GB780577A - Process for the catalytic hydrogenation of carbon monoxide - Google Patents

Process for the catalytic hydrogenation of carbon monoxide

Info

Publication number
GB780577A
GB780577A GB3390/54A GB339054A GB780577A GB 780577 A GB780577 A GB 780577A GB 3390/54 A GB3390/54 A GB 3390/54A GB 339054 A GB339054 A GB 339054A GB 780577 A GB780577 A GB 780577A
Authority
GB
United Kingdom
Prior art keywords
parts
per cent
catalysts
gas
carbon monoxide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3390/54A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
RURRCHEMIE AG
Lurgi Gesellschaft fuer Waermetechnik mbH
Original Assignee
RURRCHEMIE AG
Lurgi Gesellschaft fuer Waermetechnik mbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by RURRCHEMIE AG, Lurgi Gesellschaft fuer Waermetechnik mbH filed Critical RURRCHEMIE AG
Publication of GB780577A publication Critical patent/GB780577A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C07C1/06Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen in the presence of organic compounds, e.g. hydrocarbons

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

A process for the catalytic hydrogenation of carbon monoxide with recycling of a portion of the exit gases from the reactor, comprises dividing the recirculated gas into two streams, recycling one stream to the reactor without removing its content of carbon dioxide, and removing the carbon dioxide as extensively as possible from the other stream and combining it with the incoming fresh synthesis gas. The process may employ fixed bed catalysts, fluidized catalysts, catalysts suspended in liquids, or catalysts which are moved continuously downwardly through the synthesis zone. The hydrogen to carbon monoxide may be from 0.7 to 3.0 to 1, and the temperature may lie between 170 DEG and 350 DEG C. and the gas pressure may be from 5-100 kgs./sq. cm. In an example a catalyst was used consisting of 100 parts of Fe, 25 parts of Cu, 5 parts of K2O and 25 parts of SiO2 and the gas entering the reactor comprised 24.5 per cent Co and 48.9 per cent of H2. The recycle gas was divided, one part having a CO2 content of 12 per cent and the other part having this content reduced to 0.1 per cent.
GB3390/54A 1953-03-05 1954-02-04 Process for the catalytic hydrogenation of carbon monoxide Expired GB780577A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE780577X 1953-03-05

Publications (1)

Publication Number Publication Date
GB780577A true GB780577A (en) 1957-08-07

Family

ID=6688980

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3390/54A Expired GB780577A (en) 1953-03-05 1954-02-04 Process for the catalytic hydrogenation of carbon monoxide

Country Status (1)

Country Link
GB (1) GB780577A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4279830A (en) * 1977-08-22 1981-07-21 Mobil Oil Corporation Conversion of synthesis gas to hydrocarbon mixtures utilizing dual reactors
WO2002038699A1 (en) * 2000-11-10 2002-05-16 Sasol Technology (Proprietary) Limited Production of liquid hydrocarbon products
WO2003018517A2 (en) * 2001-08-24 2003-03-06 Shell Internationale Research Maatschappij B.V. Process for the preparation of hydrocarbons

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4279830A (en) * 1977-08-22 1981-07-21 Mobil Oil Corporation Conversion of synthesis gas to hydrocarbon mixtures utilizing dual reactors
WO2002038699A1 (en) * 2000-11-10 2002-05-16 Sasol Technology (Proprietary) Limited Production of liquid hydrocarbon products
US6784212B2 (en) 2000-11-10 2004-08-31 Sasol Technology (Proprietary) Limited Production of liquid hydrocarbon products
WO2003018517A2 (en) * 2001-08-24 2003-03-06 Shell Internationale Research Maatschappij B.V. Process for the preparation of hydrocarbons
WO2003018517A3 (en) * 2001-08-24 2003-12-24 Shell Int Research Process for the preparation of hydrocarbons

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