GB830850A - Production of alkoxymethyl acetates - Google Patents
Production of alkoxymethyl acetatesInfo
- Publication number
- GB830850A GB830850A GB34666/57A GB3466657A GB830850A GB 830850 A GB830850 A GB 830850A GB 34666/57 A GB34666/57 A GB 34666/57A GB 3466657 A GB3466657 A GB 3466657A GB 830850 A GB830850 A GB 830850A
- Authority
- GB
- United Kingdom
- Prior art keywords
- acetates
- alkoxymethyl
- distillation
- acetic anhydride
- fractional distillation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/02—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen
- C07C69/12—Acetic acid esters
- C07C69/14—Acetic acid esters of monohydroxylic compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
- C07C41/01—Preparation of ethers
- C07C41/16—Preparation of ethers by reaction of esters of mineral or organic acids with hydroxy or O-metal groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
- C07C41/48—Preparation of compounds having groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
- C07C41/48—Preparation of compounds having groups
- C07C41/50—Preparation of compounds having groups by reactions producing groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/08—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with the hydroxy or O-metal group of organic compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/02—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen
- C07C69/12—Acetic acid esters
- C07C69/16—Acetic acid esters of dihydroxylic compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Alkoxymethyl acetates are prepared by heating acetic anhydride with dialkoxy-methanes having at least 4 carbon atoms in the molecule under substantially anhydrous conditions in the presence of an acidic catalyst in a proportion of 0.1 to 1.0% by weight based on the total weight of the acetic anhydride and dialkoxymethane, and recovering the alkoxymethyl acetates by fractional distillation. Alkyl acetates are formed simultaneously. Specified dialkoxymethanes are diethoxy- and di-n-butoxymethane. Reaction is conveniently effected at the boiling-point of the mixture under reflux. The reaction mixture may be freed from the catalyst by flash distillation prior to the fractional distillation. It is preferred to use an excess of whichever reactant is most easily separated from the product by distillation.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB34666/57A GB830850A (en) | 1957-11-07 | 1957-11-07 | Production of alkoxymethyl acetates |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB34666/57A GB830850A (en) | 1957-11-07 | 1957-11-07 | Production of alkoxymethyl acetates |
Publications (1)
Publication Number | Publication Date |
---|---|
GB830850A true GB830850A (en) | 1960-03-23 |
Family
ID=10368463
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB34666/57A Expired GB830850A (en) | 1957-11-07 | 1957-11-07 | Production of alkoxymethyl acetates |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB830850A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0448006A2 (en) * | 1990-03-20 | 1991-09-25 | Hoechst Aktiengesellschaft | Process for the preparation of acylales |
WO1998008800A2 (en) * | 1996-08-30 | 1998-03-05 | Dixie Chemical Company | Method of producing compounds containing acyloxyalkoxy groups from alcohols |
-
1957
- 1957-11-07 GB GB34666/57A patent/GB830850A/en not_active Expired
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0448006A2 (en) * | 1990-03-20 | 1991-09-25 | Hoechst Aktiengesellschaft | Process for the preparation of acylales |
EP0448006A3 (en) * | 1990-03-20 | 1992-04-22 | Hoechst Aktiengesellschaft | Process for the preparation of acylales |
US5231221A (en) * | 1990-03-20 | 1993-07-27 | Hoechst Aktiengesellschaft | Process for the preparation of acylals |
WO1998008800A2 (en) * | 1996-08-30 | 1998-03-05 | Dixie Chemical Company | Method of producing compounds containing acyloxyalkoxy groups from alcohols |
WO1998008800A3 (en) * | 1996-08-30 | 2002-10-10 | Dixie Chemical Co | Method of producing compounds containing acyloxyalkoxy groups from alcohols |
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