GB830850A - Production of alkoxymethyl acetates - Google Patents

Production of alkoxymethyl acetates

Info

Publication number
GB830850A
GB830850A GB34666/57A GB3466657A GB830850A GB 830850 A GB830850 A GB 830850A GB 34666/57 A GB34666/57 A GB 34666/57A GB 3466657 A GB3466657 A GB 3466657A GB 830850 A GB830850 A GB 830850A
Authority
GB
United Kingdom
Prior art keywords
acetates
alkoxymethyl
distillation
acetic anhydride
fractional distillation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB34666/57A
Inventor
Bertram Yeomans
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Distillers Co Yeast Ltd
Distillers Co Ltd
Original Assignee
Distillers Co Yeast Ltd
Distillers Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Distillers Co Yeast Ltd, Distillers Co Ltd filed Critical Distillers Co Yeast Ltd
Priority to GB34666/57A priority Critical patent/GB830850A/en
Publication of GB830850A publication Critical patent/GB830850A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/02—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen
    • C07C69/12—Acetic acid esters
    • C07C69/14—Acetic acid esters of monohydroxylic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/01—Preparation of ethers
    • C07C41/16—Preparation of ethers by reaction of esters of mineral or organic acids with hydroxy or O-metal groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/48—Preparation of compounds having groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/48—Preparation of compounds having groups
    • C07C41/50—Preparation of compounds having groups by reactions producing groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/08—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with the hydroxy or O-metal group of organic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/02—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen
    • C07C69/12—Acetic acid esters
    • C07C69/16—Acetic acid esters of dihydroxylic compounds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Alkoxymethyl acetates are prepared by heating acetic anhydride with dialkoxy-methanes having at least 4 carbon atoms in the molecule under substantially anhydrous conditions in the presence of an acidic catalyst in a proportion of 0.1 to 1.0% by weight based on the total weight of the acetic anhydride and dialkoxymethane, and recovering the alkoxymethyl acetates by fractional distillation. Alkyl acetates are formed simultaneously. Specified dialkoxymethanes are diethoxy- and di-n-butoxymethane. Reaction is conveniently effected at the boiling-point of the mixture under reflux. The reaction mixture may be freed from the catalyst by flash distillation prior to the fractional distillation. It is preferred to use an excess of whichever reactant is most easily separated from the product by distillation.
GB34666/57A 1957-11-07 1957-11-07 Production of alkoxymethyl acetates Expired GB830850A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB34666/57A GB830850A (en) 1957-11-07 1957-11-07 Production of alkoxymethyl acetates

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB34666/57A GB830850A (en) 1957-11-07 1957-11-07 Production of alkoxymethyl acetates

Publications (1)

Publication Number Publication Date
GB830850A true GB830850A (en) 1960-03-23

Family

ID=10368463

Family Applications (1)

Application Number Title Priority Date Filing Date
GB34666/57A Expired GB830850A (en) 1957-11-07 1957-11-07 Production of alkoxymethyl acetates

Country Status (1)

Country Link
GB (1) GB830850A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0448006A2 (en) * 1990-03-20 1991-09-25 Hoechst Aktiengesellschaft Process for the preparation of acylales
WO1998008800A2 (en) * 1996-08-30 1998-03-05 Dixie Chemical Company Method of producing compounds containing acyloxyalkoxy groups from alcohols

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0448006A2 (en) * 1990-03-20 1991-09-25 Hoechst Aktiengesellschaft Process for the preparation of acylales
EP0448006A3 (en) * 1990-03-20 1992-04-22 Hoechst Aktiengesellschaft Process for the preparation of acylales
US5231221A (en) * 1990-03-20 1993-07-27 Hoechst Aktiengesellschaft Process for the preparation of acylals
WO1998008800A2 (en) * 1996-08-30 1998-03-05 Dixie Chemical Company Method of producing compounds containing acyloxyalkoxy groups from alcohols
WO1998008800A3 (en) * 1996-08-30 2002-10-10 Dixie Chemical Co Method of producing compounds containing acyloxyalkoxy groups from alcohols

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