GB1047037A - Treatment of textile fibres and polymeric sheet materials - Google Patents

Treatment of textile fibres and polymeric sheet materials

Info

Publication number
GB1047037A
GB1047037A GB19494/64A GB1949464A GB1047037A GB 1047037 A GB1047037 A GB 1047037A GB 19494/64 A GB19494/64 A GB 19494/64A GB 1949464 A GB1949464 A GB 1949464A GB 1047037 A GB1047037 A GB 1047037A
Authority
GB
United Kingdom
Prior art keywords
phenol
aromatic
ethylene oxide
methyl
ortho
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB19494/64A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nopco Chemical Co
Original Assignee
Nopco Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nopco Chemical Co filed Critical Nopco Chemical Co
Publication of GB1047037A publication Critical patent/GB1047037A/en
Expired legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/53—Polyethers
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
    • C07C37/11—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by reactions increasing the number of carbon atoms
    • C07C37/14—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by reactions increasing the number of carbon atoms by addition reactions, i.e. reactions involving at least one carbon-to-carbon unsaturated bond
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M7/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made of other substances with subsequent freeing of the treated goods from the treating medium, e.g. swelling, e.g. polyolefins
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/40—Reduced friction resistance, lubricant properties; Sizing compositions
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S524/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S524/91—Antistatic compositions

Abstract

Compounds suitable for use in the treatment of textile materials and polymeric sheet materials are produced by condensing an aromatic compound containing an aromatic moiety and an aromatic phenolic moiety having at least one phenolic hydroxy group, of which a -methyl benzyl para phenol a -methyl benzyl ortho phenol, ortho phenyl phenol, para phenyl phenol and 4-methyl-41-hydroxy diphenyl sulphone are specified, with 5-20 moles of ethylene oxide per phenolic hydroxy group contained within the compound. In Example I a -methyl benzyl para phenol is prepared by the reaction of phenol with styrene in the presence of a catalyst consisting of boron trifluoride and an aqueous solution of hypophosphorous acid, and is then condensed with 9 moles of ethylene oxide.ALSO:Compounds suitable for use in the treatment of textile materials and polymeric sheet materials are produced by condensing an aromatic compound containing an aromatic moiety and an aromatic phenolic moiety having at least one phenolic hydroxy group, of which a -methyl benzyl para phenol, a -methyl benzyl ortho phenol, ortho phenyl phenol, para phenyl phenol and 4-methyl-41-hydroxy diphenyl sulphone are specified, with 5-20 moles of ethylene oxide per phenolic hydroxy group contained within the compound. In Example XI, a resin mixture is prepared from polyvinyl chloride, di-2-ethyl hexyl phthalate, epoxidized soya bean oil, stearic acid, a barium octoate-zinc octoate stabilizer and a condensate of 1 mole of a -methyl benzyl ortho phenol with 9.1 moles of ethylene oxide and made into sheet material.ALSO:A catalytic composition comprises boron trifluoride and an aqueous solution of hypophosphorous acid.ALSO:Natural and synthetic textile materials in the form of fibre, continuous or spun yarns, filaments, rovings, slivers or tops are lubricated and rendered antistatic by treating them with a water-soluble compound produced by condensing an aromatic compound containing an aromatic moiety and an aromatic phenolic moiety having at least one phenolic hydroxy group with 5-20 moles of ethylene oxide per phenolic hydroxy group contained in the compound. The aromatic compound which is condensed with the ethylene oxide may be <FORM:1047037/D1-D2/1> in which R is an aryl or substituted aryl radical containing 6-24 carbon atoms, e.g. phenyl. chlorophenyl, octyl phenyl, diphenyl, hydroxy benzyl, dioctyl-o-hydroxy benzyl or 2-hydroxy-3-(ortho hydroxy benzyl) phenyl, X is hydrogen, chlorine, bromine or a straight or branched chain alkyl radical containing 1-15 carbon atoms and R1 and R2 which may be the same or different are hydrogen or alkyl radicals containing 1-5 carbon atoms. The compounds may be applied to the textile materials from an aqueous solution or solution in an organic solvent, e.g. ether, methyl alcohol, ethyl alcohol or acetone, in an amount of from 0.01-1.3% by weight. Textile materials made from cellulose acetate, nylon, polyethylene terephthalate, acrylic, viscose rayon, polyvinylidene chloride, copolymers of acrylonitrile and polyvinyl alcohol, polyethylene, polypropylene, cotton, wool, linen, silk, casein or vicara fibres may be treated.
GB19494/64A 1963-05-16 1964-05-11 Treatment of textile fibres and polymeric sheet materials Expired GB1047037A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US28101763A 1963-05-16 1963-05-16
US575537A US3333983A (en) 1963-05-16 1966-08-29 Antistatic polymeric materials containing ethylene oxide condensation products of phenolic derivatives

Publications (1)

Publication Number Publication Date
GB1047037A true GB1047037A (en) 1966-11-02

Family

ID=26960658

Family Applications (1)

Application Number Title Priority Date Filing Date
GB19494/64A Expired GB1047037A (en) 1963-05-16 1964-05-11 Treatment of textile fibres and polymeric sheet materials

Country Status (5)

Country Link
US (1) US3333983A (en)
DE (1) DE1469503C3 (en)
FR (1) FR1397579A (en)
GB (1) GB1047037A (en)
NL (1) NL147801B (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2227491A (en) * 1989-01-26 1990-08-01 Armstrong World Ind Inc Antistatic surface covering materials
EP2653512A2 (en) * 2012-04-18 2013-10-23 Dow Global Technologies LLC Aqueous coating compositions including phenylphenol ethoxylate surfactants

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3428481A (en) * 1966-07-06 1969-02-18 Du Pont Antistatic lubricating composition for textile fibers
US3653955A (en) * 1968-05-20 1972-04-04 Deering Milliken Res Corp Antistatic fiber treatments
US3620823A (en) * 1969-05-19 1971-11-16 Monsanto Co Process of improving the resistance of soiling of melt spun fibers
US3770494A (en) * 1969-12-18 1973-11-06 Asahi Chemical Ind Modified acrylonitrile polymer fibers
US3873353A (en) * 1973-03-05 1975-03-25 Allied Chem Antistatic fiber
US3907689A (en) * 1973-08-29 1975-09-23 Eastman Kodak Co Textile treating composition and textile yarn treated therewith
US3947613A (en) * 1974-08-07 1976-03-30 The United States Of America As Represented By The Secretary Of Agriculture Process for reducing agent migration during treatment of knitted cotton fabric
DE3126551C2 (en) * 1981-07-04 1983-12-15 Rolf Dr. 8700 Würzburg Siegel Manufacturing process for materials for immobilizing proteins and carbohydrate groups
US4457874A (en) * 1981-08-19 1984-07-03 Diamond Shamrock Chemicals Company Condensation products of substituted phenol sulfonic acid and formaldehyde
US4479826A (en) * 1982-07-09 1984-10-30 Diamond Shamrock Chemicals Company Condensation products of substituted phenol sulfonic acid and formaldehyde

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1970578A (en) * 1930-11-29 1934-08-21 Ig Farbenindustrie Ag Assistants for the textile and related industries
US2213477A (en) * 1935-12-12 1940-09-03 Gen Aniline & Film Corp Glycol and polyglycol ethers of isocyclic hydroxyl compounds
GB614594A (en) * 1946-07-16 1948-12-17 Geoffrey Philip Lee Improved articles prepared wholly or in part from polythene compositions
NL98396C (en) * 1953-03-13

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2227491A (en) * 1989-01-26 1990-08-01 Armstrong World Ind Inc Antistatic surface covering materials
GB2227491B (en) * 1989-01-26 1993-01-06 Armstrong World Ind Inc Surface covering materials
EP2653512A2 (en) * 2012-04-18 2013-10-23 Dow Global Technologies LLC Aqueous coating compositions including phenylphenol ethoxylate surfactants
EP2653512A3 (en) * 2012-04-18 2014-09-10 Dow Global Technologies LLC Aqueous coating compositions including phenylphenol ethoxylate surfactants
US8901213B2 (en) 2012-04-18 2014-12-02 Dow Global Technologies Llc Aqueous coating compositions including phenylphenol ethoxylate surfactants

Also Published As

Publication number Publication date
US3333983A (en) 1967-08-01
FR1397579A (en) 1965-04-30
NL147801B (en) 1975-11-17
DE1469503A1 (en) 1969-01-30
DE1469503C3 (en) 1974-05-16
NL6405428A (en) 1964-11-17
DE1469503B2 (en) 1973-10-11

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