GB738170A - New sulphur-containing compounds - Google Patents
New sulphur-containing compoundsInfo
- Publication number
- GB738170A GB738170A GB2629152A GB2629152A GB738170A GB 738170 A GB738170 A GB 738170A GB 2629152 A GB2629152 A GB 2629152A GB 2629152 A GB2629152 A GB 2629152A GB 738170 A GB738170 A GB 738170A
- Authority
- GB
- United Kingdom
- Prior art keywords
- compound
- agent
- phenyl radical
- substituted
- formula
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C323/00—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
The invention comprises compounds of formula <FORM:0738170/IV (b)/1> where the phenyl radical X is substituted with one or more chlorine atoms, and the phenyl radical Y is substituted with one or more nitro groups. The compound is prepared by reacting a substituted benzyl chloride of formula <FORM:0738170/IV (b)/2> with a substituted thiol of formula <FORM:0738170/IV (b)/3> in the presence of sodium ethoxide. A specific compound is p-chlorophenyl p-nitrobenzyl sulphide, obtained by reacting p-chlorophenylthiol dissolved in a solution of sodium ethoxide in ethanol, with p-nitrobenzyl chloride dissolved in ethanol.ALSO:Acaricidal preparations comprise compounds having the general formula <FORM:0738170/VI/1> where the phenyl radical X has one or more chlorine atom substituents, and the phenyl radical Y has one or more nitro group substituents. A specific compound described is p-chlorophenyl p-nitrobenzyl sulphide. The preparation may comprise the compound with a dispersing agent and/or a suspending agent in aqueous medium; or may comprise the compound with dispersing and/or suspending agents, with or without a water-miscible organic solvent, such as acetone, such that a dispersion is formed when the mixture is added to water. Dispersions may also be obtained by mixing an aqueous dispersion or dispersible powder containing the compound, with an emulsion comprising a paraffin oil, such as white oil, and an emulsifying agent in aqueous medium. Emulsions may comprise the compound in combination with an emulsifying agent and an organic solvent, such as xylene, and may also contain a wetting agent. Compositions may be prepared containing the compound and an emulsifying agent with or without a wetting agent, which form an emulsion when mixed with water. The compound may be mixed with a composition to form a smoke when ignited, or with a diluent to form a dust. The compound may be dissolved in a mixture of an oil and a solvent such as cyclohexanone or acetone, to form mists and aerosols; such compositions may comprise a propellant such as "Freon" (Registered Trade Mark) being a mixture of chloro-fluoro derivatives of methane and ethane. Examples describe p-chlorophenyl-p-nitrobenzene sulphide with Insem 108 (a non-ionic emulsifying agent which is an oleic acid ester of a glycol) and benzene; with "Belloid T.D." (Registered Trade Mark) (a condensate of formaldehyde and an alkyl aryl sulphonate), kaolin and anhydrous magnesium sulphate.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB2629152A GB738170A (en) | 1952-10-20 | 1952-10-20 | New sulphur-containing compounds |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB2629152A GB738170A (en) | 1952-10-20 | 1952-10-20 | New sulphur-containing compounds |
Publications (1)
Publication Number | Publication Date |
---|---|
GB738170A true GB738170A (en) | 1955-10-12 |
Family
ID=10241319
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB2629152A Expired GB738170A (en) | 1952-10-20 | 1952-10-20 | New sulphur-containing compounds |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB738170A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1056122B (en) * | 1957-03-01 | 1959-04-30 | Bayer Ag | Process for the production of insecticidally active thiomethylalen |
-
1952
- 1952-10-20 GB GB2629152A patent/GB738170A/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1056122B (en) * | 1957-03-01 | 1959-04-30 | Bayer Ag | Process for the production of insecticidally active thiomethylalen |
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