GB720506A - Improvements in or relating to interpolymers - Google Patents
Improvements in or relating to interpolymersInfo
- Publication number
- GB720506A GB720506A GB12718/52A GB1271852A GB720506A GB 720506 A GB720506 A GB 720506A GB 12718/52 A GB12718/52 A GB 12718/52A GB 1271852 A GB1271852 A GB 1271852A GB 720506 A GB720506 A GB 720506A
- Authority
- GB
- United Kingdom
- Prior art keywords
- hydroxy
- ester
- butyl
- per cent
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F214/02—Monomers containing chlorine
- C08F214/04—Monomers containing two carbon atoms
- C08F214/06—Vinyl chloride
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
Interpolymers are prepared by polymerizing a mixture of monomeric materials comprising from 35 to 90 per cent by weight of vinyl chloride, from 5 to 65 per cent by weight of an alkyl ester of acrylic acid and from 0.2 to 25 per cent by weight of an ester of the formula <FORM:0720506/IV (a)/1> wherein X is an ester linkage and R is a divalent saturated aliphatic radical, or from 0.2 to 25 per cent by weight of a hydroxy-alkyl ester of acrylic acid, said mixture containing at least 90 per cent by weight of said alkyl ester of acrylic acid, said vinyl chloride and said ester of given formula or said hydroxy-alkyl ester of acrylic acid, the polymerization being carried out under acidic conditions when an ester of the above formula is used. The alkyl acrylate may be methyl, ethyl, propyl, n-butyl, n-amyl, n-hexyl, n-heptyl, isohexyl, n-heptyl, isoheptyl, capryl, n-octyl, 2-ethylhexyl, 6-methyl-heptyl, n-nonyl, 3,5,5-trimethylhexyl, n-decyl or lauryl acrylate. The ester of the given formula may be the monovinyl ester of malonic, chloro- or bromo-malonic, hydroxy-malonic, dihydroxy-malonic, isosuccinic, ethyl malonic; succinic, malic, bromo-succinic, tartaric, ethyl succinic, citramalic, acetoxy-succinic, glutaric, alpha-hydroxy - glutaric, adipic, pimelic, suberic, azelaic, sebacic, brassylic or thapsic acid, or may be acryloxyacetic acid, beta-acryloxy propionic acid or 4-carboxy-butyl acrylate. The hydroxy-alkyl ester of acrylic acid may be 2-hydroxyethyl, 1-chloro-2-hydroxyethyl, 3-hydroxy - propyl, glyceryl, 2 - methoxy - 3 - hydroxy - propyl, 2 - hydroxy - butyl, 3 - hydroxy - butyl, 3,4 - dihydroxy - butyl, 2 - methoxy, 3,4 - dihydroxy - butyl, 5 - hydroxy - amyl, 6 - hydroxy - hexyl, 2 - ethyl - 6 - hydroxy - hexyl, 7 - hydroxy - heptyl, 1 - methyl - 7 - hydroxy - heptyl, 8 - hydroxy - octyl, 3,5,5 - trimethyl - 6 - hydroxy - hexyl or 10 - hydroxy - decyl acrylate. Other monomers such as vinylidene chloride, vinyl acetate, vinyl benzoate, diethyl fumarate, acrylonitrile, styrene and methyl or ethyl acrylate may be utilized to the extent of 10 per cent by weight of the monomer mixture. Polymerization may be effected in an aqueous medium at pH 4.0 to 7.0. Emulsifiers referred to are the hymolal sulphates and sulphonates, such as the sodium salt of a sulphonated paraffin oil, salts of organic bases containing long carbon chains and polyether alcohols. Granular polymers may be obtained by polymerizing in an aqueous medium containing a colloidal suspension agent such as gelatin, bentonite clay, polyvinyl alcohol, polyacrylic acid and water-soluble phenolaldehyde and urea-aldehyde condensation products. The reaction may be catalysed by actinic radiation, or a peroxygen compound such as hydrogen, benzoyl, o,o1-dichlorobenzoyl, caproyl, caprylyl, and polygonyl peroxides, cumene, tertiary butyl and 1-hydroxy-cyclohexyl hydroperoxides, tertiary butyl diperphthalate, tertiary butyl perbenzoate, sodium, potassium and ammonium persulphates, sodium peracetate and sodium percarbonate. The interpolymers of the invention are suitable for the production of films, sheets and coatings.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US720506XA | 1951-05-22 | 1951-05-22 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB720506A true GB720506A (en) | 1954-12-22 |
Family
ID=22105255
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB12718/52A Expired GB720506A (en) | 1951-05-22 | 1952-05-20 | Improvements in or relating to interpolymers |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB720506A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5380786A (en) * | 1988-09-09 | 1995-01-10 | The Geon Company | Polyvinyl chloride blends having improved physical properties including low temperature brittleness |
-
1952
- 1952-05-20 GB GB12718/52A patent/GB720506A/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5380786A (en) * | 1988-09-09 | 1995-01-10 | The Geon Company | Polyvinyl chloride blends having improved physical properties including low temperature brittleness |
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