GB709634A - Improvements in organic silicon compounds and their preparation - Google Patents

Improvements in organic silicon compounds and their preparation

Info

Publication number
GB709634A
GB709634A GB4073/51A GB407351A GB709634A GB 709634 A GB709634 A GB 709634A GB 4073/51 A GB4073/51 A GB 4073/51A GB 407351 A GB407351 A GB 407351A GB 709634 A GB709634 A GB 709634A
Authority
GB
United Kingdom
Prior art keywords
silicates
organic nitrogen
nitrogen base
silica
base
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB4073/51A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ineos Silicas Ltd
Original Assignee
Joseph Crosfield and Sons Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Joseph Crosfield and Sons Ltd filed Critical Joseph Crosfield and Sons Ltd
Priority to GB4073/51A priority Critical patent/GB709634A/en
Publication of GB709634A publication Critical patent/GB709634A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02Silicon compounds
    • C07F7/04Esters of silicic acids

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)

Abstract

The invention comprises organic nitrogen base silicates of the general formula: <FORM:0709634/IV (b)/1> wherein R1 and R2 are independent substituent groups selected from hydrogen and alkyl, hydroxyalkyl, aminoalkyl, amidino, cycloalkyl, aralkyl and aryl groups, R3 being an independent substituent group selected from hydrogen and the aforesaid groups and R4 being an independent substituent group selected from the aforesaid groups other than alkyl or R3 and R4 being both -CH2- groups forming part of a heterocyclic ring structure which includes the nitrogen atom, X is a number varying from 0.5 to 4 and Y is a number varying from 0 to 15, and a process for preparing organic nitrogen base silicates by dissolving a silica which is soluble in aqueous alkalis in a solution containing at least 0.1 per cent of an organic nitrogen base, which base has a dissociation constant of at least 10-5 and recovering the resultant organic nitrogen base silicate. Organic nitrogen base silicates may also be prepared by contacting a sodium silicate solution with a synthetic resin base exchange compound which has previously been contacted with an organic nitrogen base, in the resulting base exchange; the sodium ion in solution is replaced by the organic ammonium ion to form a solution of the corresponding organic nitrogen base silicate. The preferred organic nitrogen base silicates are the tetra-b -ethanol ammonium silicates, phenyltrimethylammonium silicates and guanidine silicates which have respectively the formul : <FORM:0709634/IV (b)/2> <FORM:0709634/IV (b)/3> and <FORM:0709634/IV (b)/4> where X and Y have the significance indicated above. Any organic nitrogen base of the following types may be used to form the organic nitrogen base silicates: primary, secondary and tertiary alkyl amines, alkyl quaternary ammonium bases in which at least one of the alkyl groups is substituted by a hydroxyl or amino group, primary, secondary and tertiary aryl amines, aryl quaternary ammonium bases, heterocyclic amines; amidino amines, cycloalkyl amines and aralkyl amines. The organic nitrogen base silicates may be prepared in water or in an organic solvent, e.g. methyl, ethyl or butyl alcohol or acetone. The silica used in the process may be hydrated, or may be in the form of a silica sol or a silica gel which may be finely divided. Dehydrated amorphous silicas such as diatomaceous earths and dried gels, vitreous silica, and crystalline forms of silica such as quartz, cristobalite or tridymite may also be used. If saturated solutions of the nitrogen bases are used for reaction with the silica, the desired base silicates may be recovered by cooling, or by concentrating the resulting solution before cooling. Precipitation of the base silicates may also be brought about by the addition of a small amount of acid or an organic water miscible solvent, e.g. alcohol or acetone. In the examples, organic nitrogen base silicates are formed by the reaction of a silica with each of the following organic nitrogen bases: phenyltrimethylammonium hydroxide and butoxide, tetra-b -ethanolammonium, benzyltrimethylammonium and dibenzyldimethylammonium hydroxides, guanidine, morpholine, cyclo- and dicyclo-hexylamine, ethylene and diethylene diamine, triethylene tetramine, tetraethylene pentamine and mono-, di- and triethanolamine.
GB4073/51A 1951-02-20 1951-02-20 Improvements in organic silicon compounds and their preparation Expired GB709634A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB4073/51A GB709634A (en) 1951-02-20 1951-02-20 Improvements in organic silicon compounds and their preparation

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB4073/51A GB709634A (en) 1951-02-20 1951-02-20 Improvements in organic silicon compounds and their preparation

Publications (1)

Publication Number Publication Date
GB709634A true GB709634A (en) 1954-06-02

Family

ID=9770228

Family Applications (1)

Application Number Title Priority Date Filing Date
GB4073/51A Expired GB709634A (en) 1951-02-20 1951-02-20 Improvements in organic silicon compounds and their preparation

Country Status (1)

Country Link
GB (1) GB709634A (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3239521A (en) * 1961-08-15 1966-03-08 Philadelphia Quartz Co Amorphous quaternary ammonium silicates
US3326910A (en) * 1963-08-16 1967-06-20 Philadelphia Quartz Co Amorphous amine silicates substantially free of alkali metal oxide and process for their preparation
US3338901A (en) * 1961-08-15 1967-08-29 Philadelphia Quartz Co Method for producing amorphous quaternary nitrogen compositions
US3383386A (en) * 1960-08-22 1968-05-14 Philadelphia Quartz Co Process for making alkali metal quaternary ammonium silicates
WO2013064161A1 (en) * 2011-11-02 2013-05-10 Mindinvest Holdings Ltd. Polyguanidine silicate and use thereof
US9695111B2 (en) 2015-09-22 2017-07-04 Polymate, Ltd. Method of producing soluble silicates with organic cations

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3383386A (en) * 1960-08-22 1968-05-14 Philadelphia Quartz Co Process for making alkali metal quaternary ammonium silicates
US3239521A (en) * 1961-08-15 1966-03-08 Philadelphia Quartz Co Amorphous quaternary ammonium silicates
US3338901A (en) * 1961-08-15 1967-08-29 Philadelphia Quartz Co Method for producing amorphous quaternary nitrogen compositions
US3326910A (en) * 1963-08-16 1967-06-20 Philadelphia Quartz Co Amorphous amine silicates substantially free of alkali metal oxide and process for their preparation
WO2013064161A1 (en) * 2011-11-02 2013-05-10 Mindinvest Holdings Ltd. Polyguanidine silicate and use thereof
US9695111B2 (en) 2015-09-22 2017-07-04 Polymate, Ltd. Method of producing soluble silicates with organic cations

Similar Documents

Publication Publication Date Title
US3391142A (en) Adamantyl secondary amines
GB709634A (en) Improvements in organic silicon compounds and their preparation
GB1069053A (en) Polyamino alcohol derivatives
GB913866A (en) Improvements in or relating to amino-norcamphane compounds
US2477937A (en) N-hydrocarbon 3-piperidinols
GB2021589A (en) Process for Preparation of Compounds Containing Phosphorus-Carbon-Nitrogen Bond
GB1024816A (en) Basic ethers of substituted hydroxy benzoic acids and process for making same
US2655498A (en) N-benzhydbyl-n alkyl-substituted
GB1128375A (en) Process for preparing sorbic acid and its salts
GB913578A (en) Preparation of tetracycline and tetracycline-urea compounds
SE7612379L (en) PROCEDURE FOR THE PREPARATION OF TERTIERA AMINES.
GB998288A (en) Novel azapentanols and a process for the manufacture thereof
GB1013901A (en) Dihydroanthracene, dibenzocycloheptadiene and dibenzocycloheptatriene derivatives
GB823338A (en) Diquaternary salts of aminoalkyl piperidines
US2526943A (en) N, n-dialkyl-n&#39;-phenyl-n&#39;(2-heterocyclyl or heterocyclylalkylene) ethylenediamines
US2704297A (en) Alkylguanylisoureas
US3187049A (en) Process for the preparation of aminomethyl-phenols
GB827832A (en) Improvements in or relating to substituted amines
GB899014A (en) New derivatives of phenoxazine and processes for their production
ES452655A1 (en) Process for removing non-fluorescent triazine derivative impurities from fluorescent agents
GB874575A (en) New basic ethers and a process for the production thereof
GB748224A (en) Improvements in or relating to bis-quaternary ammonium salts
GB803072A (en) Bis-ºÔ-aminophenoxy compounds of pharmaceutical value
GB1034573A (en) Dithiazane compounds
GB777794A (en) New 1:3-dioxolane derivatives and process for their preparation