GB823514A - Dehydrogenation of alcohols - Google Patents
Dehydrogenation of alcoholsInfo
- Publication number
- GB823514A GB823514A GB10618/58A GB1061858A GB823514A GB 823514 A GB823514 A GB 823514A GB 10618/58 A GB10618/58 A GB 10618/58A GB 1061858 A GB1061858 A GB 1061858A GB 823514 A GB823514 A GB 823514A
- Authority
- GB
- United Kingdom
- Prior art keywords
- dehydrogenation
- alcohol
- alcohols
- propionaldehyde
- cyclohexanol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/18—Carbon
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
- B01J23/42—Platinum
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
- C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
- C07C29/143—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of ketones
- C07C29/145—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of ketones with hydrogen or hydrogen-containing gases
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/002—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by dehydrogenation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/29—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
- C07C45/37—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of >C—O—functional groups to >C=O groups
- C07C45/38—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of >C—O—functional groups to >C=O groups being a primary hydroxyl group
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C47/00—Compounds having —CHO groups
- C07C47/52—Compounds having —CHO groups bound to carbon atoms of six—membered aromatic rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
- C07C49/385—Saturated compounds containing a keto group being part of a ring
- C07C49/403—Saturated compounds containing a keto group being part of a ring of a six-membered ring
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Primary and secondary alcohols are selectively dehydrogenated to aldehydes and ketones by passing them at elevated temperature over a catalyst which comprises a metal of the platinum group on a non-acidic support. The temperature at which the process is carried out is generally in the range 100-500 DEG C. and the pressure 0.01 to 10 atmospheres. Suitable carrier materials are, for example, charcoal, asbestos and calcium carbonate. The process may be used, for example, for the dehydrogenation of isopropanol to acetone, benzyl alcohol to benzaldehyde, n-propyl alcohol to propionaldehyde, sec.-butyl alcohol to methyl ethyl ketone and cyclohexanol to cyclohexanone.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US823514XA | 1957-05-02 | 1957-05-02 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB823514A true GB823514A (en) | 1959-11-11 |
Family
ID=22170652
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB10618/58A Expired GB823514A (en) | 1957-05-02 | 1958-04-02 | Dehydrogenation of alcohols |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB823514A (en) |
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1175219B (en) * | 1961-05-24 | 1964-08-06 | Shell Int Research | Process for the production of acetone |
DE1211629B (en) * | 1962-08-14 | 1966-03-03 | Basf Ag | Process for the dehydrogenation of cyclohexanol |
DE2028350A1 (en) * | 1969-06-11 | 1970-12-17 | ||
US3981923A (en) * | 1969-06-11 | 1976-09-21 | Shell Oil Company | Dehydrogenation of alcohols to ketones |
US4218401A (en) * | 1974-01-11 | 1980-08-19 | The Dow Chemical Company | Oxydehydrogenation of alcohols |
US4250121A (en) * | 1978-05-24 | 1981-02-10 | Institut Francais Du Petrole | Catalytic oxidation of alcohols with molecular oxygen to form carbonyl compounds |
US4935538A (en) * | 1986-05-29 | 1990-06-19 | The Standard Oil Company | Oxygenate condensation |
US5103066A (en) * | 1990-12-10 | 1992-04-07 | Mobil Oil Corp. | Dehydrogenation of alcohols over non-acidic metal-zeolite catalysts |
US8729317B2 (en) | 2012-02-15 | 2014-05-20 | Celanese International Corporation | Ethanol manufacturing process over catalyst with cesium and support comprising tungsten or oxides thereof |
US8729311B2 (en) | 2012-02-10 | 2014-05-20 | Celanese International Corporaton | Catalysts for converting acetic acid to acetone |
-
1958
- 1958-04-02 GB GB10618/58A patent/GB823514A/en not_active Expired
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1175219B (en) * | 1961-05-24 | 1964-08-06 | Shell Int Research | Process for the production of acetone |
DE1211629B (en) * | 1962-08-14 | 1966-03-03 | Basf Ag | Process for the dehydrogenation of cyclohexanol |
DE2028350A1 (en) * | 1969-06-11 | 1970-12-17 | ||
US3981923A (en) * | 1969-06-11 | 1976-09-21 | Shell Oil Company | Dehydrogenation of alcohols to ketones |
US4218401A (en) * | 1974-01-11 | 1980-08-19 | The Dow Chemical Company | Oxydehydrogenation of alcohols |
US4250121A (en) * | 1978-05-24 | 1981-02-10 | Institut Francais Du Petrole | Catalytic oxidation of alcohols with molecular oxygen to form carbonyl compounds |
US4935538A (en) * | 1986-05-29 | 1990-06-19 | The Standard Oil Company | Oxygenate condensation |
US5103066A (en) * | 1990-12-10 | 1992-04-07 | Mobil Oil Corp. | Dehydrogenation of alcohols over non-acidic metal-zeolite catalysts |
US8729311B2 (en) | 2012-02-10 | 2014-05-20 | Celanese International Corporaton | Catalysts for converting acetic acid to acetone |
US8729317B2 (en) | 2012-02-15 | 2014-05-20 | Celanese International Corporation | Ethanol manufacturing process over catalyst with cesium and support comprising tungsten or oxides thereof |
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