GB782816A - Process for the manufacture of para-tertiarybutylbenzoic acid - Google Patents

Process for the manufacture of para-tertiarybutylbenzoic acid

Info

Publication number
GB782816A
GB782816A GB1435754A GB1435754A GB782816A GB 782816 A GB782816 A GB 782816A GB 1435754 A GB1435754 A GB 1435754A GB 1435754 A GB1435754 A GB 1435754A GB 782816 A GB782816 A GB 782816A
Authority
GB
United Kingdom
Prior art keywords
para
acid
manufacture
tertiary
nitric acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1435754A
Inventor
Cyril Gardner
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Imperial Chemical Industries Ltd
Original Assignee
Imperial Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Imperial Chemical Industries Ltd filed Critical Imperial Chemical Industries Ltd
Priority to GB1435754A priority Critical patent/GB782816A/en
Publication of GB782816A publication Critical patent/GB782816A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/27Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with oxides of nitrogen or nitrogen-containing mineral acids
    • C07C51/275Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with oxides of nitrogen or nitrogen-containing mineral acids of hydrocarbyl groups

Abstract

A process for the manufacture of purified tertiarybutyl benzoic acid comprises oxidizing para-tertiary butyl toluene with nitric acid having an initial strength between 2 and 50 per cent by weight, at a pressure of from 100 to 600 p.s.i. and a temperature of from 50 DEG to 250 DEG C. In the example, para-tertiary-butyl benzoic acid containing a small amount of terephthalic acid is obtained by oxidizing para-tertiary-butyltoluene at elevated pressure and temperature with dilute nitric acid. The starting material may be synthesized from toluene and tertiarybutylchloride or isobutane and the product may be converted to terephthalic acid by oxidation, e.g. with nitric acid. Specifications 655,074, 662,139, 662,229, 758,676, and 782,817 are referred to.
GB1435754A 1954-05-17 1954-05-17 Process for the manufacture of para-tertiarybutylbenzoic acid Expired GB782816A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB1435754A GB782816A (en) 1954-05-17 1954-05-17 Process for the manufacture of para-tertiarybutylbenzoic acid

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB1435754A GB782816A (en) 1954-05-17 1954-05-17 Process for the manufacture of para-tertiarybutylbenzoic acid

Publications (1)

Publication Number Publication Date
GB782816A true GB782816A (en) 1957-09-11

Family

ID=10039733

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1435754A Expired GB782816A (en) 1954-05-17 1954-05-17 Process for the manufacture of para-tertiarybutylbenzoic acid

Country Status (1)

Country Link
GB (1) GB782816A (en)

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