GB899342A - Polymeric products - Google Patents
Polymeric productsInfo
- Publication number
- GB899342A GB899342A GB12855/61A GB1285561A GB899342A GB 899342 A GB899342 A GB 899342A GB 12855/61 A GB12855/61 A GB 12855/61A GB 1285561 A GB1285561 A GB 1285561A GB 899342 A GB899342 A GB 899342A
- Authority
- GB
- United Kingdom
- Prior art keywords
- methacrylamide
- heating
- followed
- methyl methacrylate
- medium containing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
- C08F20/52—Amides or imides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
- C08F222/36—Amides or imides
- C08F222/40—Imides, e.g. cyclic imides
- C08F222/408—Imides, e.g. cyclic imides substituted imides comprising other heteroatoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/48—Isomerisation; Cyclisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2800/00—Copolymer characterised by the proportions of the comonomers expressed
- C08F2800/20—Copolymer characterised by the proportions of the comonomers expressed as weight or mass percentages
Abstract
Dimethacrylimide polymers are made by heating a polymer containing methacrylamide and methacrylic ester units to a temperature of between 110 DEG and 220 DEG C. in the presence of water or an alcohol containing at least two hydroxyl groups, e.g. monoethylene, diethylene, triethylene, propylene and trimethylene glycols and glycerol. Methacrylic esters specified are the C1-C6 alkyl and cycloalkyl methacrylates. The methacrylamide employed may be N-mono-substituted by a C1-C6 alkyl and cycloalkyl groups. The copolymers may also contain up to 20% of a further monomer, e.g. acrylonitrile, methacrylonitrile, ethyl acrylate, styrene and vinyl and vinylidene chlorides. The process may be carried out by copolymerizing the monomers in water or a polyhydric alcohol followed by heat treatment of the resulting copolymer whilst still in the polymerization medium. The examples describe the copolymerization of: (1) methyl methacrylate and methacrylamide in an aqueous medium containing potassium persulphate and ethylhexyl thioglycoleate, followed by the heating of the resulting copolymer dispersion, (2) as in (1) but with the addition of magnesium carbonate, (4) methyl methacrylate and methacrylamide in an aqueous medium containing sodium sulphate benzoyl peroxide and partially saponified polyacrylonitrile to yield a pearl polymer which is then heated in aqueous suspension, (5) butyl methacrylate and methacrylamide in an aqueous medium containing potassium persulphate, followed by heating of the resulting copolymer in its aqueous phase, (6) styrene, methyl methacrylate and methacrylamide in an aqueous medium containing potassium persulphate, followed by heating of the resulting copolymer dispersion, (7) methyl methacrylate, ethyl acrylate and methacrylamide by the process described in (1) with subsequent heating of the resulting dispersion, and (11) methacrylamide and methyl methacrylate in an ethylene glycol medium containing potassium persulphate, followed by heating of the resulting copolymer dispersion.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DER27724A DE1113308B (en) | 1960-04-09 | 1960-04-09 | Process for the preparation of polymethacrylic imides and copolymers of methacrylic imides |
DER28854A DE1121335B (en) | 1960-04-09 | 1960-10-07 | Process for the preparation of polymethacrylic imides and copolymers of methacrylic imides |
Publications (1)
Publication Number | Publication Date |
---|---|
GB899342A true GB899342A (en) | 1962-06-20 |
Family
ID=25991346
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB12855/61A Expired GB899342A (en) | 1960-04-09 | 1961-04-10 | Polymeric products |
Country Status (5)
Country | Link |
---|---|
CH (1) | CH439745A (en) |
DE (2) | DE1113308B (en) |
GB (1) | GB899342A (en) |
NL (2) | NL131228C (en) |
SE (1) | SE319607B (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2000154A (en) * | 1977-06-09 | 1979-01-04 | Gaf Corp | Preparation of linear cyclic polyimides from latices |
US5104954A (en) * | 1987-10-05 | 1992-04-14 | Ciba-Geigy Corporation | Thermostropic biphilic hydrogels and hydroplastics |
US5334686A (en) * | 1992-11-30 | 1994-08-02 | Nitto Denko Corporation | Pressure-sensitive adhesive and adhesive sheets using the same |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2836875B2 (en) * | 1989-12-27 | 1998-12-14 | 株式会社クラレ | Method for producing imidized acrylic resin |
DE4002904A1 (en) * | 1990-02-01 | 1991-08-08 | Roehm Gmbh | METHOD FOR IMIDATING A METHACRYL ESTER POLYMERISATE |
DE4130612A1 (en) * | 1991-09-14 | 1993-03-18 | Roehm Gmbh | METHOD FOR PRODUCING POLYMETHACRYLIMIDE POLYMERS |
-
0
- NL NL263065D patent/NL263065A/xx unknown
- NL NL131228D patent/NL131228C/xx active
-
1960
- 1960-04-09 DE DER27724A patent/DE1113308B/en active Pending
- 1960-10-07 DE DER28854A patent/DE1121335B/en active Pending
-
1961
- 1961-01-23 CH CH77961A patent/CH439745A/en unknown
- 1961-01-26 SE SE775/61A patent/SE319607B/xx unknown
- 1961-04-10 GB GB12855/61A patent/GB899342A/en not_active Expired
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2000154A (en) * | 1977-06-09 | 1979-01-04 | Gaf Corp | Preparation of linear cyclic polyimides from latices |
GB2000154B (en) * | 1977-06-09 | 1982-03-17 | Gaf Corp | Preparation of linear cyclic polyimides from latices |
US5104954A (en) * | 1987-10-05 | 1992-04-14 | Ciba-Geigy Corporation | Thermostropic biphilic hydrogels and hydroplastics |
US5334686A (en) * | 1992-11-30 | 1994-08-02 | Nitto Denko Corporation | Pressure-sensitive adhesive and adhesive sheets using the same |
Also Published As
Publication number | Publication date |
---|---|
DE1121335B (en) | 1962-01-04 |
SE319607B (en) | 1970-01-19 |
NL131228C (en) | 1900-01-01 |
DE1113308B (en) | 1961-08-31 |
NL263065A (en) | 1900-01-01 |
CH439745A (en) | 1967-07-15 |
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