl methacyylate/lauryl methacrylate/N-vinyl pyrrolidone; stearyl methacrylate/N-vinyl piperidone; lauryl methacrylate/methacrylanilide/beta-diethyl -aminoethyl methacrylate; lauryl methacrylate/beta-diethyl-aminoethyl methacrylate; and lauryl methacrylate/N-(4-dimethyl amino cyclohexyl) methacrylamide copolymers. Ingredient (b) may be (i) a copolymer of an alpha-olefin and an unsaturated alcohol (e.g. an alpha-olefin/vinyl ester copolymer whose ester groups have been partially or completely converted to hydroxy groups) or (ii) a complex formed for example by reacting copolymer (i) with an excess of a polyvalent metal oxide, hydroxide or carbonate, preferably in the presence of carbon dioxide. Examples of ingredient (b), whose preparation is described, are alpha-olefin (one or more between C12 and C18) vinyl acetate or butyrate copolymers which have been alcoholysed to convert a large proportion of the ester groups to hydroxyl groups, or the complexes formed by reacting such alcoholysed copolymers with calcium hydroxide and carbon dioxide or boric acid. Specifications 599,729, 743,842, 744,942, 799,036 and 810,685 are referred to.ALSO:A lubricating composition having detergent and wear-inhibiting properties, and suitable for use as an engine oil, turbine oil or gear oil, comprises a major proportion of a lubricating oil and minor proportions of (a) an oil-soluble polymeric compound comprising a straight hydrocarbon chain having attached thereto radicals containing an organic nitrogen group and, indirectly through an oxygencontaining radical, alkyl radicals of at least 8 carbon atoms, each of the radicals being attached to a different carbon atom of the hydrocarbon chain, (b) an oil-soluble polyvalent metal salt and (c) an oil-soluble, waterinsoluble, non-ionic polymeric alcohol containing a plurality of non-acidic oxygen-containing radicals and at least one alkyl group of at least 4 carbon atoms in the molecule or a complex of such an alcohol with a polyvalent metal compound. The lubricating oil may be mineral oil, which may be blended with fixed oils (e.g. castor oil or lard oil) and/or synthetic lubricants (e.g. polymerized olefins, alkylene glycol or alkylene oxide copolymers, or silicone polymers). Ingredient (a) may be a copolymer of (1) one or more polymerizable compounds having an unsaturated portion in the molecule and, attached thereto through an oxygen-containing radical, an alkyl radical having at least 8 carbon atoms (e.g. alkyl esters of acrylic or methacrylic acid, vinyl esters of fatty acids, dialkyl esters of vinylene dicarboxylic acids, N-alkylsubstituted amides of unsaturated acids, or unsaturated ethers), (2) one or more unsaturated nitrogen-containing compounds (e.g. amino-substituted olefins, esters of aminoalcohols with unsaturated carboxylic acids, unsaturated ethers of amino-alcohols, unsaturated amines, amides of unsaturated carboxylic acids, vinyl pyridines, vinyl pyrrolidones and vinyl piperidones) and optionally (3) other unsaturated monomers (e.g. esters of unsaturated alcohols, unsaturated hydrocarbons, unsaturated carboxylic acids or their esters or amides, unsaturated nitriles or unsaturated ethers). Ingredient (b) may be a neutral or basic polyvalent metal salt of a sulphonic acid (e.g. petroleum sulphonic acid), phenol, alkyl phenol/aldehyde condensation product, naphthenic acid or aromatic carboxylic acid (especially an alkylated benzoic or salicylic acid). Ingredient (c) may be (i) a copolymer of an alpha-olefin and an unsaturated alcohol (e.g. an alpha-olefin/vinyl ester copolymer whose ester groups have been partially or completely converted to hydroxyl groups), (ii) a mono(alkylphenyl)ether of a polyglycol or (iii) a complex formed for example by reacting copolymer (i) with an excess of a polyvalent metal oxide, hydroxide or carbonate, preferably in the presence of carbon dioxide. The lubricating composition may contain additional ingredients such as zinc alkyl dithiophosphates, amines (e.g. phenyl alpha naphthylamine or octadecylamine), alkyl phenols, "acryloid" polymers, naphthalene-chlorinated paraffin wax condensates, organic sulphides and amine salts of trichloromethane phosphinic acid. Specifications 599,729, 743,842, 744,942, 799,036 and 810,685 are referred to.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US853535XA | 1957-11-26 | 1957-11-26 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB853535A true GB853535A (en) | 1960-11-09 |
Family
ID=22191045
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB37735/58A Expired GB853535A (en) | 1957-11-26 | 1958-11-24 | Lubricating oil compositions |
Country Status (4)
Country | Link |
---|---|
DE (1) | DE1075254B (en) |
FR (1) | FR1217095A (en) |
GB (1) | GB853535A (en) |
NL (1) | NL104534C (en) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3431062A (en) * | 1964-10-26 | 1969-03-04 | Chevron Res | Antievaporant process and composition |
EP0296674A1 (en) * | 1987-06-25 | 1988-12-28 | Shell Internationale Researchmaatschappij B.V. | Lubricating oil composition |
EP0965680A1 (en) * | 1998-06-18 | 1999-12-22 | Clariant International Ltd. | Aqueous dispersions, their preparation and use thereof |
WO2002062930A2 (en) * | 2001-02-07 | 2002-08-15 | The Lubrizol Corporation | Boron containing lubricating oil composition containing a low level of sulfur and phosphorus |
WO2003022963A1 (en) * | 2001-09-12 | 2003-03-20 | The Lubrizol Corporation | Lubricating oil composition |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0857776B2 (en) * | 1997-01-07 | 2007-05-02 | Clariant Produkte (Deutschland) GmbH | Mineral oil and mineral oil distillate flowability improvement using alkylphenol-aldehyde resins |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE903496C (en) * | 1941-09-20 | 1954-02-08 | Basf Ag | Lubricants that are exposed to high temperatures and / or must have high load capacities |
DE909021C (en) * | 1943-07-07 | 1954-04-12 | Basf Ag | lubricant |
NL66998C (en) * | 1946-08-31 | |||
DE920864C (en) * | 1951-03-07 | 1954-12-02 | Basf Ag | lubricant |
US2666044A (en) * | 1951-03-09 | 1954-01-12 | Du Pont | Alkyl acrylate/n-hydrocarbon-substituted acrylamide/unsaturated tertiary amino compound copolymers |
DE947186C (en) * | 1951-03-09 | 1956-08-09 | Du Pont | Additive to lubricating oils and heating oils |
GB770771A (en) * | 1953-05-18 | 1957-03-27 | California Research Corp | Copolymeric dispersants and lubricant compositions containing them |
NL91489C (en) * | 1953-05-25 | |||
NL92381C (en) * | 1954-05-10 |
-
0
- DE DENDAT1075254D patent/DE1075254B/en active Pending
- NL NL104534D patent/NL104534C/xx active
-
1958
- 1958-11-24 FR FR779897A patent/FR1217095A/en not_active Expired
- 1958-11-24 GB GB37735/58A patent/GB853535A/en not_active Expired
Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3431062A (en) * | 1964-10-26 | 1969-03-04 | Chevron Res | Antievaporant process and composition |
EP0296674A1 (en) * | 1987-06-25 | 1988-12-28 | Shell Internationale Researchmaatschappij B.V. | Lubricating oil composition |
JPS6485293A (en) * | 1987-06-25 | 1989-03-30 | Shell Int Research | Lubricant composition |
US4876020A (en) * | 1987-06-25 | 1989-10-24 | Shell Oil Company | Lubricating oil composition |
EP0965680A1 (en) * | 1998-06-18 | 1999-12-22 | Clariant International Ltd. | Aqueous dispersions, their preparation and use thereof |
WO1999066118A1 (en) * | 1998-06-18 | 1999-12-23 | Clariant Finance (Bvi) Limited | Aqueous dispersions, their production and use |
US6736865B1 (en) * | 1998-06-18 | 2004-05-18 | Clariant Finance (Bvi) Limited | Aqueous dispersions, their production and use |
WO2002062930A2 (en) * | 2001-02-07 | 2002-08-15 | The Lubrizol Corporation | Boron containing lubricating oil composition containing a low level of sulfur and phosphorus |
WO2002062930A3 (en) * | 2001-02-07 | 2003-03-20 | Lubrizol Corp | Boron containing lubricating oil composition containing a low level of sulfur and phosphorus |
US6605572B2 (en) | 2001-02-07 | 2003-08-12 | The Lubrizol Corporation | Lubricating oil composition |
WO2003022963A1 (en) * | 2001-09-12 | 2003-03-20 | The Lubrizol Corporation | Lubricating oil composition |
US6583092B1 (en) | 2001-09-12 | 2003-06-24 | The Lubrizol Corporation | Lubricating oil composition |
Also Published As
Publication number | Publication date |
---|---|
FR1217095A (en) | 1960-05-02 |
NL104534C (en) | |
DE1075254B (en) | 1960-02-11 |
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