GB809060A - Detergent compositions - Google Patents

Detergent compositions

Info

Publication number
GB809060A
GB809060A GB15178/57A GB1517857A GB809060A GB 809060 A GB809060 A GB 809060A GB 15178/57 A GB15178/57 A GB 15178/57A GB 1517857 A GB1517857 A GB 1517857A GB 809060 A GB809060 A GB 809060A
Authority
GB
United Kingdom
Prior art keywords
fatty acid
amides
fatty
sulphonates
carbon atoms
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB15178/57A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hedley Thomas & Co Ltd
Thomas Hedley and Co Ltd
Original Assignee
Hedley Thomas & Co Ltd
Thomas Hedley and Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hedley Thomas & Co Ltd, Thomas Hedley and Co Ltd filed Critical Hedley Thomas & Co Ltd
Publication of GB809060A publication Critical patent/GB809060A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0094—High foaming compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/65—Mixtures of anionic with cationic compounds
    • C11D1/652—Mixtures of anionic compounds with carboxylic amides or alkylol amides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/65—Mixtures of anionic with cationic compounds
    • C11D1/655—Mixtures of sulfonated products with alkylolamides of carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/06—Phosphates, including polyphosphates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C11D1/146—Sulfuric acid esters
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
    • C11D1/523—Carboxylic alkylolamides, or dialkylolamides, or hydroxycarboxylic amides (R1-CO-NR2R3), where R1, R2 or R3 contain one hydroxy group per alkyl group
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
    • C11D1/525—Carboxylic amides (R1-CO-NR2R3), where R1, R2 or R3 contain two or more hydroxy groups per alkyl group, e.g. R3 being a reducing sugar rest

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

A detergent composition comprises (a) at least one water-soluble detergent salt of an organic sulphuric reaction product containing a sulphuric or sulphonic acid radical in the molecule; and (b) one or more of the following amides, which act as foam-improving agents at temperatures below 100 DEG F.: <FORM:0809060/III/1> <FORM:0809060/III/2> <FORM:0809060/III/3> where R.CO is an acyl radical derived from a fatty acid or mixture of fatty acids containing or predominantly containing 10-14 carbon atoms, and R1 is an alkyl radical or mixture of such radicals also containing or predominantly containing 10-14 carbon atoms, the amount of (b) being 5-60 per cent, preferably 5-35 per cent, of (a). The detergent salts may be the mono - fatty acid esters of 1 : 2 - dihydroxypropane-3-sulphonates, fatty acid mono-esters of hydroxyalkyl-sulphonates, fatty amides of aminoalkyl-sulphonates, salts of fatty alcohol esters of sulphocarboxylic acids, fatty alcohol ethers of hydroxy- and poly-hydroxyalkyl sulphonates, fatty acid monoglyceride sulphates, sulphated fatty alkanolamides, and alkylpolyoxyethylene sulphates, but the preferred compounds, which suitably comprise 10-40 per cent of the composition, are the alkylbenzene sulphonates having 9-15, and an average of 12, carbon atoms in the alkyl group, and primary alkyl sulphates containing 12-18 carbon atoms. The amides, of which examples are given, are usually present to the extent of 0.5-25 per cent of the composition, which generally also contains alkali metal polyphosphate in an amount 1-5 times that of the detergent salt. The composition may also include other alkali metal phosphates, silicates, carbonates and sulphates, fluorescent dyes, bleaching agents, and perfumes.ALSO:Amides of the formula <FORM:0809060/IV (b)/1> in which R.CO is derived from a C10-14 fatty acid, are made by introducing N : N-bis-(hydroxyethyl)-trimethylenediamine below the surface of molten C10-14 fatty acid, which is stirred under a atmosphere of nitrogen, the water formed being aspirated after some time under vacuum. Specific compounds which may be so prepared are N-[3-bis-(2-hydroxyethyl) aminopropyl] - lauramide, -decanamide, and -myristamide. Amides of the formula R.CO.N(CH3)CH2(CHOH)4.CH2OH, in which R.CO- is derived from a C10-14 fatty acid, are made by heating together equimolar amounts of N-methylglucamine and C10-14 fatty acid with constant removal of water formed. N-lauroyl-, N-decanoyl-, and N-myristoyl-, N-methylglucamine are described. Amides of the formula R1.NH.CO(CHOH)4.CH2OH, in which R1 is C10-14 alkyl, are made by condensing a C10-14 alkylamine with d -gluconolactone in refluxing methanol, the product so obtained being recrystallized from methanol or ethanol. Compounds specified are the N-laryl-, N-decyl-, N-dodecyl-, and N-tetradecyl-d-gluconamide.
GB15178/57A 1956-05-14 1957-05-13 Detergent compositions Expired GB809060A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US584469A US2965576A (en) 1956-05-14 1956-05-14 Detergent compositions

Publications (1)

Publication Number Publication Date
GB809060A true GB809060A (en) 1959-02-18

Family

ID=24337447

Family Applications (1)

Application Number Title Priority Date Filing Date
GB15178/57A Expired GB809060A (en) 1956-05-14 1957-05-13 Detergent compositions

Country Status (7)

Country Link
US (1) US2965576A (en)
BE (1) BE557103A (en)
CH (1) CH359503A (en)
DE (1) DE1072347B (en)
FR (1) FR1186986A (en)
GB (1) GB809060A (en)
NL (1) NL217218A (en)

Cited By (43)

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WO1993001267A1 (en) * 1991-07-08 1993-01-21 The Procter & Gamble Company Detergent compositions containing polyhydroxy fatty acid amide surfactants and a clay softening system
US5194639A (en) * 1990-09-28 1993-03-16 The Procter & Gamble Company Preparation of polyhydroxy fatty acid amides in the presence of solvents
WO1993018125A1 (en) * 1992-03-10 1993-09-16 The Procter & Gamble Company Process for preparing polyhydroxy fatty acid amid compositions
US5254281A (en) * 1991-01-29 1993-10-19 The Procter & Gamble Company Soap bars with polyhydroxy fatty acid amides
US5288431A (en) * 1992-06-15 1994-02-22 The Procter & Gamble Company Liquid laundry detergent compositions with silicone antifoam agent
US5332528A (en) * 1990-09-28 1994-07-26 The Procter & Gamble Company Polyhydroxy fatty acid amides in soil release agent-containing detergent compositions
US5338487A (en) * 1990-09-28 1994-08-16 The Procter & Gamble Company Catalyzed process for glucamide detergents
US5338486A (en) * 1990-09-28 1994-08-16 The Procter & Gamble Company High catalyst process for glucamide detergents
US5354425A (en) * 1993-12-13 1994-10-11 The Procter & Gamble Company Tissue paper treated with polyhydroxy fatty acid amide softener systems that are biodegradable
US5380891A (en) * 1990-09-28 1995-01-10 The Procter & Gamble Company Phase transfer assisted process for glucamide detergents
US5449770A (en) * 1992-01-14 1995-09-12 The Procter & Gamble Company Process for making N-alkylamino polyols
US5454982A (en) * 1990-09-28 1995-10-03 The Procter & Gamble Company Detergent composition containing polyhydroxy fatty acid amide and alkyl ester sulfonate surfactants
US5625098A (en) * 1991-07-26 1997-04-29 The Procter & Gamble Company Process for preparing N-alkyl polyhydroxyalkyl amines in aqueous/hydroxy solvents
US5648329A (en) * 1992-10-13 1997-07-15 The Procter & Gamble Company High active premix based on polyhydroxy fatty acid amides for use in detergent compositions
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US6569826B1 (en) 1999-10-19 2003-05-27 The Procter & Gamble Company Radical scavenger
US6677294B2 (en) 2000-11-29 2004-01-13 The Procter & Gamble Company Cleansing compositions
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US8067625B2 (en) 2006-07-04 2011-11-29 Merck Patent Gesellschaft Mit Beschrankter Haftung Fluorosurfactants
US8192552B2 (en) 2002-02-11 2012-06-05 Rhodia Chimie Detergent composition comprising a block copolymer
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FR1186986A (en) 1959-09-04
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