US2889282A - Lubricating oil compositions - Google Patents

Lubricating oil compositions Download PDF

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US2889282A
US2889282A US610405A US61040556A US2889282A US 2889282 A US2889282 A US 2889282A US 610405 A US610405 A US 610405A US 61040556 A US61040556 A US 61040556A US 2889282 A US2889282 A US 2889282A
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acid
group
vinylpyridine
methacrylate
oil
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US610405A
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Lyman E Lorensen
Emmett R Barnum
Zachar John
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Shell Development Co
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Shell Development Co
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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M149/00—Lubricating compositions characterised by the additive being a macromolecular compound containing nitrogen
    • C10M149/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M149/10—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a nitrogen-containing hetero ring
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    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/08—Inorganic acids or salts thereof
    • C10M2201/082—Inorganic acids or salts thereof containing nitrogen
    • C10M2201/083—Inorganic acids or salts thereof containing nitrogen nitrites
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    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
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    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
    • C10M2205/026—Butene
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    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/04—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing aromatic monomers, e.g. styrene
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    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/22—Alkylation reaction products with aromatic type compounds, e.g. Friedel-crafts
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    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02—Hydroxy compounds
    • C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
    • C10M2207/026—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings with tertiary alkyl groups
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    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/282—Esters of (cyclo)aliphatic oolycarboxylic acids
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    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/34—Esters having a hydrocarbon substituent of thirty or more carbon atoms, e.g. substituted succinic acid derivatives
    • C—CHEMISTRY; METALLURGY
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    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/40—Fatty vegetable or animal oils
    • C—CHEMISTRY; METALLURGY
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    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/40—Fatty vegetable or animal oils
    • C10M2207/402—Castor oils
    • C—CHEMISTRY; METALLURGY
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    • C10M2207/40—Fatty vegetable or animal oils
    • C10M2207/404—Fatty vegetable or animal oils obtained from genetically modified species
    • C—CHEMISTRY; METALLURGY
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    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/08—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
    • C10M2209/084—Acrylate; Methacrylate
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    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/101—Condensation polymers of aldehydes or ketones and phenols, e.g. Also polyoxyalkylene ether derivatives thereof
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    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
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    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
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    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2215/044—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms having cycloaliphatic groups
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    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/26—Amines
    • C—CHEMISTRY; METALLURGY
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    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/02—Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2217/028—Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a nitrogen-containing hetero ring
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    • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/06—Macromolecular compounds obtained by functionalisation op polymers with a nitrogen containing compound
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
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    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/08—Thiols; Sulfides; Polysulfides; Mercaptals
    • C10M2219/082—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms
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    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
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    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C10M2223/041—Triaryl phosphates
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    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C10M2223/042—Metal salts thereof
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    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
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    • C10M2223/04—Phosphate esters
    • C10M2223/045—Metal containing thio derivatives
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    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/06—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having phosphorus-to-carbon bonds
    • C10M2223/065—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having phosphorus-to-carbon bonds containing sulfur
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    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/12—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions obtained by phosphorisation of organic compounds, e.g. with PxSy, PxSyHal or PxOy
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    • C10M2225/04—Organic macromolecular compounds containing phosphorus as ingredients in lubricant compositions obtained by phosphorisation of macromolecualr compounds not containing phosphorus in the monomers
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    • C10M2229/04—Siloxanes with specific structure
    • C10M2229/041—Siloxanes with specific structure containing aliphatic substituents
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    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00—Metal present as such or in compounds
    • C10N2010/04—Groups 2 or 12

Definitions

  • This invention relates to new and improved mineral oil lubricating compositions Containing a high molecular weight polymer which does not form ash, these lubricating compositions possessing particularly good pour point depressing properties.
  • Lubricating oils because of the nature of their Lsource and/or methods of refining, contain greater or lesser amounts of wax.
  • Lubricating oils of this type are less desirable for many types of operations, particularly under cold operating conditions, such as those encountered in cold climates, this because they readily congeal.
  • pour point depressants In order to overcome this defect in wax-containing lubricating oils, pour point depressants have to be employed with such oils.
  • the polymeric esters of the acrylic or alkacrylic, e.g. methacrylic, acids are also known polymeric materials used for this purpose.
  • Other known polymeric materials used for this purpose are the polymerized olefins, alkylated naphthalene and the like. I
  • polymeric materials can efiectively reduce the pour point of some oils, they are restricted in use to some particular base oils; otherwise they are ineffective and impart certain undesirable properties to the final composition because: (a) they are corrosive, (b) they have the tendency to form emulsions when water or steam is present, and (c) they possess the tendency to break down at elevated temperatures.
  • an excellent pour point depressant which is effective in all mineral oils cornprises an oil-soluble polymeric compound of at least three polymerizable monomers one of them being a vinylpyridine and at least two dissimilar esters of acrylic acid and preferably methacrylic acid and dissimilar long chain aliphatic alcohols, these alcohols containing at least and not more than 20 carbon atoms and wherein the average chain length of these alkyl side chains (straight or branch-chain) in the ester mixture is in the C to C range and preferably in the C to C range.
  • the mole ratio of the vinylpyridine to the polymerizable esters can vary from 1:2 to 1:10 and the dissimilar acrylate esters can vary in the mole ratio of 1:4 to 4:1.
  • the final polymer should have a molecular weight varying from about fifty thousand to about two and one half million and preferably between 100,000 and '85 0,000 as determined by the light scattering method. More specifically, it has been found that terpolymers of a vinylpyridine and mixtures of esters of methacrylic acid and dissimilar aliphatic alcohols, as described above exhibit pour point depressant activity which is far greater than that of the corresponding copolymers of a vinylpyridine with a single ester of methacrylic acid and a long chain aliphatic alcohol.
  • the vinylpyridines used in making the polymers may be exemplified by 2-vinylpyridine, 3-vinylpyridine, 4- vinylpyridine, as well as the alkyl-substituted derivatives thereof, e.g. 2-methyl-5-vinylpyridine, 4-methyl-2-vinylpyridine, S-ethyI-Z-vinylpyridine and '2-butyl-5-vinylpyridine and the like.
  • pyridines include at least two dissimilar esters of acrylic latent O P
  • esters include dodecyl methacrylate/octadecyl methacrylate, tetradecyl acrylate/octadecyl methacrylate, decyl methacrylate/octadecyl methacrylate, tetradecyl methacrylate/hexadecyl methacrylate, technical lauryl methacrylate/octadecyl methacrylate, these ester mixtures being in a mole ratio of from 1:4 to 4: 1, respectively, and so controlled that the average chain length of the alkyl radicals in the final polymer is in the range indicated above.
  • esters of acrylic or methacrylic acid and technical lauryl alcohol which is a mixture of straight chain alcohols should not be considered as a mixture of two or more esters or that using such an ester would result .
  • a polymeric additive suitable for use in oil compositions of this invention since copolymers of lauryl (technical) methacrylate and a vinylpyridine will not have the required dissimilar alkyl chains or the average alkyl chain length which is an essential limitation that polymers of this invention should possess. Rather such copolymers function as simple copolymers and possess the limitations of such esters namely they function as pour point depressants only in specific oils, they tend to break down, form emulsion and cause corrosion.
  • terpolymers derived from a vinylpyridine and a mixture of lauryl methacrylate (derived from technical lauryl :alcohol) and octadecyl (stearyl) methacrylate form excellent pour point depressants of this invention.
  • any suitable method may be employed to make polymers of the present invention.
  • Factors which exert an influence on the molecular weight of thepolymer include the method of polymerization (e.g., polymerization in emulsion, suspension, solvent solution or bulk), the nature and concentration of the catalyst employed, the temperature, and nature and amount of the, monomers.
  • the molecular weight of the product will be lower when the dilution is stronger, i.e., when the concentration of solvent is greater. With the same catalyst, the higher polymerization temperature tends to give lower molecular weights.
  • Polymerization initiators that are particularly suited for use in preparing the claimed copolymers include various free radical yielding catalysts as peroxide.
  • catalysts such as, for example benzoyl peroxide, lauroyl peroxide, tertiary butyl .hydroperoxide, 2,2-bis(tertiary butyl peroxy) butane, di(terti'ary butyl) peroxide, tertiary butyl perlargonate, hydrogen peroxide, sodium or potassium persulfate, percarbonate, peracetic acid and the like.
  • Other suitable catalysts include sodium bisulfite, diethyl sulfoxide, azo compounds, such as alpha,alpha 'azodiisobutyronitrile and the like.
  • the amount of the initiator added may vary over a considerable range. In general, the amount of initiator added will vary from 0.1% to 5% by weight of the material being polymerized. Preferred amounts vary from 0.1% to 2% 'bjw'eight. v
  • the temperature selected will vary depending chiefly on the type of initiator selected, the desired rate of reaction and the molecular weight desired. Generally, the temperature will range from about 50 C. to C., and more preferably from 60 to 150 C. p
  • the polymerization may be conducted in the presence or absence of air. In most :cases, however, it has been found desirable to conduct the polymerization in the absenceof air, e.g., in the presence of an inert gas 'suc has nitrogen. Atmospheric, reduced or superatmospheric pressure may be employed. a I
  • any un'reacted monomer or monomers and/ or solvents may 'be removed, preferably "by distillation or by precipitation with apple priate solvents.
  • the mineral lubricating oils used in compositions of this invention can be obtained from any parafinic, naphthenic, asphaltic or mixed base crude, and/or mixtures thereof.
  • the viscosity of these oils may vary over a wide range, such as from 100 SUS at 100 F. to 100 SUS at 210 F.
  • the hydrocarbon oils may be blended with fixed oils such as castor oil, lard oil and the like and/ or with synthetic lubricants such as polymerized olefins, co-
  • polymers of alkylene 'glycols and alkylene oxides organic esters, e.g., Z-ethylhexyl sebacate, dioctyl polymers, e.'g.,
  • dimethyl silicone polymers and the like.
  • Mineral lubricating oils which are particularly desirable for use in compositions of this invention can be obtained from West Texas Ellenburger crudes, East Texas crudes, Oklahoma crudes, California crudes.
  • a useful refined East Texas mineral lubricating oil had the following propertiesz- Pour point, F. +20
  • Viscosity, cs. at 100 F. 57.2 Viscosity index 90 Example I A mixture of 2.5 mole of stearyl methacrylate, 5.3 mole of lauryl methacrylate and 1 mole of 2-methyl-5-vinylpyridine and 0.2% w. of alpha,alpha'-azodi-isobutyro- Znitrile dissolved in a minor amount for solubility of acetone were placed in a reaction vessel and reacted for about 24-48 hours at 65 C. with stirring in a nitrogen atmosphere. The polymer was then dispersed in equal volumes of benzene and thereafter precipitated with 5-10 volumes of a mixture of acetone and methanol.
  • Example II This was repeated and a terpolymer of stearyl methacrylate/ lauryl methacrylate/Z-methyl-S-vinylpyridine having a ni-
  • the procedure of Example I was followed except that the monomers stearyl methacrylate, lauryl methacrylate and 2-methyl-5-vinylpyridine were reacted in the mole ratio of 2.9, 1.3 and 1, respectively.
  • the average side chain length of the end product was around 13.1.
  • Example 111 The procedure of Example I was followed except that the monomers stearyl methacrylate, lauryl methacrylate and Z-methyl-S-vinylpyridine were reacted in the mole ratio of 1.3, 2.9 and 1 respectively.
  • the average side chain length of the end product was around 12.
  • Example IV I The procedure of Example I was followed except that the monomers stearyl methacrylate, lauryl methacrylate and 2-methy1-5-vinylpyridine were reacted in the mole ratio of 2.2, 2.2, and 1 respectively.
  • the average side chain length of the end product was around 12.5.
  • Example V The procedure of Example I was followed except that the monomers stearyl methacrylate, lauryl methacrylate and Z-methyl-S-vinylpyridine were reacted in the moleratio of 2, 6 and 1, respectively.
  • the average side chain length of the end product was around 12.7.
  • polymeric additives which can be used in compositions of this invention include, dodecyl acrylate/stearyl acrylate/vinylpyridine, hexadecyl methacrylate/stearyl methacrylate/ 2 methyl 5 5 vinylpyri- 4 dine, lauryl methacrylate/stearyl methacrylate/Z-ethyl-S- vinylpyridine and decyl methacrylate/octadecyl methacrylate/vinylpyridine.
  • Example 1 ... l 0.5 30
  • Example II- 0. 5 10 Example III 0.5 25
  • Example IV ... 0. 5 l5
  • Example V 0. 5 -15
  • Example A Copolymer of stearyl methacrylate/Z-methyI-avmyI-pyridine (4.3m): Average chain length 14.1 0. 5 +15
  • Example B Olepolymer of lauryl methacrylate/ 2-methy1-5-vinyl-pyridine (III/1)): Average chain length 8.7 0. 5 +20
  • Example 0 (Oopolymer of stearyl methcrylate/ Z-methyl-5-vinyl-pyridlne (8/1)): Average chain length 15.3 0.
  • compositions ofthis invention can be modified by addition thereto of minor amounts (0.01-2%) of pour point depressants, 'viscosity index improvers, corrosion inhibitors, extreme pressure efiects, anti-oxidants and the like.
  • trichloroethyl phosphite tricresyl phosphate, dilorol phosphate, phosphorus sulfide-olefin reaction products such as P S -terpene reaction products, organic sulfides, e.g., wax disulfide, ethylene bistolyl sulfide; anti-wear agents such as sulfonates and phenates, e.g.
  • a mineral lubricating oil composition comprising a major amount of a mineral lubricating oil and a minor amount sufi'icient to effectively depress the pour point of the oil and improve its detergent properties, of an oil-soluble copolymer of (1) a monovinyl-substituted pyridine of the group consisting of pyridines substituted on one of the ring carbon atoms with, as the sole substituted substituent, a vinyl group, and derivatives of the afore-described vinyl pyridines having a lower alkyl group substituted on a ring carbon atom and (2) a mixture of a C to C alkyl ester of an acrylic acid of the group consisting of acrylic acid and methacrylic acid and a C to C alkyl ester of an acrylic acid of the group consisting of acrylic acid and methacrylic acid in mole ratios varying from 1:4 to 4:1, said copolymer having the monovinyl pyridine and the combined acrylic acid esters in a mole ratio varying
  • composition of claim 1 wherein in the oil soluble copolymer the pyridine is 4-viny1pyridine.
  • composition of claim 1 wherein in the oilsoluble copolymer the pyridine is 2-methyl-5-vinylpyridine.
  • Amineral lubricating oil composition comprising a major amount of a mineral lubricating oil and from about 0.1% to about 5% of an oil-soluble copolymer of (1) monovinyl-substituted pyridine of the group consisting of pyridines substituted on one of the ring carbon atoms with, as the sole substituted substituent, a vinyl group, and derivatives of the aforedescribed vinylpyridines having a lower alkyl group substituted on a ring carbon atom and (2) a mixture of a C to C alkyl ester of an acrylic acid of the group consisting of acrylic acid and methacrylic acid and a C to C alkyl ester of an acrylic acid of the group consisting of acrylic acid and methacrylic acid in mole ratios varying from 1:4 to
  • composition of claim 4 wherein the oil-soluble copolymer is a 2-methyl-5-vinylpyridine/stearyl methacrylate/lauryl methacrylate polymer in the mole ratio of 1:5:2.5, respectively, having a molecular weight of about 800,000.

Description

United States LUBRICATIN G OIL COMPOSITIONS No Drawing. Application September '17, 1956 Serial No. 610,405
6 Claims. cl. 252-515 This invention relates to new and improved mineral oil lubricating compositions Containing a high molecular weight polymer which does not form ash, these lubricating compositions possessing particularly good pour point depressing properties.
Many lubricating oils, because of the nature of their Lsource and/or methods of refining, contain greater or lesser amounts of wax. Lubricating oils of this type are less desirable for many types of operations, particularly under cold operating conditions, such as those encountered in cold climates, this because they readily congeal. In order to overcome this defect in wax-containing lubricating oils, pour point depressants have to be employed with such oils. Among the best known additives for this purpose are the polymeric esters of the acrylic or alkacrylic, e.g. methacrylic, acids. Other known polymeric materials used for this purpose are the polymerized olefins, alkylated naphthalene and the like. I
Although the above-mentioned polymeric materials can efiectively reduce the pour point of some oils, they are restricted in use to some particular base oils; otherwise they are ineffective and impart certain undesirable properties to the final composition because: (a) they are corrosive, (b) they have the tendency to form emulsions when water or steam is present, and (c) they possess the tendency to break down at elevated temperatures.
It has now been discovered that an excellent pour point depressant which is effective in all mineral oils cornprises an oil-soluble polymeric compound of at least three polymerizable monomers one of them being a vinylpyridine and at least two dissimilar esters of acrylic acid and preferably methacrylic acid and dissimilar long chain aliphatic alcohols, these alcohols containing at least and not more than 20 carbon atoms and wherein the average chain length of these alkyl side chains (straight or branch-chain) in the ester mixture is in the C to C range and preferably in the C to C range. The mole ratio of the vinylpyridine to the polymerizable esters can vary from 1:2 to 1:10 and the dissimilar acrylate esters can vary in the mole ratio of 1:4 to 4:1. The final polymer should have a molecular weight varying from about fifty thousand to about two and one half million and preferably between 100,000 and '85 0,000 as determined by the light scattering method. More specifically, it has been found that terpolymers of a vinylpyridine and mixtures of esters of methacrylic acid and dissimilar aliphatic alcohols, as described above exhibit pour point depressant activity which is far greater than that of the corresponding copolymers of a vinylpyridine with a single ester of methacrylic acid and a long chain aliphatic alcohol.
[ The vinylpyridines used in making the polymers may be exemplified by 2-vinylpyridine, 3-vinylpyridine, 4- vinylpyridine, as well as the alkyl-substituted derivatives thereof, e.g. 2-methyl-5-vinylpyridine, 4-methyl-2-vinylpyridine, S-ethyI-Z-vinylpyridine and '2-butyl-5-vinylpyridine and the like.
pyridines include at least two dissimilar esters of acrylic latent O P The esters which can be polymerized with the vinyl-" Patented June 2, 1 959 or methacrylic acid and long chain aliphatic alcohols, e.g. decyl, dodecyl, tetradecyl, hexadecyl (or technical lauryl alcohol), octadecyl and eicosyl alcohols. Specific mixture combinations of these esters include dodecyl methacrylate/octadecyl methacrylate, tetradecyl acrylate/octadecyl methacrylate, decyl methacrylate/octadecyl methacrylate, tetradecyl methacrylate/hexadecyl methacrylate, technical lauryl methacrylate/octadecyl methacrylate, these ester mixtures being in a mole ratio of from 1:4 to 4: 1, respectively, and so controlled that the average chain length of the alkyl radicals in the final polymer is in the range indicated above. I v
An ester of acrylic or methacrylic acid and technical lauryl alcohol, which is a mixture of straight chain alcohols should not be considered as a mixture of two or more esters or that using such an ester would result .in a polymeric additive suitable for use in oil compositions of this invention since copolymers of lauryl (technical) methacrylate and a vinylpyridine will not have the required dissimilar alkyl chains or the average alkyl chain length which is an essential limitation that polymers of this invention should possess. Rather such copolymers function as simple copolymers and possess the limitations of such esters namely they function as pour point depressants only in specific oils, they tend to break down, form emulsion and cause corrosion. On the other hand, terpolymers derived from a vinylpyridine and a mixture of lauryl methacrylate (derived from technical lauryl :alcohol) and octadecyl (stearyl) methacrylate form excellent pour point depressants of this invention.
Any suitable method may be employed to make polymers of the present invention. Factors which exert an influence on the molecular weight of thepolymer include the method of polymerization (e.g., polymerization in emulsion, suspension, solvent solution or bulk), the nature and concentration of the catalyst employed, the temperature, and nature and amount of the, monomers. When the polymerization is accomplished in solution, the molecular weight of the product will be lower when the dilution is stronger, i.e., when the concentration of solvent is greater. With the same catalyst, the higher polymerization temperature tends to give lower molecular weights. Polymerization initiators that are particularly suited for use in preparing the claimed copolymers include various free radical yielding catalysts as peroxide. catalysts, such as, for example benzoyl peroxide, lauroyl peroxide, tertiary butyl .hydroperoxide, 2,2-bis(tertiary butyl peroxy) butane, di(terti'ary butyl) peroxide, tertiary butyl perlargonate, hydrogen peroxide, sodium or potassium persulfate, percarbonate, peracetic acid and the like. Other suitable catalysts include sodium bisulfite, diethyl sulfoxide, azo compounds, such as alpha,alpha 'azodiisobutyronitrile and the like. The amount of the initiator added may vary over a considerable range. In general, the amount of initiator added will vary from 0.1% to 5% by weight of the material being polymerized. Preferred amounts vary from 0.1% to 2% 'bjw'eight. v
The temperature selected will vary depending chiefly on the type of initiator selected, the desired rate of reaction and the molecular weight desired. Generally, the temperature will range from about 50 C. to C., and more preferably from 60 to 150 C. p
The polymerization may be conducted in the presence or absence of air. In most :cases, however, it has been found desirable to conduct the polymerization in the absenceof air, e.g., in the presence of an inert gas 'suc has nitrogen. Atmospheric, reduced or superatmospheric pressure may be employed. a I
- At the end of the polymerization, any un'reacted monomer or monomers and/ or solvents may 'be removed, preferably "by distillation or by precipitation with apple priate solvents.
The mineral lubricating oils used in compositions of this invention can be obtained from any parafinic, naphthenic, asphaltic or mixed base crude, and/or mixtures thereof. The viscosity of these oils may vary over a wide range, such as from 100 SUS at 100 F. to 100 SUS at 210 F. The hydrocarbon oils may be blended with fixed oils such as castor oil, lard oil and the like and/ or with synthetic lubricants such as polymerized olefins, co-
polymers of alkylene 'glycols and alkylene oxides, organic esters, e.g., Z-ethylhexyl sebacate, dioctyl polymers, e.'g.,
dimethyl silicone polymers and the like.
Mineral lubricating oils which are particularly desirable for use in compositions of this invention can be obtained from West Texas Ellenburger crudes, East Texas crudes, Oklahoma crudes, California crudes. A useful refined East Texas mineral lubricating oil had the following propertiesz- Pour point, F. +20
Viscosity, cs. at 100 F. 57.2 Viscosity index 90 Example I A mixture of 2.5 mole of stearyl methacrylate, 5.3 mole of lauryl methacrylate and 1 mole of 2-methyl-5-vinylpyridine and 0.2% w. of alpha,alpha'-azodi-isobutyro- Znitrile dissolved in a minor amount for solubility of acetone were placed in a reaction vessel and reacted for about 24-48 hours at 65 C. with stirring in a nitrogen atmosphere. The polymer was then dispersed in equal volumes of benzene and thereafter precipitated with 5-10 volumes of a mixture of acetone and methanol. This was repeated and a terpolymer of stearyl methacrylate/ lauryl methacrylate/Z-methyl-S-vinylpyridine having a ni- The procedure of Example I was followed except that the monomers stearyl methacrylate, lauryl methacrylate and 2-methyl-5-vinylpyridine were reacted in the mole ratio of 2.9, 1.3 and 1, respectively. The average side chain length of the end product was around 13.1.
Example 111 The procedure of Example I was followed except that the monomers stearyl methacrylate, lauryl methacrylate and Z-methyl-S-vinylpyridine were reacted in the mole ratio of 1.3, 2.9 and 1 respectively. The average side chain length of the end product was around 12.
Example IV I The procedure of Example I was followed except that the monomers stearyl methacrylate, lauryl methacrylate and 2-methy1-5-vinylpyridine were reacted in the mole ratio of 2.2, 2.2, and 1 respectively. The average side chain length of the end product was around 12.5.
Example V The procedure of Example I was followed except that the monomers stearyl methacrylate, lauryl methacrylate and Z-methyl-S-vinylpyridine were reacted in the moleratio of 2, 6 and 1, respectively. The average side chain length of the end product was around 12.7. v
Other examples of polymeric additives which can be used in compositions of this invention include, dodecyl acrylate/stearyl acrylate/vinylpyridine, hexadecyl methacrylate/stearyl methacrylate/ 2 methyl 5 5 vinylpyri- 4 dine, lauryl methacrylate/stearyl methacrylate/Z-ethyl-S- vinylpyridine and decyl methacrylate/octadecyl methacrylate/vinylpyridine.
The pour point effects which additives of this invention lmpart to mineral Oil is evidenced from the data presented below:
[Base-East Texas 250 neutral, pour point +20 FJ Amt, ASTM Additive percent (13-97-47) wt. our Point,
Example 1.... l 0.5 30 Example II- 0. 5 10 Example III 0.5 25 Example IV... 0. 5 l5 Example V 0. 5 -15 Example A (Copolymer of stearyl methacrylate/Z-methyI-avmyI-pyridine (4.3m): Average chain length 14.1 0. 5 +15 Example B (Oopolymer of lauryl methacrylate/ 2-methy1-5-vinyl-pyridine (III/1)): Average chain length 8.7 0. 5 +20 Example 0 (Oopolymer of stearyl methcrylate/ Z-methyl-5-vinyl-pyridlne (8/1)): Average chain length 15.3 0. 5 +21) Compositions ofthis invention can be modified by addition thereto of minor amounts (0.01-2%) of pour point depressants, 'viscosity index improvers, corrosion inhibitors, extreme pressure efiects, anti-oxidants and the like. Among such materials are VI and pour point agent, e.g., high molecular weight polymers, e.'g., Acryloids; wax naphthalene condensation products, isobutylene polymers, alkylstyrene polymers; corrosion inhibitors, e.g., inorganic and organic nitrites such as NaNO or LiNO and =diisopropylammonium nitrite or dicyclohexyl ammonium nitrite, metal organic phosphates, e.'g., Ca or Zn dicyclohexylthiophosphate or methylcyclohexylthiophosphate; extreme pressure agents such as organic phosphites, phosphates and phosphonates, e.g. trichloroethyl phosphite, tricresyl phosphate, dilorol phosphate, phosphorus sulfide-olefin reaction products such as P S -terpene reaction products, organic sulfides, e.g., wax disulfide, ethylene bistolyl sulfide; anti-wear agents such as sulfonates and phenates, e.g. calcium petroleum sulfonate and/or calcium salt of octyl phenol formaldehyde condensation product, anti-oxidants such as phenols and amines, e.g., octadecylamine, 2,6-dietertbutyl-4-methylphenol and the like.
This application is a continuation-in-part of our applications Serial No. 389,840, filed November 2, 1953, now abandoned, and Serial No. 553,731, filed December We claim as our invention:
1. A mineral lubricating oil composition comprising a major amount of a mineral lubricating oil and a minor amount sufi'icient to effectively depress the pour point of the oil and improve its detergent properties, of an oil-soluble copolymer of (1) a monovinyl-substituted pyridine of the group consisting of pyridines substituted on one of the ring carbon atoms with, as the sole substituted substituent, a vinyl group, and derivatives of the afore-described vinyl pyridines having a lower alkyl group substituted on a ring carbon atom and (2) a mixture of a C to C alkyl ester of an acrylic acid of the group consisting of acrylic acid and methacrylic acid and a C to C alkyl ester of an acrylic acid of the group consisting of acrylic acid and methacrylic acid in mole ratios varying from 1:4 to 4:1, said copolymer having the monovinyl pyridine and the combined acrylic acid esters in a mole ratio varying from 1:2 to 1:10, respectively, and a molecular weight from 5x10 to 2.5x10
2. The composition of claim 1 wherein in the oil soluble copolymer the pyridine is 4-viny1pyridine.
, 3. The composition of claim 1 wherein in the oilsoluble copolymer the pyridine is 2-methyl-5-vinylpyridine.
4. Amineral lubricating oil composition comprising a major amount of a mineral lubricating oil and from about 0.1% to about 5% of an oil-soluble copolymer of (1) monovinyl-substituted pyridine of the group consisting of pyridines substituted on one of the ring carbon atoms with, as the sole substituted substituent, a vinyl group, and derivatives of the aforedescribed vinylpyridines having a lower alkyl group substituted on a ring carbon atom and (2) a mixture of a C to C alkyl ester of an acrylic acid of the group consisting of acrylic acid and methacrylic acid and a C to C alkyl ester of an acrylic acid of the group consisting of acrylic acid and methacrylic acid in mole ratios varying from 1:4 to
1:2 to 1:10 and a molecular weight from 100,000 to 15 2,666,044
5. The composition of claim 4 wherein in the oilsoluble copolymer the vinylpyridine is Z-methyl-S-vinylpyridine and the acrylic ester is a mixture of stearyl methacrylate and lauryl methacrylate.
6. The composition of claim 4 wherein the oil-soluble copolymer is a 2-methyl-5-vinylpyridine/stearyl methacrylate/lauryl methacrylate polymer in the mole ratio of 1:5:2.5, respectively, having a molecular weight of about 800,000.
References Cited in the file of this patent UNITED STATES PATENTS Munday et a1 Oct. 13, 1953 Catlin Jan. 12, 1954 Catlin Mar. 6, 1956

Claims (1)

1. A MINERAL LUBRICATING OIL COMPOSITION COMPRISING A MAJOR AMOUNT OF A MINERAL LUBRICATING OIL AND A MINOR AMOUNT SUFFICIENT TO EFFECTIVELY DEPRESS THE POUR POINT OF THE OIL AND IMPROVE ITS DETERGENT PROPERTIES, OF AN OIL-SOLUBLE COPOLYMER OF (1) A MONOVINYL-SUBSTITUTED PYRIDINE OF THE GROUP CONSISTING OF PYRIDINES SUBSTITUTED ON ONE OF THE RING CARBONS WITH, AS THE SOLE SUBSITUTED SUBSTITUENT, A VINYL GROUP, AND DERIVATIVES OF THE AFORE-DESCRIBED VINYL PRYRIDINES HAVING A LOWER ALKYL GROUP SUBSTITUTED ON A RING CARBON ATOM AND (2) A MIXTURE OF A C16 ALKYUL ESTER OF AN ARCYLIC ACID OF THE GROUP CONSISTING OF ARYCLINE ACID AND METHACRYLIC ACID AND A C10 TO C20 ALKYL ESTER OF AN ARCYLIC ACID OF THE GROUP CONSISTING OF THE ARCYLIC ACID AND METHACYRLIC ACID IN MOLE RATIOS VARYING FROM 1:4 TO 4:1, SAID COPOLYMER HAVING THE MONOVINYL PYRIDINE AND THE COMBINED ARCYLIC ACID ESTERS IN A MOLE RATIO VARYING FROM 1:2 TO 1:10 RESPECTIVELY, AND A MOLECULAR WEIGHT FROM 5 X 104 TO 295 X 106.
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