GB705408A - Improvements relating to synthetic detergents - Google Patents
Improvements relating to synthetic detergentsInfo
- Publication number
- GB705408A GB705408A GB1154751A GB1154751A GB705408A GB 705408 A GB705408 A GB 705408A GB 1154751 A GB1154751 A GB 1154751A GB 1154751 A GB1154751 A GB 1154751A GB 705408 A GB705408 A GB 705408A
- Authority
- GB
- United Kingdom
- Prior art keywords
- fatty
- mixture
- added
- polyhydric alcohol
- aromatic compound
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D11/00—Special methods for preparing compositions containing mixtures of detergents ; Methods for using cleaning compositions
- C11D11/04—Special methods for preparing compositions containing mixtures of detergents ; Methods for using cleaning compositions by chemical means, e.g. by sulfonating in the presence of other compounding ingredients followed by neutralising
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/28—Sulfonation products derived from fatty acids or their derivatives, e.g. esters, amides
Abstract
In the process for producing a synthetic detergent by sulphating mono-esters of polyhydric alcohols and fatty acids having 8 to 26 carbon atoms, or by sulphating a mixture of polyhydric alcohol and fatty material in the approximate proportions to give such a monoester, followed by neutralization, an alkylated aromatic compound having 8 to 26 alkyl carbon atoms is added to the reaction mixture at any stage prior to the neutralization. Preferably, a mixture of the alkylated aromatic compound and a polyhydric alcohol is first sulphonated and then the fatty material is introduced. Alternatively, the alkylated aromatic compound is first sulphonated with excess sulphonating reagent, and then a mixture of polyhydric alcohol and fatty material is added, or the polyhydric alcohol may first be sulphonated and then a mixture of the fatty material and alkylated aromatic compound is added. The polyhydric alcohol is preferably glycerol but ethylene glycol, diethylene glycol, propylene glycol or erythritol may be used. The fatty material preferably has a fatty acid content with 16 to 20 carbon atoms, and it may be in the form of free fatty acids or natural fats and fatty oils of vegetable, animal or marine origin. Suitable fatty materials include hydrogenated tallow, hydrogenated fish oil, hydrogenated whale blubber oil, fatty waxes such as spermaceti, or a mixture of hydrogenated fish oil and coconut oil. The alkylated aromatic compound may be derived from benzene, toluene, phenol or naphthalene and the alkyl substituent preferably has 12 to 14 carbon atoms. The sulphonating agent is preferably oleum containing 20 per cent. free SO3, but other agents such as chlorosulphonic acid and sulphur trioxide may be used. Other sulphonatable material which may be added to the reaction mixture includes fatty alcohols such as lauric and cetyl alcohols and mixtures of alcohols obtained from fatty oils; fatty amides and fatty alkanolamides. The sulphonated product is preferably neutralized with an alkaline sodium compound, such as a 30 per cent. aqueous solution of caustic soda, to a pH between 5.0 and 6.5. Builders may be added to the neutralized product and the mixture spray-dried to give a detergent composition (see Group III).ALSO:In the process for producing a synthetic detergent by sulphating mono-esters of polyhydric alcohols and fatty acids having 8 to 26 carbon atoms, or by sulphating a mixture of polyhydric alcohol and fatty material in the approximate proportions to give such a monoester, followed by neutralization, an alkylated aromatic compound having 8 to 26 alkyl carbon atoms is added to the reaction mixture at any stage prior to the neutralization. Preferably a mixture of the alkylated aromatic compound and a polyhydric alcohol is first sulphonated and then the fatty material is introduced. Alternatively, the alkylated aromatic compound is first sulphonated with excess sulphonating reagent, and then a mixture of polyhydric alcohol and fatty material is added, or the polyhydric alcohol may first be sulphonated and then a mixture of the fatty material and alkylated aromatic compound is added. The polyhydric alcohol is preferably glycerol but ethylene glycol, diethylene glycol, propylene glycol or erythritol may be used. The fatty material preferably has a fatty acid content with 16 to 20 carbon atoms, and it may be in the form of free fatty acids or natural fats and fatty oils of vegetable, animal or marine origin. Suitable fatty materials include hydrogenated tallow, hydrogenated fish oil, hydrogenated whale blubber oil, fatty waxes such as spermaceti, or a mixture of hydrogenated fish oil and coconut oil. The alkylated aromatic compound may be derived from benzene, toluene, phenol, or naphthalene and the alkyl substituent preferably has 12 to 14 carbon atoms. The sulphonating agent is preferably oleum containing 20 per cent. free SO3, but other agents such as chlorosulphonic acid and sulphur trioxide may be used. Other sulphonatable material which may be added to the reaction mixture includes fatty alcohols such as lauric and cetyl alcohols and mixtures of alcohols obtained from fatty oils; fatty amides and fatty alkanolamides. The sulphonated product is preferably neutralized with an alkaline sodium compound, such as a 30 per cent. aqueous solution of caustic soda, to a pH between 5.0 and 6.5. Builders may be added to the neutralized product and the mixture spray dried. Suitable builders include alkali metal phosphates, pyrophosphates, polyphosphates, silicates, borates and carbonates, and carboxymethyl cellulose, fatty alcohols, fatty acid amides, and fatty alkylamides.
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
BE504122D BE504122A (en) | 1951-05-17 | ||
GB1154751A GB705408A (en) | 1951-05-17 | 1951-05-17 | Improvements relating to synthetic detergents |
CH300866D CH300866A (en) | 1951-05-17 | 1951-05-25 | Process for the production of a synthetic detergent mixture. |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB1154751A GB705408A (en) | 1951-05-17 | 1951-05-17 | Improvements relating to synthetic detergents |
Publications (1)
Publication Number | Publication Date |
---|---|
GB705408A true GB705408A (en) | 1954-03-10 |
Family
ID=9988239
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB1154751A Expired GB705408A (en) | 1951-05-17 | 1951-05-17 | Improvements relating to synthetic detergents |
Country Status (3)
Country | Link |
---|---|
BE (1) | BE504122A (en) |
CH (1) | CH300866A (en) |
GB (1) | GB705408A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1993025646A1 (en) * | 1992-06-17 | 1993-12-23 | Lion Corporation | Detergent composition having low skin irritability |
-
0
- BE BE504122D patent/BE504122A/xx unknown
-
1951
- 1951-05-17 GB GB1154751A patent/GB705408A/en not_active Expired
- 1951-05-25 CH CH300866D patent/CH300866A/en unknown
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1993025646A1 (en) * | 1992-06-17 | 1993-12-23 | Lion Corporation | Detergent composition having low skin irritability |
US5681803A (en) * | 1992-06-17 | 1997-10-28 | Lion Corporation | Detergent composition having low skin irritability |
Also Published As
Publication number | Publication date |
---|---|
CH300866A (en) | 1954-08-31 |
BE504122A (en) |
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