GB764752A - Improved residual fuel - Google Patents

Improved residual fuel

Info

Publication number
GB764752A
GB764752A GB828755A GB828755A GB764752A GB 764752 A GB764752 A GB 764752A GB 828755 A GB828755 A GB 828755A GB 828755 A GB828755 A GB 828755A GB 764752 A GB764752 A GB 764752A
Authority
GB
United Kingdom
Prior art keywords
acid
oil
complex
residual
molecular weight
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB828755A
Inventor
Arnold Jesse Morway
Raymond William Walker
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Technology and Engineering Co
Original Assignee
Exxon Research and Engineering Co
Esso Research and Engineering Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US387528A external-priority patent/US2832677A/en
Application filed by Exxon Research and Engineering Co, Esso Research and Engineering Co filed Critical Exxon Research and Engineering Co
Priority to GB828755A priority Critical patent/GB764752A/en
Publication of GB764752A publication Critical patent/GB764752A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/188—Carboxylic acids; metal salts thereof
    • C10L1/1881—Carboxylic acids; metal salts thereof carboxylic group attached to an aliphatic carbon atom

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Liquid Carbonaceous Fuels (AREA)

Abstract

A vanadium-containing residual fuel oil has dissolved therein a complex calcium borium or magnesium soap of an acid having 1 to 5 carbon atoms in the molecule and an acid having 16 to 22 carbon atoms in the molecule. The lower molecular weight acid may be acetic, formic, proprionic, crotonic or acrylic acid, and the higher molecular weight acid may be stearic acid, oleic acid or hydrogenated fish oil acids. The complex is added to the residual oil in amounts to give 0.02 to 0.5 weight per cent of calcium, borium or magnesium metal based on the residual oil, or in an amount sufficient to secure an atomic ratio of calcium, borium or magnesium to vanadium in the oil of 1/1 to 5/1 . The complex soap may comprise 10 to 80 per cent by weight of the lower molecular weight acid, and 90 to 20 per cent by weight of the higher molecular weight acid. The complex soaps preferably formed in the presence of a mineral oil, which may be some of the residual oil, to form a composition which is then added to the residual oil to obtain the fuel composition. In an example a complex soap is formed from acetic and stearic or hydrogenated fish oil acids, with calcium hydroxide, in mineral oil, and added to a residual fuel oil.
GB828755A 1953-10-21 1955-03-22 Improved residual fuel Expired GB764752A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB828755A GB764752A (en) 1953-10-21 1955-03-22 Improved residual fuel

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US387528A US2832677A (en) 1953-10-21 1953-10-21 Residual fuel
GB828755A GB764752A (en) 1953-10-21 1955-03-22 Improved residual fuel

Publications (1)

Publication Number Publication Date
GB764752A true GB764752A (en) 1957-01-02

Family

ID=26242080

Family Applications (1)

Application Number Title Priority Date Filing Date
GB828755A Expired GB764752A (en) 1953-10-21 1955-03-22 Improved residual fuel

Country Status (1)

Country Link
GB (1) GB764752A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3994699A (en) * 1972-08-17 1976-11-30 The Perolin Company, Inc. Fuel compositions useful for gas turbines and process for the combustion of such fuel compositions
EP2236585A1 (en) * 2009-04-02 2010-10-06 GE Energy Products France SNC Method of operating a thermal device and use of such a method to inhibit vanadium corrosion
WO2012047839A1 (en) * 2010-10-04 2012-04-12 General Electric Company Method of operating a combusion installation and use of such a method for inhibiting vanadium corrosion
US9556393B2 (en) 2013-04-23 2017-01-31 General Electric Company Methods of operating a gas turbine to inhibit vanadium corrosion
US9976488B2 (en) 2014-04-22 2018-05-22 Ge Energy Products France Snc Method of operating a gas turbine engine burning vanadium-contaminated liquid fuel

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3994699A (en) * 1972-08-17 1976-11-30 The Perolin Company, Inc. Fuel compositions useful for gas turbines and process for the combustion of such fuel compositions
EP2236585A1 (en) * 2009-04-02 2010-10-06 GE Energy Products France SNC Method of operating a thermal device and use of such a method to inhibit vanadium corrosion
US8282693B2 (en) 2009-04-02 2012-10-09 Ge Energy Products France Snc Method of operating a thermal installation and use of such a method for inhibiting vanadium corrosion
WO2012047839A1 (en) * 2010-10-04 2012-04-12 General Electric Company Method of operating a combusion installation and use of such a method for inhibiting vanadium corrosion
CN103140575A (en) * 2010-10-04 2013-06-05 通用电气公司 Method of operating a combusion installation and use of such a method for inhibiting vanadium corrosion
US9556393B2 (en) 2013-04-23 2017-01-31 General Electric Company Methods of operating a gas turbine to inhibit vanadium corrosion
US9976488B2 (en) 2014-04-22 2018-05-22 Ge Energy Products France Snc Method of operating a gas turbine engine burning vanadium-contaminated liquid fuel

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