GB719683A - Improvements in the production of moisture-proof coatings, impregnations, prints andthe like on fibrous materials and compositions therefor - Google Patents

Improvements in the production of moisture-proof coatings, impregnations, prints andthe like on fibrous materials and compositions therefor

Info

Publication number
GB719683A
GB719683A GB25690/52A GB2569052A GB719683A GB 719683 A GB719683 A GB 719683A GB 25690/52 A GB25690/52 A GB 25690/52A GB 2569052 A GB2569052 A GB 2569052A GB 719683 A GB719683 A GB 719683A
Authority
GB
United Kingdom
Prior art keywords
copolymer
acrylamide
ammonia
acrylate
chlorethyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB25690/52A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Badische Anilin and Sodafabrik AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE, Badische Anilin and Sodafabrik AG filed Critical BASF SE
Publication of GB719683A publication Critical patent/GB719683A/en
Expired legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/285—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acid amides or imides
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/39—Aldehyde resins; Ketone resins; Polyacetals
    • D06M15/423—Amino-aldehyde resins

Abstract

Compositions for the production of moistureproof coatings, impregnations, prints or dyeings on fibrous materials comprise aqueous dispersions of polymers containing both halogen and acid amide groups, hardenable initial condensation products of thermosetting resins and, if desired, hardening agents and/or pigments. Suitable polymers are copolymers of acrylamide and vinyl chloride or as-dichlorethylene; methacrylamide and a -chloracrylic acid esters, vinyl-b -chlorethyl ether or acrylic or methacrylic acid-b -chlorethyl ester. The copolymers may also contain styrene, butadiene or acrylates. Mixtures of acrylonitrile-as-dichlorethylene and acrylamide-ethyl acrylate copolymers may also be used. Suitable condensation products are those of formaldehyde and urea, thiourea, alkylated ureas, acetylene diurea, melamine, dicyandiamide, guanidine, urethanes, diurethanes, glyoxal monourein and phenol, or methylol ethers. The dispersions may also contain emulsions of benzine, xylene, toluene or trichlorethylene, softeners, protective colloids, fillers, waterproofing and flameproofing agents. Examples describe the use of aqueous dispersions of (1) a copolymer of b -chlorethyl acrylate, methyl acrylate and acrylamide containing ammonia, tetramethylol-acetylene diurea, trimethylolmelamine or dimethylol urea, ammonium polyacrylate and nitrate and the azo dyestuff from 2 mols of diazotized 2.4-dichloraniline coupled with diaceto-acetyl-3.31-tolidine; (2) a copolymer of as-dichlorethylene, butyl acrylate and acrylamide, ammonia, gum tragacanth, dimethylol-1.4-butanediol diurethane, ammonium nitrate, white spirit and copper phthalocyanine paste; (3) a copolymer of vinyl chloride, methyl and butyl acrylates and acrylamide, ammonia, gum tragacanth, glycerine, trimethylol melamine, ammonium thiocyanate, white spirit and aluminium powder wetted with an oleyl alcohol-ethylene oxide reaction product; (4) a copolymer of vinyl chloride, butyl acrylate and methacrylamide, methyl cellulose, a formaldehyde-glyoxal monourein condensate, ammonia, ammonium sulphate, trichlorethylene and copper phthalocyanine paste; (5) a copolymer of b -chlorethyl methacrylate, propyl acrylate and acrylamide, sodium alginate, formaldehydemelamine condensate, ammonium nitrate and iron oxide; (6) a copolymer of vinyl-b -chlorethylether and methyl acrylate, a copolymer of butyl acrylate, acrylonitrile and acrylamide, sodium pectinate, dimethylol-dimethyl urea, ammonia, ammonium nitrate, gasoline and the pigment of (1); (7) a copolymer of as-dichlorethylene, acrylonitrile and propyl acrylate, a copolymer of vinyl chloride, butyl acrylate and methacrylamide, sodium polyacrylate, bismethyl ether of tetramethylolmelamine, tartaric acid, xylene, ammonia and copper phthalocyanine paste. The compositions may be applied to fibres of natural or regenerated cellulose, cellulose acetate, polyamide, polyacrylonitrile, polyesters, wool, silk or leather, dried at 50 DEG to 100 DEG C. and then heated, e.g. at 100 DEG to 200 DEG C.ALSO:Compositions for the production of moistureproof coatings, impregnations, prints or dyeings on fibrous materials comprise aqueous dispersions of polymers containing both halogen and acid amide groups, hardenable initial condensation products of thermo-setting resins and, if desired, hardening agents and/or pigments. Suitable polymers are copolymers of acrylamide and vinyl chloride or as-dichlorethylene; methacrylamide and a -chloracrylic acid esters, vinyl-b -chlorethyl ether or acrylic or methacrylic acid b -chlorethyl ester. The copolymers may also contain styrene, butadiene or acrylates. Mixtures of acrylonitrile-as-dichlorethylene and acrylamide-ethyl acrylate copolymers may also be used. Suitable condensation products are those of formaldehyde and urea, thiourea, alkylated ureas, acetylene diurea, melamine, dicyandiamide, guanidine, urethanes, diurethanes, glyoxal monourein and phenol, or methylol ethers. The dispersions may also contain emulsions of benzine, xylene, toluene or trichlorethylene, softeners, protective colloids, fillers, waterproofing and flameproofing agents. Examples describe the use of aqueous dispersions of (1) a copolymer of b -chlorethyl acrylate, methyl acrylate and acrylamide containing ammonia, tetramethyloyl-acetylene diurea, trimethylolmelamine or dimethylol urea, ammonium polyacrylate and nitrate and the azo dyestuff from 2 mols of diazotized 2.4-dichloraniline coupled with diaceto-acetyl-3.31-tolidine; (2) a copolymer of as-dichlorethylene, butyl acrylate and acrylamide, ammonia, gum tragacanth, dimethylol-1.4-butanediol diurethane, ammonium nitrate, white spirit and copper phthalocyanine paste; (3) a copolymer of vinyl chloride, methyl and butyl acrylates and acrylamide, ammonia, gum tragacanth, glycerine, trimethylol melamine, ammonium thiocyanate, white spirit and aluminium powder wetted with an oleyl alcohol-ethylene oxide reaction product; (4) a copolymer of vinyl chloride, butyl acrylate and methacrylamide, methyl cellulose, a formaldehydeglyoxal monourein condensate, ammonia, ammonium sulphate, trichlorethylene and copper phthalocyanine paste; (5) a copolymer of b -chlorethyl methacrylate, propyl acrylate and acrylamide, sodium alginate, formaldehyde-melamine condensate, ammonium nitrate and iron oxide; (6) a copolymer of vinyl b -chlorethyl ether and methyl acrylate, a copolymer of butyl acrylate acrylonitrile and acrylamide, sodium pectinate, dimethylol-dimethyl urea, ammonia, ammonium nitrate, gasoline and the pigment of ex (1); (7) a copolymer of as-dichlorethylene, acrylonitrile and propyl acrylate, a copolymer of vinyl chloride, butyl acrylate and methacrylamide, sodium polyacrylate, bis-methyl ether of tetramethylolmelamine, tartaric acid, xylene, ammonia and copper phthalocyanine paste. The compositions may be applied to fibres of natural or regenerated cellulose, cellulose acetate, polyamide, polyacrylonitrile, polyesters, wool, silk or leather, dried at 50 DEG to 100 DEG C. and then heated, e.g. at 100 DEG to 200 DEG C.
GB25690/52A 1951-10-20 1952-10-14 Improvements in the production of moisture-proof coatings, impregnations, prints andthe like on fibrous materials and compositions therefor Expired GB719683A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE308869X 1951-10-20

Publications (1)

Publication Number Publication Date
GB719683A true GB719683A (en) 1954-12-08

Family

ID=6121855

Family Applications (1)

Application Number Title Priority Date Filing Date
GB25690/52A Expired GB719683A (en) 1951-10-20 1952-10-14 Improvements in the production of moisture-proof coatings, impregnations, prints andthe like on fibrous materials and compositions therefor

Country Status (3)

Country Link
CH (1) CH308869A (en)
FR (1) FR1064543A (en)
GB (1) GB719683A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112323514A (en) * 2020-11-20 2021-02-05 浙江理工大学 Low-ammonia-nitrogen urea substitute with high color-obtaining performance and active printing method thereof
CN112941914A (en) * 2021-01-19 2021-06-11 温州华特热熔胶股份有限公司 Damp-proof thermal fuse and preparation method thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112323514A (en) * 2020-11-20 2021-02-05 浙江理工大学 Low-ammonia-nitrogen urea substitute with high color-obtaining performance and active printing method thereof
CN112323514B (en) * 2020-11-20 2022-08-05 浙江理工大学 Low-ammonia-nitrogen urea substitute with high color-obtaining performance and active printing method thereof
CN112941914A (en) * 2021-01-19 2021-06-11 温州华特热熔胶股份有限公司 Damp-proof thermal fuse and preparation method thereof
CN112941914B (en) * 2021-01-19 2022-05-17 温州华特热熔胶股份有限公司 Damp-proof thermal fuse and preparation method thereof

Also Published As

Publication number Publication date
FR1064543A (en) 1954-05-14
CH308869A (en) 1955-08-15

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