GB794576A - Improved hydrodesulfurization process - Google Patents
Improved hydrodesulfurization processInfo
- Publication number
- GB794576A GB794576A GB15631/55A GB1563155A GB794576A GB 794576 A GB794576 A GB 794576A GB 15631/55 A GB15631/55 A GB 15631/55A GB 1563155 A GB1563155 A GB 1563155A GB 794576 A GB794576 A GB 794576A
- Authority
- GB
- United Kingdom
- Prior art keywords
- catalyst
- sulphur
- per cent
- presulphiding
- temperature
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 title abstract 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 13
- 239000003054 catalyst Substances 0.000 abstract 13
- 239000005864 Sulphur Substances 0.000 abstract 12
- 239000007789 gas Substances 0.000 abstract 7
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 4
- 239000001257 hydrogen Substances 0.000 abstract 4
- 229910052739 hydrogen Inorganic materials 0.000 abstract 4
- 239000003208 petroleum Substances 0.000 abstract 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 abstract 3
- KYYSIVCCYWZZLR-UHFFFAOYSA-N cobalt(2+);dioxido(dioxo)molybdenum Chemical compound [Co+2].[O-][Mo]([O-])(=O)=O KYYSIVCCYWZZLR-UHFFFAOYSA-N 0.000 abstract 3
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 abstract 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 2
- 238000009835 boiling Methods 0.000 abstract 2
- 239000010941 cobalt Substances 0.000 abstract 2
- 229910017052 cobalt Inorganic materials 0.000 abstract 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 abstract 2
- 238000010438 heat treatment Methods 0.000 abstract 2
- 239000000047 product Substances 0.000 abstract 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical class [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 abstract 1
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 abstract 1
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 abstract 1
- 239000007864 aqueous solution Substances 0.000 abstract 1
- 229910001570 bauxite Inorganic materials 0.000 abstract 1
- BTANRVKWQNVYAZ-UHFFFAOYSA-N butan-2-ol Chemical compound CCC(C)O BTANRVKWQNVYAZ-UHFFFAOYSA-N 0.000 abstract 1
- 238000004523 catalytic cracking Methods 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 238000004939 coking Methods 0.000 abstract 1
- 238000006356 dehydrogenation reaction Methods 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract 1
- 239000012263 liquid product Substances 0.000 abstract 1
- 229910000476 molybdenum oxide Inorganic materials 0.000 abstract 1
- PQQKPALAQIIWST-UHFFFAOYSA-N oxomolybdenum Chemical class [Mo]=O PQQKPALAQIIWST-UHFFFAOYSA-N 0.000 abstract 1
- 239000002245 particle Substances 0.000 abstract 1
- 230000008929 regeneration Effects 0.000 abstract 1
- 238000011069 regeneration method Methods 0.000 abstract 1
- 239000000741 silica gel Substances 0.000 abstract 1
- 229910002027 silica gel Inorganic materials 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
- 235000011121 sodium hydroxide Nutrition 0.000 abstract 1
- 239000003381 stabilizer Substances 0.000 abstract 1
- CXVCSRUYMINUSF-UHFFFAOYSA-N tetrathiomolybdate(2-) Chemical compound [S-][Mo]([S-])(=S)=S CXVCSRUYMINUSF-UHFFFAOYSA-N 0.000 abstract 1
- 238000004227 thermal cracking Methods 0.000 abstract 1
- 229960004418 trolamine Drugs 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
- C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
- C10G45/06—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
- C10G45/08—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof in combination with chromium, molybdenum, or tungsten metals, or compounds thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/16—Clays or other mineral silicates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/882—Molybdenum and cobalt
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
- B01J27/04—Sulfides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/20—Sulfiding
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Dispersion Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US438362A US2761817A (en) | 1954-06-21 | 1954-06-21 | Hydrodesulfurization process with precoditioned catalyst |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB794576A true GB794576A (en) | 1958-05-07 |
Family
ID=23740347
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB15631/55A Expired GB794576A (en) | 1954-06-21 | 1955-05-31 | Improved hydrodesulfurization process |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US2761817A (enrdf_load_stackoverflow) |
| DE (1) | DE1019786B (enrdf_load_stackoverflow) |
| FR (1) | FR1142978A (enrdf_load_stackoverflow) |
| GB (1) | GB794576A (enrdf_load_stackoverflow) |
| NL (2) | NL95620C (enrdf_load_stackoverflow) |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2918427A (en) * | 1954-10-11 | 1959-12-22 | Exxon Research Engineering Co | Hydrodesulfurization process employing a presulfided platinum catalyst |
| US2900332A (en) * | 1955-04-06 | 1959-08-18 | British Petroleum Co | Hydrocatalytic desulfurization of gas oil |
| US2921022A (en) * | 1956-05-18 | 1960-01-12 | Marion H Gwynn | Three stage hydrodesulfurization process employing nickel catalyst |
| US2916445A (en) * | 1956-09-18 | 1959-12-08 | Exxon Research Engineering Co | Hydrotreating hydrocarbon solvents to improve odor and color |
| US2866750A (en) * | 1956-11-05 | 1958-12-30 | Exxon Research Engineering Co | Pretreatment of cobalt molybdate-on-alumina catalyst |
| BE564267A (enrdf_load_stackoverflow) * | 1957-01-29 | |||
| US2946738A (en) * | 1957-07-01 | 1960-07-26 | Phillips Petroleum Co | Hydrocracking a gas oil with a presulfided catalyst consisting of oxides of vanadium, cobalt and molybdenum on gamma alumina |
| US2953519A (en) * | 1957-12-16 | 1960-09-20 | Gulf Research Development Co | Start up procedure for catalytic hydrogen treatment of hydrocarbons |
| NL242628A (enrdf_load_stackoverflow) * | 1958-08-27 | |||
| US3113983A (en) * | 1959-04-07 | 1963-12-10 | Air Prod & Chem | Selective hydrogenation of diolefins |
| NL250492A (enrdf_load_stackoverflow) * | 1959-04-14 | |||
| US3000816A (en) * | 1959-06-24 | 1961-09-19 | Exxon Research Engineering Co | Desulfurization with a modified molybdenum disulfide catalyst |
| DE1289226B (de) * | 1960-08-24 | 1969-02-13 | Hydrocarbon Research Inc | Verfahren zur katalytischen Behandlung von Kohlenwasserstoffoelen |
| US3194897A (en) * | 1962-03-21 | 1965-07-13 | Telex Corp | Semi-conductor hearing aid amplifier |
| US3642613A (en) * | 1970-06-19 | 1972-02-15 | Universal Oil Prod Co | Black oil conversion process startup procedure |
| US6893554B2 (en) * | 2002-03-13 | 2005-05-17 | Exxonmobil Research And Engineering Company | Naphtha desulfurization with selectively suppressed hydrogenation |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2143078A (en) * | 1936-11-23 | 1939-01-10 | Standard Oil Co | Catalytic desulphurization of petroleum |
| US2337358A (en) * | 1939-10-20 | 1943-12-21 | Albert C Travis | Treatment of hydrocarbons |
| US2608521A (en) * | 1948-01-06 | 1952-08-26 | Shell Dev | Process for refining carbonaceous material |
| US2620362A (en) * | 1948-07-07 | 1952-12-02 | Du Pont | Method of catalytically removing sulfur |
| US2512570A (en) * | 1948-07-20 | 1950-06-20 | Shell Dev | Desulfurization of hydrocarbon oils |
| US2604438A (en) * | 1949-05-23 | 1952-07-22 | Shell Dev | Catalytic dehydrogenation of hydrocarbon oils |
| NL71294C (enrdf_load_stackoverflow) * | 1949-09-22 | |||
| US2647857A (en) * | 1949-10-04 | 1953-08-04 | Gulf Research Development Co | Hydrodesulfurization process |
| DE933648C (de) * | 1953-06-27 | 1955-09-29 | Basf Ag | Verfahren zur Herstellung von feststoff- und asphaltfreiem und schwefelarmem Schweroel |
-
0
- NL NL198189D patent/NL198189A/xx unknown
- NL NL95620D patent/NL95620C/xx active
-
1954
- 1954-06-21 US US438362A patent/US2761817A/en not_active Expired - Lifetime
-
1955
- 1955-05-31 GB GB15631/55A patent/GB794576A/en not_active Expired
- 1955-06-08 FR FR1142978D patent/FR1142978A/fr not_active Expired
- 1955-06-10 DE DEE10840A patent/DE1019786B/de active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| NL95620C (enrdf_load_stackoverflow) | |
| NL198189A (enrdf_load_stackoverflow) | |
| DE1019786B (de) | 1957-11-21 |
| FR1142978A (fr) | 1957-09-25 |
| US2761817A (en) | 1956-09-04 |
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