GB685540A - Improvements in or relating to trialkylsilyl-phenoxysilanes - Google Patents
Improvements in or relating to trialkylsilyl-phenoxysilanesInfo
- Publication number
- GB685540A GB685540A GB3061349A GB3061349A GB685540A GB 685540 A GB685540 A GB 685540A GB 3061349 A GB3061349 A GB 3061349A GB 3061349 A GB3061349 A GB 3061349A GB 685540 A GB685540 A GB 685540A
- Authority
- GB
- United Kingdom
- Prior art keywords
- me3si
- c6h3o
- oc6h4sime3
- me3sic6h4o
- etme2si
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229910052783 alkali metal Inorganic materials 0.000 abstract 2
- 150000001340 alkali metals Chemical class 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- 125000005843 halogen group Chemical group 0.000 abstract 2
- CIUQDSCDWFSTQR-UHFFFAOYSA-N [C]1=CC=CC=C1 Chemical group [C]1=CC=CC=C1 CIUQDSCDWFSTQR-UHFFFAOYSA-N 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 239000012442 inert solvent Substances 0.000 abstract 1
- 150000003961 organosilicon compounds Chemical class 0.000 abstract 1
- 239000000376 reactant Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/0834—Compounds having one or more O-Si linkage
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
Abstract
The invention comprises organo-silicon compounds of the formula <FORM:0685540/IV (b)/1> wherein R is an alkyl radical, R1 is an alkyl or phenyl radical, b is 1 or 2, c is 0 or 1 and n is 1 or 2, and a method of preparing the above compounds by reacting a halophenoxysilane of the general formula <FORM:0685540/IV (b)/2> wherein R, R1, b, c and n have the above significance and X is a halogen atom, with a trialkylsilane of the general formula R3SiY, wherein Y is a halogen atom and R has the above significance, by contacting the two reactants with an alkali metal. The process is preferably carried out in an inert solvent which boils above the melting-point of the alkali metal. In the examples the following compounds are prepared by the method referred to above:- Me3Si(p-OC6H4SiMe3), Me3Si(o-OC6H4SiMe3), Me3Si[2.4(Me3Si)2C6H3O-], Me3Si[3Me.4(Me3Si)C6H3O-], Me3Si[2.4(Me3SiO)2C6H3-], Me3Si(2-C6H5-4-(Me3Si)C6H3O-), EtMe2Si(o-Me3SiC6H4O-), EtMe2Si(p-Me3SiC6H4O-), Me3Si(p-Me2EtSiC6H4O-), and Me3Si(2-C6H5-6-(Me3Si)C6H3O-). Specification 685,539 is referred to.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB3061349A GB685540A (en) | 1949-11-29 | 1949-11-29 | Improvements in or relating to trialkylsilyl-phenoxysilanes |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB3061349A GB685540A (en) | 1949-11-29 | 1949-11-29 | Improvements in or relating to trialkylsilyl-phenoxysilanes |
Publications (1)
Publication Number | Publication Date |
---|---|
GB685540A true GB685540A (en) | 1953-01-07 |
Family
ID=10310399
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB3061349A Expired GB685540A (en) | 1949-11-29 | 1949-11-29 | Improvements in or relating to trialkylsilyl-phenoxysilanes |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB685540A (en) |
-
1949
- 1949-11-29 GB GB3061349A patent/GB685540A/en not_active Expired
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