GB804952A - Improvements in textiles and sizing compositions - Google Patents

Improvements in textiles and sizing compositions

Info

Publication number
GB804952A
GB804952A GB16147/55A GB1614755A GB804952A GB 804952 A GB804952 A GB 804952A GB 16147/55 A GB16147/55 A GB 16147/55A GB 1614755 A GB1614755 A GB 1614755A GB 804952 A GB804952 A GB 804952A
Authority
GB
United Kingdom
Prior art keywords
methacrylic acid
starch
per cent
copolymer
alcohols
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB16147/55A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Rohm and Haas Co
Original Assignee
Rohm and Haas Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rohm and Haas Co filed Critical Rohm and Haas Co
Publication of GB804952A publication Critical patent/GB804952A/en
Expired legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
    • D06M15/267—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof of unsaturated carboxylic esters having amino or quaternary ammonium groups
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D06M15/03—Polysaccharides or derivatives thereof
    • D06M15/11—Starch or derivatives thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

A textile size comprises an aqueous solution or dispersion of an hydrophilic polymeric colloid and an ammonium or alkali metal salt of a copolymer consisting exclusively of 5 to 20 mol. per cent of acrylic or methacrylic acid with 80 to 95 mol. per cent of at least one ester consisting of the acrylates or methacrylates of aliphatic alcohols having from 1 to 18 carbon atoms, a sufficient proportion amounting to at least 50 mol. per cent of the total ester component of the copolymer being selected from acrylates of primary and secondary acylic alcohols having from 1 to 18 carbon atoms, methacrylates of primary and secondary acyclic alcohols having 6 to 18 carbon atoms, and mixtures thereof. Copolymers specified are ethyl acrylate/acrylic acid, ethyl acrylate/methacrylic acid, butyl acrylate/acrylic acid, propyl acrylate/methacryclic acid, ethyl acrylate/butyl acrylate/methacrylic acid, ethyl acrylate/butyl methacrylate/methacrylic acid, ethyl acrylate/lauryl acrylate/methacrylic acid, methyl methacrylate/octyl methacrylate/methacrylic acid and methyl methacrylate/lauryl methacrylate/methacrylic acid. The solution or dispersion of the copolymer contains hydrophilic colloids such as starch, chlorinated starch, starch acetate, ethylene oxide modified starch, dextrins, sodium carboxymethyl and carboxyethyl cellulose, methyl cellulose, hydroxyethyl cellulose, polyvinyl alcohol, partially hydrolysed polyvinyl acetate, gelatin, casein, gum arabic and tragacanth; and may also contain lubricants such as mineral oil, paraffin wax, animal and vegetable fats and oils, tallow, ethylene oxide modified long chain fatty acids alcohols or amines, turkey red oil, monostearin and ethylene oxide modified sorbitan monolaurate; and swelling agents such as diethylenetriamine, triethylenetetramine and tetraethylene pentamine.ALSO:A dry, sized textile comprising hydrophobic filamentary material carries thereon 1-20 per cent of a water-dispersible ammonium or alkali metal salt of a copolymer consisting exclusively of 5 to 20 mol. per cent of acrylic or methacrylic acid with 80 to 95 mol. per cent of at least one ester consisting of the acrylates or methacrylates of aliphatic alcohols having from 1 to 18 carbon atoms, a sufficient proportion amounting to at least 50 mol. per cent of the total ester component of the copolymer being selected from acrylates of primary and secondary acyclic alcohols having from 1 to 18 carbon atoms, methacrylates of primary and secondary acyclic alcohols having 6 to 18 carbon atoms and mixtures thereof, to impart to the copolymer a Knoop hardness of not over 7, and a hydrophilic polymeric colloid, the sizing being readily removable by common scouring operations. The hydrophobic filamentary material may be of nylon, polyethylene terephthalate, acrylonitrile polymers, vinyl and vinylidene chloride copolymers and cellulose acetate. The copolymer salt is applied to the textile in an aqueous solution or dispersion which contains a hydrophilic colloid such as starch, chlorinated starch, starch acetate, ethylene oxide modified starch, dextrins, sodium carboxymethyl cellulose and carboxyethyl cellulose, methyl cellulose, hydroxyethyl cellulose, polyvinyl alcohol, partially hydrolysed polyvinyl acetate, gelatin, casein, gum arabic and tragacanth; and may also contain lubricants such as mineral oil, paraffin wax, animal and vegetable fats and oils, tallow, ethylene oxide modified long-chain fatty acids, alcohols or amines, turkey red oil, monostearin and sorbitan monolaurate modified with ethylene oxide; and swelling agents such as diethylenetriamine, triethylenetetramine and tetraethylenepentamine.
GB16147/55A 1954-06-14 1955-06-06 Improvements in textiles and sizing compositions Expired GB804952A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US436687A US2807865A (en) 1954-06-14 1954-06-14 Sized textile and method of fabricating yarn into fabric

Publications (1)

Publication Number Publication Date
GB804952A true GB804952A (en) 1958-11-26

Family

ID=23733420

Family Applications (1)

Application Number Title Priority Date Filing Date
GB16147/55A Expired GB804952A (en) 1954-06-14 1955-06-06 Improvements in textiles and sizing compositions

Country Status (6)

Country Link
US (1) US2807865A (en)
CH (1) CH338425A (en)
DE (1) DE1042516B (en)
FR (1) FR1132921A (en)
GB (1) GB804952A (en)
NL (3) NL197897A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2137671A (en) * 1983-04-08 1984-10-10 Kao Corp Agent for improving processability of fibres

Families Citing this family (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2899341A (en) * 1959-08-11 Textile finishing process
US2969791A (en) * 1956-04-30 1961-01-31 Bofors Ab Rigid supporting dressing
US3036537A (en) * 1957-04-09 1962-05-29 Marcus I Breier Materials handling method
US3008215A (en) * 1958-01-31 1961-11-14 Du Pont Antistatic textile material
US2992943A (en) * 1959-06-19 1961-07-18 Eastman Kodak Co Sizing compositions for textile yarns
BE617263A (en) * 1961-05-04
US3236685A (en) * 1962-06-20 1966-02-22 Eastman Kodak Co Process for treating textile fibers and other shaped products with coatings
US3296023A (en) * 1964-03-11 1967-01-03 Rockland Bleach And Dye Works Fabric coated with light reflecting filler and acrylic polymer
US3364164A (en) * 1964-10-06 1968-01-16 Gulf Oil Corp Aqueous dispersion of hydrocarbonalkyl acrylate copolymer containing hydrophilic substituents, and a dispersing agent
GB1144316A (en) * 1965-08-13 1969-03-05 Dunlop Co Ltd Improved emulsions of alkali-soluble copolymers
US3386938A (en) * 1966-02-16 1968-06-04 Du Pont Acrylic wax abrasion resistant fiber finish composition
DE1621988C3 (en) * 1967-09-25 1974-07-11 Kalle Ag, 6202 Wiesbaden-Biebrich Transparent drawing material
US3634295A (en) * 1968-07-24 1972-01-11 Donald Thomas Dunlap Textile sizing composition
US3632422A (en) * 1969-12-04 1972-01-04 Burlington Industries Inc Textile fabric having soil release finish and method of making same
US3782898A (en) * 1971-08-12 1974-01-01 Pennwalt Corp Temporary soil release resins applied to fabrics in laundering
US4448839A (en) * 1981-10-16 1984-05-15 Rohm And Haas Company Method of sizing hydrophobic yarn
US4394128A (en) * 1980-10-31 1983-07-19 Rohm And Haas Company Method of sizing polyester yarn
US5082896A (en) * 1989-01-17 1992-01-21 Milliken Research Corporation Polymeric materials useful for sizing synthetic yarns to be used in water jet weaving
US5354815A (en) * 1992-06-05 1994-10-11 Comfort Technologies Polymers having enhanced hydrophilicity and thermal regulated properties and process of producing the same
TW282478B (en) * 1992-06-05 1996-08-01 Comfort Tech Inc
US5408012A (en) * 1993-05-27 1995-04-18 Comfort Technologies, Inc. Polymers having enhanced durable hydrophilicity and durable rewetting properties and process of producing the same

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2046885A (en) * 1934-12-29 1936-07-07 Du Pont Textile material
US2183226A (en) * 1936-01-17 1939-12-12 Ig Farbenindustrie Ag Sizing of textile materials
US2244704A (en) * 1937-08-30 1941-06-10 Du Pont Sizing of textile materials
US2244703A (en) * 1938-04-16 1941-06-10 Du Pont Water soluble salts of interpolymers containing methacrylic acid
US2244702A (en) * 1938-04-16 1941-06-10 Du Pont Methacrylate polymerization products
DE870688C (en) * 1941-08-26 1953-03-16 Roehm & Haas G M B H Method of finishing
US2651587A (en) * 1947-06-02 1953-09-08 Monsanto Chemicals Treatment of textile materials
US2653140A (en) * 1951-10-09 1953-09-22 Canadian Ind Textile finishing compositions

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2137671A (en) * 1983-04-08 1984-10-10 Kao Corp Agent for improving processability of fibres

Also Published As

Publication number Publication date
US2807865A (en) 1957-10-01
NL197987A (en)
FR1132921A (en) 1957-03-19
CH338425A (en) 1959-05-31
NL197897A (en)
NL90438C (en)
DE1042516B (en) 1958-11-06

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