GB763010A - Stabilized organic titanium and zirconium compounds - Google Patents
Stabilized organic titanium and zirconium compoundsInfo
- Publication number
- GB763010A GB763010A GB13463/54A GB1346354A GB763010A GB 763010 A GB763010 A GB 763010A GB 13463/54 A GB13463/54 A GB 13463/54A GB 1346354 A GB1346354 A GB 1346354A GB 763010 A GB763010 A GB 763010A
- Authority
- GB
- United Kingdom
- Prior art keywords
- acid
- amino
- alcohol
- alkyl
- titanic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 title abstract 2
- 229910052719 titanium Inorganic materials 0.000 title 1
- 239000010936 titanium Substances 0.000 title 1
- 150000003755 zirconium compounds Chemical class 0.000 title 1
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 abstract 6
- 239000002253 acid Substances 0.000 abstract 5
- 150000001414 amino alcohols Chemical class 0.000 abstract 5
- RGHNJXZEOKUKBD-SQOUGZDYSA-N D-gluconic acid Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O RGHNJXZEOKUKBD-SQOUGZDYSA-N 0.000 abstract 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 4
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical group C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 4
- 239000005977 Ethylene Substances 0.000 abstract 4
- 238000007792 addition Methods 0.000 abstract 3
- HEBKCHPVOIAQTA-UHFFFAOYSA-N meso ribitol Natural products OCC(O)C(O)C(O)CO HEBKCHPVOIAQTA-UHFFFAOYSA-N 0.000 abstract 3
- 230000000087 stabilizing effect Effects 0.000 abstract 3
- YAXKTBLXMTYWDQ-UHFFFAOYSA-N 1,2,3-butanetriol Chemical compound CC(O)C(O)CO YAXKTBLXMTYWDQ-UHFFFAOYSA-N 0.000 abstract 2
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 abstract 2
- FBPFZTCFMRRESA-KVTDHHQDSA-N D-Mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 abstract 2
- HEBKCHPVOIAQTA-QWWZWVQMSA-N D-arabinitol Chemical compound OC[C@@H](O)C(O)[C@H](O)CO HEBKCHPVOIAQTA-QWWZWVQMSA-N 0.000 abstract 2
- RGHNJXZEOKUKBD-MGCNEYSASA-N D-galactonic acid Chemical compound OC[C@@H](O)[C@H](O)[C@H](O)[C@@H](O)C(O)=O RGHNJXZEOKUKBD-MGCNEYSASA-N 0.000 abstract 2
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 abstract 2
- RGHNJXZEOKUKBD-UHFFFAOYSA-N D-gluconic acid Natural products OCC(O)C(O)C(O)C(O)C(O)=O RGHNJXZEOKUKBD-UHFFFAOYSA-N 0.000 abstract 2
- WQZGKKKJIJFFOK-QTVWNMPRSA-N D-mannopyranose Chemical compound OC[C@H]1OC(O)[C@@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-QTVWNMPRSA-N 0.000 abstract 2
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 abstract 2
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 abstract 2
- 229930195725 Mannitol Natural products 0.000 abstract 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 abstract 2
- 125000002723 alicyclic group Chemical group 0.000 abstract 2
- 125000001931 aliphatic group Chemical group 0.000 abstract 2
- 125000000217 alkyl group Chemical group 0.000 abstract 2
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 abstract 2
- 125000004432 carbon atom Chemical group C* 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- LVTYICIALWPMFW-UHFFFAOYSA-N diisopropanolamine Chemical compound CC(O)CNCC(C)O LVTYICIALWPMFW-UHFFFAOYSA-N 0.000 abstract 2
- 150000002148 esters Chemical class 0.000 abstract 2
- FBPFZTCFMRRESA-GUCUJZIJSA-N galactitol Chemical compound OC[C@H](O)[C@@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-GUCUJZIJSA-N 0.000 abstract 2
- 235000012208 gluconic acid Nutrition 0.000 abstract 2
- 239000000174 gluconic acid Substances 0.000 abstract 2
- 239000008103 glucose Substances 0.000 abstract 2
- 150000002430 hydrocarbons Chemical group 0.000 abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 abstract 2
- 239000001257 hydrogen Substances 0.000 abstract 2
- 150000001261 hydroxy acids Chemical class 0.000 abstract 2
- 239000000594 mannitol Substances 0.000 abstract 2
- 235000010355 mannitol Nutrition 0.000 abstract 2
- 239000000243 solution Substances 0.000 abstract 2
- 239000000600 sorbitol Substances 0.000 abstract 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- AVXURJPOCDRRFD-UHFFFAOYSA-N Hydroxylamine Chemical compound ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 abstract 1
- 239000000654 additive Substances 0.000 abstract 1
- 230000000996 additive effect Effects 0.000 abstract 1
- 125000005907 alkyl ester group Chemical group 0.000 abstract 1
- 239000007864 aqueous solution Substances 0.000 abstract 1
- 150000002431 hydrogen Chemical class 0.000 abstract 1
- 239000011541 reaction mixture Substances 0.000 abstract 1
- 230000001105 regulatory effect Effects 0.000 abstract 1
- HEBKCHPVOIAQTA-ZXFHETKHSA-N ribitol Chemical compound OC[C@H](O)[C@H](O)[C@H](O)CO HEBKCHPVOIAQTA-ZXFHETKHSA-N 0.000 abstract 1
- 239000004753 textile Substances 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/003—Compounds containing elements of Groups 4 or 14 of the Periodic Table without C-Metal linkages
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Solutions of amino-alcohol esters of titanic or zirconic acid are stabilized by the addition of a polyhydroxy aliphatic or alicyclic alcohol or a monobasic hydroxy acid. The titanic or zirconic acid ester may be of an amino alcohol having the formula HORN(R1)(R11) where R is ethylene or an alkyl-substituted ethylene and R1 and R11 are hydrogen, an alkyl hydrocarbon group containing not more than 3 carbon atoms or a b -amino or b -hydroxyalkyl radical, such as triethanolamine, di-isopropanolamine, or b -amino-ethyl-ethanolamine. The stabilizing additive may be sorbitol, mannitol, dulcitol, glucose, mannose, gluconic acid, galactonic acid, glycollic acid, glycerol, 1,2,3-butane-triol, arabitol or adonitrol. The additions may be regulated to give stability over a pH range from 2.5 to 14. The stabilizing compound may be added to the undissolved aminoalcohol titanate or zirconate, or to an aqueous solution of the latter which is at a stable pH, or to the reaction mixture of an amino alcohol and an alkyl ester of orthotitanic or orthozirconic acid, the alcohol liberated during the reaction being evaporated and the evaporated alcohol being replaced with water.ALSO:Solutions of amino-alcohol esters of titanic or zirconic acid for treating textile fibres are stabilized by the addition of a polyhydroxy aliphatic or alicyclic alcohol or a monobasic hydroxy acid. The stabilizing compound may be sorbitol, mannitol, dulcitol, glucose, mannose, gluconic acid, galactonic acid, glycollic acid, glycerol, 1, 2, 3 butane-triol, arabitol or adonitol. The amino-alcohols from which the titanic or zirconic acid esters are derived may have the formula HORN (R1)(R11) where R is ethylene or alkyl-substituted ethylene and R1 and R11 are hydrogen or an alkyl hydrocarbon group containing not more than 3 carbon atoms or a b -amino-alkyl or b -hydroxy-alkyl radical, such as triethanolamine, di-isopropanolamine or b -aminoethyl ethanolamine.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US763010XA | 1953-05-14 | 1953-05-14 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB763010A true GB763010A (en) | 1956-12-05 |
Family
ID=22131123
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB13463/54A Expired GB763010A (en) | 1953-05-14 | 1954-05-07 | Stabilized organic titanium and zirconium compounds |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB763010A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2039673A5 (en) * | 1969-03-18 | 1971-01-15 | British Titan Products |
-
1954
- 1954-05-07 GB GB13463/54A patent/GB763010A/en not_active Expired
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2039673A5 (en) * | 1969-03-18 | 1971-01-15 | British Titan Products |
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