GB823514A - Dehydrogenation of alcohols - Google Patents

Dehydrogenation of alcohols

Info

Publication number
GB823514A
GB823514A GB10618/58A GB1061858A GB823514A GB 823514 A GB823514 A GB 823514A GB 10618/58 A GB10618/58 A GB 10618/58A GB 1061858 A GB1061858 A GB 1061858A GB 823514 A GB823514 A GB 823514A
Authority
GB
United Kingdom
Prior art keywords
dehydrogenation
alcohol
alcohols
propionaldehyde
cyclohexanol
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB10618/58A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Engelhard Industries Inc
Original Assignee
Engelhard Industries Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Engelhard Industries Inc filed Critical Engelhard Industries Inc
Publication of GB823514A publication Critical patent/GB823514A/en
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/18—Carbon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/42—Platinum
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/143—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of ketones
    • C07C29/145—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of ketones with hydrogen or hydrogen-containing gases
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/002—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by dehydrogenation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/29—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/37—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of >C—O—functional groups to >C=O groups
    • C07C45/38—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of >C—O—functional groups to >C=O groups being a primary hydroxyl group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C47/00—Compounds having —CHO groups
    • C07C47/52—Compounds having —CHO groups bound to carbon atoms of six—membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/385—Saturated compounds containing a keto group being part of a ring
    • C07C49/403—Saturated compounds containing a keto group being part of a ring of a six-membered ring

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Primary and secondary alcohols are selectively dehydrogenated to aldehydes and ketones by passing them at elevated temperature over a catalyst which comprises a metal of the platinum group on a non-acidic support. The temperature at which the process is carried out is generally in the range 100-500 DEG C. and the pressure 0.01 to 10 atmospheres. Suitable carrier materials are, for example, charcoal, asbestos and calcium carbonate. The process may be used, for example, for the dehydrogenation of isopropanol to acetone, benzyl alcohol to benzaldehyde, n-propyl alcohol to propionaldehyde, sec.-butyl alcohol to methyl ethyl ketone and cyclohexanol to cyclohexanone.
GB10618/58A 1957-05-02 1958-04-02 Dehydrogenation of alcohols Expired GB823514A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US823514XA 1957-05-02 1957-05-02

Publications (1)

Publication Number Publication Date
GB823514A true GB823514A (en) 1959-11-11

Family

ID=22170652

Family Applications (1)

Application Number Title Priority Date Filing Date
GB10618/58A Expired GB823514A (en) 1957-05-02 1958-04-02 Dehydrogenation of alcohols

Country Status (1)

Country Link
GB (1) GB823514A (en)

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1175219B (en) * 1961-05-24 1964-08-06 Shell Int Research Process for the production of acetone
DE1211629B (en) * 1962-08-14 1966-03-03 Basf Ag Process for the dehydrogenation of cyclohexanol
DE2028350A1 (en) * 1969-06-11 1970-12-17
US3981923A (en) * 1969-06-11 1976-09-21 Shell Oil Company Dehydrogenation of alcohols to ketones
US4218401A (en) * 1974-01-11 1980-08-19 The Dow Chemical Company Oxydehydrogenation of alcohols
US4250121A (en) * 1978-05-24 1981-02-10 Institut Francais Du Petrole Catalytic oxidation of alcohols with molecular oxygen to form carbonyl compounds
US4935538A (en) * 1986-05-29 1990-06-19 The Standard Oil Company Oxygenate condensation
US5103066A (en) * 1990-12-10 1992-04-07 Mobil Oil Corp. Dehydrogenation of alcohols over non-acidic metal-zeolite catalysts
US8729311B2 (en) 2012-02-10 2014-05-20 Celanese International Corporaton Catalysts for converting acetic acid to acetone
US8729317B2 (en) 2012-02-15 2014-05-20 Celanese International Corporation Ethanol manufacturing process over catalyst with cesium and support comprising tungsten or oxides thereof

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1175219B (en) * 1961-05-24 1964-08-06 Shell Int Research Process for the production of acetone
DE1211629B (en) * 1962-08-14 1966-03-03 Basf Ag Process for the dehydrogenation of cyclohexanol
DE2028350A1 (en) * 1969-06-11 1970-12-17
US3981923A (en) * 1969-06-11 1976-09-21 Shell Oil Company Dehydrogenation of alcohols to ketones
US4218401A (en) * 1974-01-11 1980-08-19 The Dow Chemical Company Oxydehydrogenation of alcohols
US4250121A (en) * 1978-05-24 1981-02-10 Institut Francais Du Petrole Catalytic oxidation of alcohols with molecular oxygen to form carbonyl compounds
US4935538A (en) * 1986-05-29 1990-06-19 The Standard Oil Company Oxygenate condensation
US5103066A (en) * 1990-12-10 1992-04-07 Mobil Oil Corp. Dehydrogenation of alcohols over non-acidic metal-zeolite catalysts
US8729311B2 (en) 2012-02-10 2014-05-20 Celanese International Corporaton Catalysts for converting acetic acid to acetone
US8729317B2 (en) 2012-02-15 2014-05-20 Celanese International Corporation Ethanol manufacturing process over catalyst with cesium and support comprising tungsten or oxides thereof

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