GB716235A - Improvements in and relating to catalysts - Google Patents
Improvements in and relating to catalystsInfo
- Publication number
- GB716235A GB716235A GB985450A GB985450A GB716235A GB 716235 A GB716235 A GB 716235A GB 985450 A GB985450 A GB 985450A GB 985450 A GB985450 A GB 985450A GB 716235 A GB716235 A GB 716235A
- Authority
- GB
- United Kingdom
- Prior art keywords
- spheres
- pieces
- catalytic
- plastic mass
- adjuvant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2/00—Processes or devices for granulating materials, e.g. fertilisers in general; Rendering particulate materials free flowing in general, e.g. making them hydrophobic
- B01J2/28—Processes or devices for granulating materials, e.g. fertilisers in general; Rendering particulate materials free flowing in general, e.g. making them hydrophobic using special binding agents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Catalysts (AREA)
Abstract
Substantially spherical catalytic bodies, adapted for use in a continuous chemical process involving a liquid phase and a static bed, are prepared by mixing an adjuvant and a particulate material to obtain a plastic mass, dividing the plastic mass into pieces and moulding the pieces into approximate spheres of diameter 1/16 -\ba3/4 inch (preferably 1/8 -\ba3/8 inch) by means of two surfaces between which there is relative movement, and then heating the spheres to a moderate temperature. Catalytic substances may be present in the particulate material or may be introduced in solution or suspension in a liquid adjuvant such as water, a solution of sugar or gum, a volatile organic liquid, or a mineral oil; grease or petroleum may also be used as the adjuvant. Alternatively catalytic material may be applied to the spheres after moulding and heating. The plastic mass may be extruded into cylinders, cut into pieces and then rolled between two corrugated surfaces or between two rubber band conveyers moving in opposite directions at different speeds, the upper band having a lateral reciprocating motion. Specified catalytic materials are aqueous gels of aluminium or ferric hydroxide, tungstic oxide or sulphide, and a mixture of kieselguhr and phosphoric acid. In an example, boron phosphate formed by reacting orthophosphoric acid and boric acid, is ground, made into a paste with water formed into spheres and dried. The Provisional Specification refers to forming the spheres by granulation in a mixer, or by adding graphite and pelleting by means of tools having hemispherical concave tips. The preparation of mullite spheres according to Specification 715,882 is disclaimed. Specifications 220,649, [Class 1 (i)], 340,239 and 608,849, [Group XIII], also are referred to.ALSO:Substantially spherical catalytic bodies are prepared by mixing an adjuvant and a particulate material to obtain a plastic mass, dividing the plastic mass into pieces and moulding the pieces into approximate spheres of diameter 1/16 -\ba3/4 inch (preferably 1/8 -\ba3/8 inch) by means of two surfaces between which there is relative movement, and then heating the spheres to a moderate temperature. Catalytic substances may be present in the particulate material or may be introduced in solution or suspension in a liquid adjuvent such as water, a solution of sugar or gum, a volatile organic liquid, or a mineral oil; grease or petrolatum may also be used as the adjuvant. Alternatively catalytic material may be applied to the spheres after moulding and heating. The plastic mass may be extruded into cylinders, cut into pieces, and then rolled between two corrugated surfaces or between two rubber band conveyers moving in opposite p directions at different speeds, the upper band having a lateral reciprocating motion. Specified catalytic materials are aqueous gels of aluminium or ferric hydroxide, tungstic oxide of sulphide, and a mixture of kieselghur and phosphoric acid. In an example boron phosphate, formed by reacting orthophosphoric acid and boric acid, is ground, made into a paste with water formed into spheres, and dried. The Provisional Specification refers to forming the spheres by granulation in a mixer, or by adding graphite and pelletting by means of tools having hemispherical concave tips. The preparation of mullite spheres according to Specification 715,882, [Group III], is disclaimed Specifications 220,649, [Class I (i)], 340,239, [Group III], and 608,849, [Group XII], also are referred to.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB985450A GB716235A (en) | 1950-04-21 | 1950-04-21 | Improvements in and relating to catalysts |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB985450A GB716235A (en) | 1950-04-21 | 1950-04-21 | Improvements in and relating to catalysts |
Publications (1)
Publication Number | Publication Date |
---|---|
GB716235A true GB716235A (en) | 1954-09-29 |
Family
ID=9880032
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB985450A Expired GB716235A (en) | 1950-04-21 | 1950-04-21 | Improvements in and relating to catalysts |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB716235A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2101924A (en) * | 1981-05-13 | 1983-01-26 | Masao Kobayashi | Apparatus for forming soft food material into globular shape |
-
1950
- 1950-04-21 GB GB985450A patent/GB716235A/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2101924A (en) * | 1981-05-13 | 1983-01-26 | Masao Kobayashi | Apparatus for forming soft food material into globular shape |
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