GB724457A - Process for the production of finely divided silica and alkali metal formate - Google Patents

Process for the production of finely divided silica and alkali metal formate

Info

Publication number
GB724457A
GB724457A GB7937/53A GB793753A GB724457A GB 724457 A GB724457 A GB 724457A GB 7937/53 A GB7937/53 A GB 7937/53A GB 793753 A GB793753 A GB 793753A GB 724457 A GB724457 A GB 724457A
Authority
GB
United Kingdom
Prior art keywords
alkali metal
solution
silica
metal formate
finely divided
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB7937/53A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Evonik Operations GmbH
Original Assignee
Degussa GmbH
Deutsche Gold und Silber Scheideanstalt
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Degussa GmbH, Deutsche Gold und Silber Scheideanstalt filed Critical Degussa GmbH
Publication of GB724457A publication Critical patent/GB724457A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00Silicon; Compounds thereof
    • C01B33/113Silicon oxides; Hydrates thereof
    • C01B33/12Silica; Hydrates thereof, e.g. lepidoic silicic acid
    • C01B33/18Preparation of finely divided silica neither in sol nor in gel form; After-treatment thereof
    • C01B33/187Preparation of finely divided silica neither in sol nor in gel form; After-treatment thereof by acidic treatment of silicates
    • C01B33/193Preparation of finely divided silica neither in sol nor in gel form; After-treatment thereof by acidic treatment of silicates of aqueous solutions of silicates
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/10Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00Physical properties of inorganic compounds
    • C01P2006/11Powder tap density
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00Physical properties of inorganic compounds
    • C01P2006/22Rheological behaviour as dispersion, e.g. viscosity, sedimentation stability
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00Physical properties of inorganic compounds
    • C01P2006/80Compositional purity

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Silicon Compounds (AREA)

Abstract

Alkali metal formate, together with finely divided silica, is produced by reacting an aqueous solution of an alkali metal silicate of a concentration not exceeding 20 per cent (w/v) with carbon monoxide at a temperature above 100 DEG C. while intensely mixing or stirring the solution at increased pressure. The process may be operated continuously by withdrawing a portion of the treated solution after separation of silica for the recovery of alkali metal formate, making up the remainder with fresh aqueous alkali metal silicate solution and recycling. The treated solution leaving the reaction vessel may become substantially saturated with alkali metal formate.ALSO:Finely divided silica, together with alkali metal formate, is produced by reacting an aqueous solution of an alkali metal silicate of a concentration not exceeding 20 per cent. (w/v) with carbon monoxide at a temperature above 100 DEG C. while intensely mixing or stirring the solution at increased pressure. The process may be operated continuously by withdrawing a portion of the treated solution after separation of silica for the recovery of alkali metal formate, making up the remainder with fresh aqueous alkali metal silicate solution, and recycling. The treated solution leaving the reaction vessel may become substantially saturated with alkali metal formate. The silica may be precipitated in the presence of a protective colloid which imparts hydrophobic properties to the precipitated silica, for example stearic acid and organic amines.
GB7937/53A 1952-04-24 1953-03-23 Process for the production of finely divided silica and alkali metal formate Expired GB724457A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE724457X 1952-04-24

Publications (1)

Publication Number Publication Date
GB724457A true GB724457A (en) 1955-02-23

Family

ID=6634302

Family Applications (1)

Application Number Title Priority Date Filing Date
GB7937/53A Expired GB724457A (en) 1952-04-24 1953-03-23 Process for the production of finely divided silica and alkali metal formate

Country Status (1)

Country Link
GB (1) GB724457A (en)

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