GB715202A - Improvements in stabilisers for polyvinyl chloride and interpolymers containing vinyl chloride - Google Patents
Improvements in stabilisers for polyvinyl chloride and interpolymers containing vinyl chlorideInfo
- Publication number
- GB715202A GB715202A GB19978/51A GB1997851A GB715202A GB 715202 A GB715202 A GB 715202A GB 19978/51 A GB19978/51 A GB 19978/51A GB 1997851 A GB1997851 A GB 1997851A GB 715202 A GB715202 A GB 715202A
- Authority
- GB
- United Kingdom
- Prior art keywords
- vinyl chloride
- ureido
- aminophenol
- glycide ether
- epoxyureas
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/21—Urea; Derivatives thereof, e.g. biuret
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Vinyl chloride polymers are heat-stabilized by incorporating in the polymer, which may be plasticized, an epoxyurea of the formula: <FORM:0715202/IV (a)/1> in which Ar represents a substituted or unsubstituted aromatic radical. The polymer may be polyvinyl chloride or a copolymer of vinyl chloride and vinyl acetate. Specified stabilizers are ureido-phenyl-glycide ether and ureido-naphthyl-glycide ether. Plasticizers mentioned are dioctyl phthalate, dialkyl adipates and tricresyl phosphate.ALSO:Epoxyureas of the formula <FORM:0715202/IV (b)/1> where Ar represents an aromatic radical which may be substituted are made by reacting hydroxy-arylamines with a cyanate to form the desired hydroxyphenylurea and converting the latter with epichlorhydrin into the epoxyurea. In example (1) ureido-phenyl glycide ether is made by reacting epichlorhydrin and metahydroxyphenylurea made from meta-aminophenol hydrochloride and potassium cyanate; in example (2) para-aminophenol replaces meta-aminophenol whilst in example (3) a ureidonaphthyl glycide ether is obtained from 6-amino-1-naphthol in a manner similar to example (1) by way of hydroxynaphthylurea. The epoxyureas are used as stabilizers for vinyl chloride polymers.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB19978/51A GB715202A (en) | 1951-08-24 | 1951-08-24 | Improvements in stabilisers for polyvinyl chloride and interpolymers containing vinyl chloride |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB19978/51A GB715202A (en) | 1951-08-24 | 1951-08-24 | Improvements in stabilisers for polyvinyl chloride and interpolymers containing vinyl chloride |
Publications (1)
Publication Number | Publication Date |
---|---|
GB715202A true GB715202A (en) | 1954-09-08 |
Family
ID=10138300
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB19978/51A Expired GB715202A (en) | 1951-08-24 | 1951-08-24 | Improvements in stabilisers for polyvinyl chloride and interpolymers containing vinyl chloride |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB715202A (en) |
-
1951
- 1951-08-24 GB GB19978/51A patent/GB715202A/en not_active Expired
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