GB804973A - Improvements relating to process for preparing dye developers - Google Patents

Improvements relating to process for preparing dye developers

Info

Publication number
GB804973A
GB804973A GB2850457A GB2850457A GB804973A GB 804973 A GB804973 A GB 804973A GB 2850457 A GB2850457 A GB 2850457A GB 2850457 A GB2850457 A GB 2850457A GB 804973 A GB804973 A GB 804973A
Authority
GB
United Kingdom
Prior art keywords
anthraquinone
amino
beta
bis
compound
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2850457A
Inventor
Elkan Rogers Blout
Myron Sydney Simon
Marilyn Ruby Cohler
Milton Green
Robert Burns Woodward
Richard Stancliffe Corley
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Polaroid Corp
Original Assignee
Polaroid Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Polaroid Corp filed Critical Polaroid Corp
Publication of GB804973A publication Critical patent/GB804973A/en
Expired legal-status Critical Current

Links

Classifications

    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03CPHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C8/00Diffusion transfer processes or agents therefor; Photosensitive materials for such processes
    • G03C8/02Photosensitive materials characterised by the image-forming section
    • G03C8/08Photosensitive materials characterised by the image-forming section the substances transferred by diffusion consisting of organic compounds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09BORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B1/00Dyes with anthracene nucleus not condensed with any other ring
    • C09B1/16Amino-anthraquinones
    • C09B1/20Preparation from starting materials already containing the anthracene nucleus
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09BORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B1/00Dyes with anthracene nucleus not condensed with any other ring
    • C09B1/16Amino-anthraquinones
    • C09B1/20Preparation from starting materials already containing the anthracene nucleus
    • C09B1/26Dyes with amino groups substituted by hydrocarbon radicals
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09BORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B43/00Preparation of azo dyes from other azo compounds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09BORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B43/00Preparation of azo dyes from other azo compounds
    • C09B43/12Preparation of azo dyes from other azo compounds by acylation of amino groups
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09BORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B43/00Preparation of azo dyes from other azo compounds
    • C09B43/12Preparation of azo dyes from other azo compounds by acylation of amino groups
    • C09B43/124Preparation of azo dyes from other azo compounds by acylation of amino groups with monocarboxylic acids, carbamic esters or halides, mono- isocyanates, or haloformic acid esters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09BORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B6/00Anthracene dyes not provided for above
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03CPHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C8/00Diffusion transfer processes or agents therefor; Photosensitive materials for such processes
    • G03C8/02Photosensitive materials characterised by the image-forming section
    • G03C8/08Photosensitive materials characterised by the image-forming section the substances transferred by diffusion consisting of organic compounds
    • G03C8/10Photosensitive materials characterised by the image-forming section the substances transferred by diffusion consisting of organic compounds of dyes or their precursors
    • G03C8/12Photosensitive materials characterised by the image-forming section the substances transferred by diffusion consisting of organic compounds of dyes or their precursors characterised by the releasing mechanism
    • G03C8/14Oxidation of the chromogenic substances
    • G03C8/16Oxidation of the chromogenic substances initially diffusible in alkaline environment
    • G03C8/18Dye developers
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03CPHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C8/00Diffusion transfer processes or agents therefor; Photosensitive materials for such processes
    • G03C8/42Structural details

Landscapes

  • Organic Chemistry (AREA)
  • Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Architecture (AREA)
  • Structural Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Color Printing (AREA)
  • Silver Salt Photography Or Processing Solution Therefor (AREA)
  • Coloring (AREA)
  • Developing Agents For Electrophotography (AREA)
  • Thermal Transfer Or Thermal Recording In General (AREA)

Abstract

The invention comprises dye developers of the formul : <FORM:0804973/IV (c)/1> wherein A represents an anthraquinone nucleus, D1 represents an organic radical containing an aryl nucleus substituted by at least two substitutuents selected from hydroxyl, amino, and substituted amino groups so that the resulting compound is capable of developing exposed silver halide, Q represents a hydrogen atom or an alkyl group, or, when the substituents on the aryl nucleus of D1 are hydroxyl groups, Q may also be acyl (which may be aliphatic or aromatic), Z is a bivalent organic radical containing at least one methylene group, m is a positive integer less than 5, and n is 2, 3, or 4, and each Y may be hydrogen, halogen, amino, alkyl, aryl, nitro, alkylamino, arylamino, aryloxy, alkoxy, hydroxyl, sulphonamido, carboxamido, carboxy, sulpho, <FORM:0804973/IV (c)/2> or <FORM:0804973/IV (c)/3> and a process of making a slightly wider class, including the above, and defined by the same formul , but where n may also be 1, by reacting in a manner depending upon the substituent to be replaced by an amine radical, a compound of the anthraquinone series containing at least one sulpho, halogen, nitro, hydroxy, alkoxy, or amino substituent with a primary amine of the formula D1-Z-NH2 or D1-NH2. When the substituent to be replaced is amino or hydroxy, the anthraquinone compound may be employed as leuco compound, the initial product being oxidized. In examples, leucoquinizarin is condensed with (1) aminohydroquinone monobenzoate, followed by hydrolysis; (2) 4-(beta-aminoethyl)-catechol, followed by benzoylation with benzoyl chloride. Products specifically claimed are 1,4-bis-(21,51-dihydroxyanilino) - anthraquinone, 1,5 - bis - (21,51 - dihydroxyanilino) - 4,8 - dihydroxy - anthraquinone, 1,4 - bis - [beta - (31,41 - dihydroxyphenyl) - ethylamino] - anthraquinone and its N-monobenzoyl derivative, 1,4-bis-[beta - (21,51 - dihydroxyphenyl) - ethylamino]-anthraquinone and its N-monobenzoyl derivative, 1 - chloro - 4 - [beta - (21,51 - dihydroxyphenyl) - ethylamino] - anthraquinone. Specification 804,974 is referred to.
GB2850457A 1954-03-09 1955-03-09 Improvements relating to process for preparing dye developers Expired GB804973A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US41507354A 1954-03-09 1954-03-09

Publications (1)

Publication Number Publication Date
GB804973A true GB804973A (en) 1958-11-26

Family

ID=23644267

Family Applications (6)

Application Number Title Priority Date Filing Date
GB690455A Expired GB804971A (en) 1954-03-09 1955-03-09 Improvements in or relating to photography
GB690555A Expired GB804972A (en) 1954-03-09 1955-03-09 Improvements in or relating to photography
GB3880457A Expired GB804976A (en) 1954-03-09 1955-03-09 Improvements relating to color photography
GB2850457A Expired GB804973A (en) 1954-03-09 1955-03-09 Improvements relating to process for preparing dye developers
GB2850557A Expired GB804974A (en) 1954-03-09 1955-03-09 Improvements relating to process for preparing dye developers
GB2850657A Expired GB804975A (en) 1954-03-09 1955-03-09 Improvements relating to process for preparing dye developers

Family Applications Before (3)

Application Number Title Priority Date Filing Date
GB690455A Expired GB804971A (en) 1954-03-09 1955-03-09 Improvements in or relating to photography
GB690555A Expired GB804972A (en) 1954-03-09 1955-03-09 Improvements in or relating to photography
GB3880457A Expired GB804976A (en) 1954-03-09 1955-03-09 Improvements relating to color photography

Family Applications After (2)

Application Number Title Priority Date Filing Date
GB2850557A Expired GB804974A (en) 1954-03-09 1955-03-09 Improvements relating to process for preparing dye developers
GB2850657A Expired GB804975A (en) 1954-03-09 1955-03-09 Improvements relating to process for preparing dye developers

Country Status (6)

Country Link
BE (1) BE554213A (en)
CH (7) CH363560A (en)
DE (5) DE1196075B (en)
FR (2) FR1178429A (en)
GB (6) GB804971A (en)
NL (2) NL103503C (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3135605A (en) * 1962-02-15 1964-06-02 Polaroid Corp Novel photographic products, processes, and compositions employing novel anthraquinone dye developers
US3230083A (en) * 1959-04-02 1966-01-18 Polaroid Corp Photographic processes and products
US4124393A (en) * 1974-10-08 1978-11-07 Fuji Photo Film Co., Ltd. Shifted anthraquinone dye developing agents

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3053656A (en) * 1954-07-01 1962-09-11 Polaroid Corp Photographic silver halide developers containing triazine rings
NL247650A (en) * 1959-01-26
NL132776C (en) * 1959-01-26
DE1422849B1 (en) * 1960-08-22 1970-07-09 Eastman Kodak Co Multilayer photographic recording material for the dye developer diffusion process
NL268156A (en) * 1960-08-22
DE1422850B1 (en) * 1960-08-22 1970-06-04 Eastman Kodak Co Dye developer diffusion process for the production of multicolored images
DE1157484B (en) * 1960-08-22 1963-11-14 Eastman Kodak Co Process for rendering colored positive images produced by diffusion transfer processes using a dye developer to lightfast
NL126854C (en) * 1960-08-22
BE610705A (en) * 1960-11-23
BE607371A (en) * 1960-11-25
BE614794A (en) * 1961-03-09
US3255002A (en) * 1961-03-09 1966-06-07 Polaroid Corp Color photographic process and product
US3239339A (en) * 1961-05-05 1966-03-08 Polaroid Corp Novel photographic products, compositions and processes
US3241963A (en) * 1962-02-19 1966-03-22 Polaroid Corp Novel photographic products, processes and compositions
US3265505A (en) * 1962-04-02 1966-08-09 Eastman Kodak Co Photographic products
US3077400A (en) * 1962-04-26 1963-02-12 Polaroid Corp Color diffusion transfer using gelatinsilver halide emulsions containing cellulose ethers
US3287133A (en) * 1963-03-01 1966-11-22 Eastman Kodak Co Photographic dye developer dispersions utilizing water-soluble sulfites
US3837852A (en) * 1972-10-02 1974-09-24 Gaf Corp Color diffusion transfer process utilizing azo coupling to actuate diffusion of color providing species

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2543691A (en) * 1946-06-07 1951-02-27 Gen Aniline & Film Corp Azo dyes as silver halide photographic developing agents
US2661293A (en) * 1946-10-08 1953-12-01 Polaroid Corp Process of producing a colored photographic image by means of exhaustion of developer
US2559643A (en) * 1948-02-19 1951-07-10 Polaroid Corp Photographic product and process
US2647649A (en) * 1951-06-28 1953-08-04 Onno L Maynard Trash moving fork for tractors

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3230083A (en) * 1959-04-02 1966-01-18 Polaroid Corp Photographic processes and products
US3135605A (en) * 1962-02-15 1964-06-02 Polaroid Corp Novel photographic products, processes, and compositions employing novel anthraquinone dye developers
US4124393A (en) * 1974-10-08 1978-11-07 Fuji Photo Film Co., Ltd. Shifted anthraquinone dye developing agents

Also Published As

Publication number Publication date
DE1172386B (en) 1964-06-18
NL103503C (en) 1963-01-15
NL103504C (en) 1963-01-15
DE1419842A1 (en) 1968-12-19
GB804972A (en) 1958-11-26
GB804971A (en) 1958-11-26
CH386444A (en) 1965-01-15
CH363560A (en) 1962-07-31
DE1066092B (en)
BE554213A (en) 1957-07-16
GB804976A (en) 1958-11-26
DE1035660B (en) 1958-08-07
CH358327A (en) 1961-11-15
CH356356A (en) 1961-08-15
GB804974A (en) 1958-11-26
DE1196075B (en) 1965-07-01
GB804975A (en) 1958-11-26
NL195422A (en) 1962-08-15
FR1178429A (en) 1959-05-11
CH386245A (en) 1964-12-31
FR1168292A (en) 1958-12-05
NL195421A (en) 1962-08-15
CH391931A (en) 1965-05-15
CH404832A (en) 1965-12-31

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