GB853535A - Lubricating oil compositions - Google Patents

Lubricating oil compositions

Info

Publication number
GB853535A
GB853535A GB37735/58A GB3773558A GB853535A GB 853535 A GB853535 A GB 853535A GB 37735/58 A GB37735/58 A GB 37735/58A GB 3773558 A GB3773558 A GB 3773558A GB 853535 A GB853535 A GB 853535A
Authority
GB
United Kingdom
Prior art keywords
unsaturated
vinyl
esters
oil
alkyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB37735/58A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bataafsche Petroleum Maatschappij NV
Original Assignee
Bataafsche Petroleum Maatschappij NV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bataafsche Petroleum Maatschappij NV filed Critical Bataafsche Petroleum Maatschappij NV
Publication of GB853535A publication Critical patent/GB853535A/en
Expired legal-status Critical Current

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Classifications

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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M161/00Lubricating compositions characterised by the additive being a mixture of a macromolecular compound and a non-macromolecular compound, each of these compounds being essential
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M129/00Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen
    • C10M129/02Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen having a carbon chain of less than 30 atoms
    • C10M129/16Ethers
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    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M135/00Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing sulfur, selenium or tellurium
    • C10M135/08Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing sulfur, selenium or tellurium containing a sulfur-to-oxygen bond
    • C10M135/10Sulfonic acids or derivatives thereof
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    • C10M137/00Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing phosphorus
    • C10M137/02Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing phosphorus having no phosphorus-to-carbon bond
    • C10M137/04Phosphate esters
    • C10M137/10Thio derivatives
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    • C10M143/00Lubricating compositions characterised by the additive being a macromolecular hydrocarbon or such hydrocarbon modified by oxidation
    • C10M143/08Lubricating compositions characterised by the additive being a macromolecular hydrocarbon or such hydrocarbon modified by oxidation containing aliphatic monomer having more than 4 carbon atoms
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    • C10M145/00Lubricating compositions characterised by the additive being a macromolecular compound containing oxygen
    • C10M145/02Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M145/06Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to an acyloxy radical of a saturated carboxylic or carbonic acid
    • C10M145/08Vinyl esters of a saturated carboxylic or carbonic acid
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    • C10M145/00Lubricating compositions characterised by the additive being a macromolecular compound containing oxygen
    • C10M145/18Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M145/20Condensation polymers of aldehydes or ketones
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    • C10M145/00Lubricating compositions characterised by the additive being a macromolecular compound containing oxygen
    • C10M145/18Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M145/24Polyethers
    • C10M145/26Polyoxyalkylenes
    • C10M145/36Polyoxyalkylenes etherified
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    • C10M149/00Lubricating compositions characterised by the additive being a macromolecular compound containing nitrogen
    • C10M149/02Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
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    • C10M159/00Lubricating compositions characterised by the additive being of unknown or incompletely defined constitution
    • C10M159/12Reaction products
    • C10M159/20Reaction mixtures having an excess of neutralising base, e.g. so-called overbasic or highly basic products
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    • C10M159/12Reaction products
    • C10M159/20Reaction mixtures having an excess of neutralising base, e.g. so-called overbasic or highly basic products
    • C10M159/22Reaction mixtures having an excess of neutralising base, e.g. so-called overbasic or highly basic products containing phenol radicals
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    • C10M159/12Reaction products
    • C10M159/20Reaction mixtures having an excess of neutralising base, e.g. so-called overbasic or highly basic products
    • C10M159/24Reaction mixtures having an excess of neutralising base, e.g. so-called overbasic or highly basic products containing sulfonic radicals
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    • C10M167/00Lubricating compositions characterised by the additive being a mixture of a macromolecular compound, a non-macromolecular compound and a compound of unknown or incompletely defined constitution, each of these compounds being essential
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    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/087Boron oxides, acids or salts
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    • C10M2205/00Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
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    • C10M2205/00Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/02Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
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    • C10M2205/02Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
    • C10M2205/028Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers containing aliphatic monomers having more than four carbon atoms
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    • C10M2205/00Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/22Alkylation reaction products with aromatic type compounds, e.g. Friedel-crafts
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    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02Hydroxy compounds
    • C10M2207/023Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
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    • C10M2207/02Hydroxy compounds
    • C10M2207/023Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
    • C10M2207/027Neutral salts thereof
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    • C10M2207/02Hydroxy compounds
    • C10M2207/023Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
    • C10M2207/028Overbased salts thereof
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    • C10M2207/046Hydroxy ethers
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    • C10M2207/10Carboxylix acids; Neutral salts thereof
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    • C10M2207/141Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings monocarboxylic
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    • C10M2207/142Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings polycarboxylic
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    • C10M2207/146Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings having carboxyl groups bound to carbon atoms of six-membeered aromatic rings having a hydrocarbon substituent of thirty or more carbon atoms
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    • C10M2209/084Acrylate; Methacrylate
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  • Lubricants (AREA)

Abstract

Ingredients of a lubricating composition (see Group III) are (a) an oil-soluble polymeric compound comprising a straight hydrocarbon chain having attached thereto radicals containing an organic nitrogen group and, indirectly through an oxygen-containing radical, alkyl radicals of at least 8 carbon atoms, each of the radicals being attached to a different carbon atom of the hydrocarbon chain and (b) an oilsoluble, water-insoluble, non-ionic polymeric alcohol containing a plurality of non-acidic oxygen-containing radicals and at least one alkyl group of at least 4 carbon atoms in the molecule or a complex of such an alcohol with a polyvalent metal compound. Ingredient (a) may be a copolymer of (1) one or more polymerizable compounds, having an unsaturated portion in the molecule and, attached thereto through an oxygen-containing radical, an alkyl radical having at least 8 carbon atoms (e.g. alkyl esters of acrylic or methacrylic acid, vinyl esters of fatty acids, dialkyl esters of vinylene dicarboxylic acids, N-alkyl-substituted amides of unsaturated acids, or unsaturated ethers), (2) one or more unsaturated nitrogen-containing compounds (e.g. amino-substituted olefins, esters of amino-alcohols with unsaturated carboxylic acids, unsaturated ethers of amino-alcohols, unsaturated amines, amides of unsaturated carboxylic acids, vinyl pyridines, vinyl pyrrolidones and vinyl piperidones) and optionally (3) other unsaturated monomers (e.g. esters of unsaturated alcohols, unsaturated hydrocarbons, unsaturated carboxylic acids or their esters of amides, unsaturated nitriles or unsaturated ethers). Examples of ingredient (a), whose preparation is described, are stearyl methacrylate/lauryl methacrylate/2-methyl-5-vinyl pyridine; lauryl methacrylate/2-methyl-5-vinyl pyridine; stearyl methacrylate/lauryl methacrylate/methyl methacrylate/2-methyl -5-vinyl pyridine; lauryl methacrylate/N-vinyl pyrrolidone; stearyl methacyylate/lauryl methacrylate/N-vinyl pyrrolidone; stearyl methacrylate/N-vinyl piperidone; lauryl methacrylate/methacrylanilide/beta-diethyl -aminoethyl methacrylate; lauryl methacrylate/beta-diethyl-aminoethyl methacrylate; and lauryl methacrylate/N-(4-dimethyl amino cyclohexyl) methacrylamide copolymers. Ingredient (b) may be (i) a copolymer of an alpha-olefin and an unsaturated alcohol (e.g. an alpha-olefin/vinyl ester copolymer whose ester groups have been partially or completely converted to hydroxy groups) or (ii) a complex formed for example by reacting copolymer (i) with an excess of a polyvalent metal oxide, hydroxide or carbonate, preferably in the presence of carbon dioxide. Examples of ingredient (b), whose preparation is described, are alpha-olefin (one or more between C12 and C18) vinyl acetate or butyrate copolymers which have been alcoholysed to convert a large proportion of the ester groups to hydroxyl groups, or the complexes formed by reacting such alcoholysed copolymers with calcium hydroxide and carbon dioxide or boric acid. Specifications 599,729, 743,842, 744,942, 799,036 and 810,685 are referred to.ALSO:A lubricating composition having detergent and wear-inhibiting properties, and suitable for use as an engine oil, turbine oil or gear oil, comprises a major proportion of a lubricating oil and minor proportions of (a) an oil-soluble polymeric compound comprising a straight hydrocarbon chain having attached thereto radicals containing an organic nitrogen group and, indirectly through an oxygencontaining radical, alkyl radicals of at least 8 carbon atoms, each of the radicals being attached to a different carbon atom of the hydrocarbon chain, (b) an oil-soluble polyvalent metal salt and (c) an oil-soluble, waterinsoluble, non-ionic polymeric alcohol containing a plurality of non-acidic oxygen-containing radicals and at least one alkyl group of at least 4 carbon atoms in the molecule or a complex of such an alcohol with a polyvalent metal compound. The lubricating oil may be mineral oil, which may be blended with fixed oils (e.g. castor oil or lard oil) and/or synthetic lubricants (e.g. polymerized olefins, alkylene glycol or alkylene oxide copolymers, or silicone polymers). Ingredient (a) may be a copolymer of (1) one or more polymerizable compounds having an unsaturated portion in the molecule and, attached thereto through an oxygen-containing radical, an alkyl radical having at least 8 carbon atoms (e.g. alkyl esters of acrylic or methacrylic acid, vinyl esters of fatty acids, dialkyl esters of vinylene dicarboxylic acids, N-alkylsubstituted amides of unsaturated acids, or unsaturated ethers), (2) one or more unsaturated nitrogen-containing compounds (e.g. amino-substituted olefins, esters of aminoalcohols with unsaturated carboxylic acids, unsaturated ethers of amino-alcohols, unsaturated amines, amides of unsaturated carboxylic acids, vinyl pyridines, vinyl pyrrolidones and vinyl piperidones) and optionally (3) other unsaturated monomers (e.g. esters of unsaturated alcohols, unsaturated hydrocarbons, unsaturated carboxylic acids or their esters or amides, unsaturated nitriles or unsaturated ethers). Ingredient (b) may be a neutral or basic polyvalent metal salt of a sulphonic acid (e.g. petroleum sulphonic acid), phenol, alkyl phenol/aldehyde condensation product, naphthenic acid or aromatic carboxylic acid (especially an alkylated benzoic or salicylic acid). Ingredient (c) may be (i) a copolymer of an alpha-olefin and an unsaturated alcohol (e.g. an alpha-olefin/vinyl ester copolymer whose ester groups have been partially or completely converted to hydroxyl groups), (ii) a mono(alkylphenyl)ether of a polyglycol or (iii) a complex formed for example by reacting copolymer (i) with an excess of a polyvalent metal oxide, hydroxide or carbonate, preferably in the presence of carbon dioxide. The lubricating composition may contain additional ingredients such as zinc alkyl dithiophosphates, amines (e.g. phenyl alpha naphthylamine or octadecylamine), alkyl phenols, "acryloid" polymers, naphthalene-chlorinated paraffin wax condensates, organic sulphides and amine salts of trichloromethane phosphinic acid. Specifications 599,729, 743,842, 744,942, 799,036 and 810,685 are referred to.
GB37735/58A 1957-11-26 1958-11-24 Lubricating oil compositions Expired GB853535A (en)

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GB853535A true GB853535A (en) 1960-11-09

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DE (1) DE1075254B (en)
FR (1) FR1217095A (en)
GB (1) GB853535A (en)
NL (1) NL104534C (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3431062A (en) * 1964-10-26 1969-03-04 Chevron Res Antievaporant process and composition
EP0296674A1 (en) * 1987-06-25 1988-12-28 Shell Internationale Researchmaatschappij B.V. Lubricating oil composition
EP0965680A1 (en) * 1998-06-18 1999-12-22 Clariant International Ltd. Aqueous dispersions, their preparation and use thereof
WO2002062930A2 (en) * 2001-02-07 2002-08-15 The Lubrizol Corporation Boron containing lubricating oil composition containing a low level of sulfur and phosphorus
WO2003022963A1 (en) * 2001-09-12 2003-03-20 The Lubrizol Corporation Lubricating oil composition

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0857776B2 (en) * 1997-01-07 2007-05-02 Clariant Produkte (Deutschland) GmbH Mineral oil and mineral oil distillate flowability improvement using alkylphenol-aldehyde resins

Family Cites Families (9)

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Publication number Priority date Publication date Assignee Title
DE903496C (en) * 1941-09-20 1954-02-08 Basf Ag Lubricants that are exposed to high temperatures and / or must have high load capacities
DE909021C (en) * 1943-07-07 1954-04-12 Basf Ag lubricant
NL66998C (en) * 1946-08-31
DE920864C (en) * 1951-03-07 1954-12-02 Basf Ag lubricant
US2666044A (en) * 1951-03-09 1954-01-12 Du Pont Alkyl acrylate/n-hydrocarbon-substituted acrylamide/unsaturated tertiary amino compound copolymers
DE947186C (en) * 1951-03-09 1956-08-09 Du Pont Additive to lubricating oils and heating oils
GB770771A (en) * 1953-05-18 1957-03-27 California Research Corp Copolymeric dispersants and lubricant compositions containing them
NL91489C (en) * 1953-05-25
NL92381C (en) * 1954-05-10

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3431062A (en) * 1964-10-26 1969-03-04 Chevron Res Antievaporant process and composition
EP0296674A1 (en) * 1987-06-25 1988-12-28 Shell Internationale Researchmaatschappij B.V. Lubricating oil composition
JPS6485293A (en) * 1987-06-25 1989-03-30 Shell Int Research Lubricant composition
US4876020A (en) * 1987-06-25 1989-10-24 Shell Oil Company Lubricating oil composition
EP0965680A1 (en) * 1998-06-18 1999-12-22 Clariant International Ltd. Aqueous dispersions, their preparation and use thereof
WO1999066118A1 (en) * 1998-06-18 1999-12-23 Clariant Finance (Bvi) Limited Aqueous dispersions, their production and use
US6736865B1 (en) * 1998-06-18 2004-05-18 Clariant Finance (Bvi) Limited Aqueous dispersions, their production and use
WO2002062930A2 (en) * 2001-02-07 2002-08-15 The Lubrizol Corporation Boron containing lubricating oil composition containing a low level of sulfur and phosphorus
WO2002062930A3 (en) * 2001-02-07 2003-03-20 Lubrizol Corp Boron containing lubricating oil composition containing a low level of sulfur and phosphorus
US6605572B2 (en) 2001-02-07 2003-08-12 The Lubrizol Corporation Lubricating oil composition
WO2003022963A1 (en) * 2001-09-12 2003-03-20 The Lubrizol Corporation Lubricating oil composition
US6583092B1 (en) 2001-09-12 2003-06-24 The Lubrizol Corporation Lubricating oil composition

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NL104534C (en)
DE1075254B (en) 1960-02-11

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