GB821113A - Improvements in and relating to cellulosic woven and sheet materials having bactericidal properties - Google Patents
Improvements in and relating to cellulosic woven and sheet materials having bactericidal propertiesInfo
- Publication number
- GB821113A GB821113A GB37929/56A GB3792956A GB821113A GB 821113 A GB821113 A GB 821113A GB 37929/56 A GB37929/56 A GB 37929/56A GB 3792956 A GB3792956 A GB 3792956A GB 821113 A GB821113 A GB 821113A
- Authority
- GB
- United Kingdom
- Prior art keywords
- bis
- biguanide
- alkyl
- group
- wetting agents
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides
- A01N47/42—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides containing —N=CX2 groups, e.g. isothiourea
- A01N47/44—Guanidine; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L15/00—Chemical aspects of, or use of materials for, bandages, dressings or absorbent pads
- A61L15/16—Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons
- A61L15/20—Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons containing organic materials
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L15/00—Chemical aspects of, or use of materials for, bandages, dressings or absorbent pads
- A61L15/16—Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons
- A61L15/42—Use of materials characterised by their function or physical properties
- A61L15/46—Deodorants or malodour counteractants, e.g. to inhibit the formation of ammonia or bacteria
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Epidemiology (AREA)
- Hematology (AREA)
- Materials Engineering (AREA)
- Pest Control & Pesticides (AREA)
- General Chemical & Material Sciences (AREA)
- Biochemistry (AREA)
- Microbiology (AREA)
- Textile Engineering (AREA)
- Agronomy & Crop Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Plant Pathology (AREA)
- Zoology (AREA)
- Wood Science & Technology (AREA)
- Dentistry (AREA)
- Environmental Sciences (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Cellulosic woven and sheet materials are impregnated with at least 0.001 per cent of their dry weight of a bis-biguanide (or a salt thereof) of the formula: <FORM:0821113/IV(c)/1> where A is a phenyl radical which may be substituted by alkyl, alkoxy, nitro or halogen, X is a direct linkage or an alkylene radical of not more than 3 carbon atoms, R is hydrogen or an alkyl or aralkyl radical and n is an integer from 2 to 12 inclusive and wherein the polymethylene chain (CH2)n may optionally be interrupted by oxygen atoms and/or by aromatic nuclei, whereby the materials are given self-sterilizing and bactericidal properties. Suitable bis-biguanide salts are hydrochlorides and acetates and those derived from polyhydroxy carboxylic acids, e.g. D-gluconates, and from hydroxy alkane sulphonic acids, e.g. isethionates. The bis-biguanides may be applied in aqueous solutions, e.g. aqueous ethanol or aqueous propylene glycol, or in organic solvents, e.g. ethyl alcohol and/or acetone. Aqueous solutions preferably contain between 0.001 and 10 per cent by weight of the bis-biguanide and may also contain wetting agents and/or detergents, e.g. inorganic detergents and/or organic surface-active substances of the cationic or non-ionic kind. Suitable wetting agents are condensation products of ethylene oxide with alkyl phenols, e.g. octyl cresol, or with fatty alcohols, e.g. cetyl alcohol, or long-chain quaternary salts, e.g. cetyl trimethyl ammonium bromide. Haemostatic agents, e.g. natural vegetable gums, such as alginic acid, and synthetic gums, such as carboxymethyl cellulose, may also be present. Specifications 705,838, [Group IV (b)], 710,105, [Group VI], 785,937, [Group VIII], 815,800 and 815,925, [both in Group VI], are referred to.ALSO:Cellulosic medical goods, e.g. surgical dressings, gauze, lint, cotton wool, and towelling, and handkerchief tissues, are given self-sterilizing and bactericidal properties by impregnating them with at least 0.001% of their dry weight of a bis-biguanide (or a salt thereof) of the formula <FORM:0821113/VI/1> where A is a phenyl radical which may be substituted by alkyl, alkoxy, nitro or halogen, X is a direct linkage or an alkylene radical of not more than 3 carbon atoms, R is hydrogen or an alkyl or aralkyl radical and n is an integer from 2 to 12 inclusive and wherein the polymethylene chain (CH2)n may optionally be interrupted by oxygen atoms and/or by aromatic nuclei. Suitable bis-biguanide salts are hydrochlorides and acetates and those derived from polyhydroxy carboxylic acids, e.g. D-glucanates, and from hydroxy alkane sulphonic acids, e.g. isothionates. The bis-biguanides may be applied in aqueous solutions, e.g. aqueous ethanol or aqueous propylene glycol, or in organic solvents, e.g. ethyl alcohol and/or acetone. Aqueous solutions preferably contain between 0.001 and 10% by weight of the bis-biguanide and may also contain wetting agents and/or detergents, e.g. inorganic detergents and/or organic surface-active substances of the cationic or non-ionic kind. Suitable wetting agents are condensation products of ethylene oxide with alkyl phenols, e.g. octyl cresol, or with fatty alcohols, e.g. cetyl alcohol, or long-chain quaternary salts, e.g. cetyl trimethyl ammonium bromide. Haemostatic agents, e.g. natural vegetable gums, such as alginic acid, and synthetic gums, such as carboxymethyl cellulose, may also be present. Specifications 705,838, [Group IV (b)], 710,105, 785,937, [Group VIII], 815,800 and 815,925 are referred to.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB37929/56A GB821113A (en) | 1956-12-12 | 1956-12-12 | Improvements in and relating to cellulosic woven and sheet materials having bactericidal properties |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB37929/56A GB821113A (en) | 1956-12-12 | 1956-12-12 | Improvements in and relating to cellulosic woven and sheet materials having bactericidal properties |
Publications (1)
Publication Number | Publication Date |
---|---|
GB821113A true GB821113A (en) | 1959-09-30 |
Family
ID=10400007
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB37929/56A Expired GB821113A (en) | 1956-12-12 | 1956-12-12 | Improvements in and relating to cellulosic woven and sheet materials having bactericidal properties |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB821113A (en) |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2218893A1 (en) * | 1973-02-23 | 1974-09-20 | Procter & Gamble | |
EP0099209A1 (en) * | 1982-07-01 | 1984-01-25 | JOHNSON & JOHNSON MEDICAL, INC. | Aqueous disinfectant solutions having residual biocidal activity |
FR2686221A1 (en) * | 1992-01-22 | 1993-07-23 | Hutchinson | Compositions based on antiseptics and their applications |
EP0555116A2 (en) * | 1992-01-22 | 1993-08-11 | Hutchinson | Compositions based on antiseptics and their applications |
FR2691325A1 (en) * | 1992-05-21 | 1993-11-26 | Hutchinson | Synergistic antiseptic compsns. |
WO1995012021A1 (en) * | 1993-10-27 | 1995-05-04 | Zeneca Limited | Antimicrobial treatment of textile materials |
WO2003080073A1 (en) * | 2002-03-26 | 2003-10-02 | Belozerskaya Galina Gennadievn | Hemostatic dressing |
ITMI20100520A1 (en) * | 2010-03-29 | 2011-09-30 | Darwin Labo S R L | HYGIENIC COVER MATERIAL WITH ANTIBACTERIAL AND GERMICIDAL PROPERTIES, AND RELATIVE METHOD |
-
1956
- 1956-12-12 GB GB37929/56A patent/GB821113A/en not_active Expired
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2218893A1 (en) * | 1973-02-23 | 1974-09-20 | Procter & Gamble | |
EP0099209A1 (en) * | 1982-07-01 | 1984-01-25 | JOHNSON & JOHNSON MEDICAL, INC. | Aqueous disinfectant solutions having residual biocidal activity |
FR2686221A1 (en) * | 1992-01-22 | 1993-07-23 | Hutchinson | Compositions based on antiseptics and their applications |
EP0555116A2 (en) * | 1992-01-22 | 1993-08-11 | Hutchinson | Compositions based on antiseptics and their applications |
EP0555116A3 (en) * | 1992-01-22 | 1993-10-06 | Hutchinson | Compositions based on antiseptics and their applications |
FR2691325A1 (en) * | 1992-05-21 | 1993-11-26 | Hutchinson | Synergistic antiseptic compsns. |
WO1995012021A1 (en) * | 1993-10-27 | 1995-05-04 | Zeneca Limited | Antimicrobial treatment of textile materials |
US5700742A (en) * | 1993-10-27 | 1997-12-23 | Zeneca Limited | Antimicrobial treatment of textile materials |
WO2003080073A1 (en) * | 2002-03-26 | 2003-10-02 | Belozerskaya Galina Gennadievn | Hemostatic dressing |
ITMI20100520A1 (en) * | 2010-03-29 | 2011-09-30 | Darwin Labo S R L | HYGIENIC COVER MATERIAL WITH ANTIBACTERIAL AND GERMICIDAL PROPERTIES, AND RELATIVE METHOD |
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