GB771557A - A process for the reduction of iron catalysts for the hydrogenation of carbon monoxide - Google Patents
A process for the reduction of iron catalysts for the hydrogenation of carbon monoxideInfo
- Publication number
- GB771557A GB771557A GB2015551A GB2015551A GB771557A GB 771557 A GB771557 A GB 771557A GB 2015551 A GB2015551 A GB 2015551A GB 2015551 A GB2015551 A GB 2015551A GB 771557 A GB771557 A GB 771557A
- Authority
- GB
- United Kingdom
- Prior art keywords
- catalyst
- reduction
- carbon monoxide
- per cent
- gas
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/16—Reducing
Abstract
Iron catalysts prior to their use in the hydrogenation of carbon monoxide are reduced by passing carbon monoxide or a gas containing it over the catalyst at a space velocity greater than 300 and at a temperature within the range 180 DEG to 600 DEG C., the gas being passed over the catalyst at substantially constant velocity from the beginning of the process of reduction. The space velocity is preferably greater than a 1000 volumes per volume per hour and the gas and catalyst are preferably separately heated to the reduction temperature, desirably between 200 DEG and 400 DEG C. The reduced catalyst may subsequently be treated with hydrogen at 250 DEG to 400 DEG C. The reduction may be effected with impure carbon monoxide containing carbon dioxide, or with a synthesis gas which at the high space velocities employed is only slightly converted. The reduction may be carried out in thin layers having a thickness less than 1 m. According to an example, a carrier free iron catalyst containing 0.2 per cent by weight of copper, both the iron and copper being in the form of their carbonates obtained by coprecipitation from a solution of the nitrates, and 0.25 per cent of potassium carbonate was reduced in a synthesis reactor with water gas containing 6 per cent carbon dioxide, 38 per cent carbon monoxide, 47 per cent hydrogen and the rest nitrogen at a temperature of 290 DEG to 310 DEG C. at a space velocity of 3000 volumes per volume per hour. The so-reduced catalyst was used in synthesis with water gas at a gauge pressure of less than 10 atmospheres at 190 DEG to 215 DEG C.ALSO:Iron catalysts prior to their use in the hydrogenation of carbon monoxide are reduced by passing carbon monoxide or a gas containing it over the catalyst at a space velocity greater than 300 and at a temperature within the range 180 to 600 DEG C. the gas being passed over the catalyst at substantially constant velocity from the beginning of the process of reduction. The space velocity is preferably greater than a 1000 volumes per volume per hour and the gas and catalyst are preferably separately heated to the reduction temperature, desirably between 200 and 400 DEG C. The reduced catalyst may subsequently be treated with hydrogen at 250 to 400 DEG C. The reduction may be effected with impure carbon monoxide containing carbon dioxide, or with a synthesis gas which at the high space velocities employed is only slightly converted. The reduction may be carried out in thin layers having a thickness less than 1 m. According to an example a carrier free iron catalyst containing 0.2 per cent by weight of copper, both the iron and copper being in the form of their carbonates obtained by co-preciptation from a solution of the nitrates, and 0.25 per cent of potassium carbonate was reduced in a synthesis reactor with water gas containing 6 per cent carbon dioxide, 38 per cent carbon monoxide, 47 per cent hydrogen and the rest nitrogen at a temperature of 290 to 310 DEG C. at a space velocity of 3000 volumes per volume per hour. The so reduced catalyst was used in synthesis with water gas at a gauge pressure of less than 10 atmospheres at 190 to 215 DEG C.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB2015551A GB771557A (en) | 1951-08-27 | 1951-08-27 | A process for the reduction of iron catalysts for the hydrogenation of carbon monoxide |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB2015551A GB771557A (en) | 1951-08-27 | 1951-08-27 | A process for the reduction of iron catalysts for the hydrogenation of carbon monoxide |
Publications (1)
Publication Number | Publication Date |
---|---|
GB771557A true GB771557A (en) | 1957-04-03 |
Family
ID=10141286
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB2015551A Expired GB771557A (en) | 1951-08-27 | 1951-08-27 | A process for the reduction of iron catalysts for the hydrogenation of carbon monoxide |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB771557A (en) |
-
1951
- 1951-08-27 GB GB2015551A patent/GB771557A/en not_active Expired
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