GB684856A - Process for manufacturing films of chlorinated rubber from an aqueous dispersion of chlorinated rubber and a plasticiser - Google Patents
Process for manufacturing films of chlorinated rubber from an aqueous dispersion of chlorinated rubber and a plasticiserInfo
- Publication number
- GB684856A GB684856A GB5928/50A GB592850A GB684856A GB 684856 A GB684856 A GB 684856A GB 5928/50 A GB5928/50 A GB 5928/50A GB 592850 A GB592850 A GB 592850A GB 684856 A GB684856 A GB 684856A
- Authority
- GB
- United Kingdom
- Prior art keywords
- chlorinated rubber
- rubber
- dispersion
- chlorinated
- aqueous dispersion
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000006185 dispersion Substances 0.000 title abstract 10
- 239000004014 plasticizer Substances 0.000 title abstract 5
- 238000004519 manufacturing process Methods 0.000 title 1
- 238000000034 method Methods 0.000 title 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 5
- 230000035699 permeability Effects 0.000 abstract 4
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 abstract 4
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 abstract 4
- 230000015572 biosynthetic process Effects 0.000 abstract 3
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 abstract 2
- KWVPFECTOKLOBL-KTKRTIGZSA-N 2-[(z)-octadec-9-enoxy]ethanol Chemical compound CCCCCCCC\C=C/CCCCCCCCOCCO KWVPFECTOKLOBL-KTKRTIGZSA-N 0.000 abstract 2
- 239000004215 Carbon black (E152) Substances 0.000 abstract 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 abstract 2
- PYGXAGIECVVIOZ-UHFFFAOYSA-N Dibutyl decanedioate Chemical compound CCCCOC(=O)CCCCCCCCC(=O)OCCCC PYGXAGIECVVIOZ-UHFFFAOYSA-N 0.000 abstract 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 abstract 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 abstract 2
- 239000002253 acid Substances 0.000 abstract 2
- 150000001412 amines Chemical class 0.000 abstract 2
- 125000006267 biphenyl group Chemical group 0.000 abstract 2
- 239000005018 casein Substances 0.000 abstract 2
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 abstract 2
- 235000021240 caseins Nutrition 0.000 abstract 2
- 239000003795 chemical substances by application Substances 0.000 abstract 2
- 229910052801 chlorine Inorganic materials 0.000 abstract 2
- 239000000460 chlorine Substances 0.000 abstract 2
- 230000001427 coherent effect Effects 0.000 abstract 2
- 239000003599 detergent Substances 0.000 abstract 2
- 239000003995 emulsifying agent Substances 0.000 abstract 2
- 150000002148 esters Chemical class 0.000 abstract 2
- 229930195733 hydrocarbon Natural products 0.000 abstract 2
- 150000002430 hydrocarbons Chemical class 0.000 abstract 2
- 229910044991 metal oxide Inorganic materials 0.000 abstract 2
- 150000004706 metal oxides Chemical class 0.000 abstract 2
- 229940055577 oleyl alcohol Drugs 0.000 abstract 2
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 abstract 2
- 229920000915 polyvinyl chloride Polymers 0.000 abstract 2
- 239000004800 polyvinyl chloride Substances 0.000 abstract 2
- 238000003825 pressing Methods 0.000 abstract 2
- 239000002904 solvent Substances 0.000 abstract 2
- 239000003381 stabilizer Substances 0.000 abstract 2
- 239000000126 substance Substances 0.000 abstract 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract 1
- 239000011111 cardboard Substances 0.000 abstract 1
- 230000008020 evaporation Effects 0.000 abstract 1
- 238000001704 evaporation Methods 0.000 abstract 1
- 239000002657 fibrous material Substances 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 239000000123 paper Substances 0.000 abstract 1
- 239000000049 pigment Substances 0.000 abstract 1
- 230000001737 promoting effect Effects 0.000 abstract 1
- 239000004753 textile Substances 0.000 abstract 1
- 235000010215 titanium dioxide Nutrition 0.000 abstract 1
- 239000002023 wood Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D115/00—Coating compositions based on rubber derivatives
- C09D115/02—Rubber derivatives containing halogen
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Laminated Bodies (AREA)
Abstract
In making coherent chlorinated rubber films having a low permeability for water vapour, an aqueous dispersion of preferably insoluble chlorinated rubber, made by chlorinating an acid aqueous dispersion of unmasticated rubber and containing up to 61 per cent of chlorine and between 5 and 25 per cent of a plasticizer by weight of the chlorinated rubber, is formed into a thin layer, water is evaporated and the residue is coalesced into a homogeneous film without applying pressure or adding volatile solvents or other agents assisting film formation. The dispersion of chlorinated rubber may be made as described in Specification 634,241. The permeability of the film may be lowered by adding to the dispersion a highly polymeric substance, e.g. polyvinyl chloride. The plasticizer may be chlorinated diphenyl or an ester of phosphoric, phthalic or sebacic acid, e.g. dibutyl sebacate. An emulsifier, e.g. casein, "Emulphor O" (obtained by reacting polyethylene oxide with oleyl alcohol), a sulphonated oil or hydrocarbon or an invert soap may be used. Stabilizers, e.g. amines or metal oxides, may be added. Specification 428,456 also is referred to.ALSO:In making coherent chlorinated rubber films having a low permeability for water vapour, an aqueous dispersion of preferably insoluble chlorinated rubber, made by chlorinating an acid aqueous dispersion of unmasticated rubber and containing up to 61 per cent of chlorine and between 5 and 25 per cent of a plasticizer by weight of the chlorinated rubber, is formed into a thin layer, water is evaporated and the residue is coalesced into a homogeneous film without applying pressure or adding volatile solvents or other agents promoting film formation. The dispersion of chlorinated rubber may be made as described in Specification 634,241. Evaporation of water and film formation may be accelerated by infra-red heating. The permeability of the film may be lowered by adding to the dispersion a highly polymeric substance, e.g. rubber, cyclised rubber or polyvinyl chloride. A pigment e.g. titanium white may be added. The plasticizer may be chlorinated diphenyl or an ester of phosphoric, phthalic or sebacic acid, e.g. dibutyl sebacate. Stabilizers, e.g. amines or metal oxides may be added. An emulsifier, e.g. casein, "Emulphor O" (obtained by reacting polyethylene oxide with oleyl alcohol), a sulphonated oil or hydrocarbon or an invert soap may be used. The dispersion may be applied to metal surfaces or to fibrous materials, e.g. paper, cardboard, wood and textiles. Specification 428,456, [Group IV], also is referred to.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NL684856X | 1949-05-31 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB684856A true GB684856A (en) | 1952-12-24 |
Family
ID=19805626
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB5928/50A Expired GB684856A (en) | 1949-05-31 | 1950-03-09 | Process for manufacturing films of chlorinated rubber from an aqueous dispersion of chlorinated rubber and a plasticiser |
Country Status (4)
| Country | Link |
|---|---|
| DE (1) | DE875565C (en) |
| FR (1) | FR1095301A (en) |
| GB (1) | GB684856A (en) |
| NL (1) | NL70446C (en) |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL33478C (en) * | 1931-10-27 | |||
| DE720174C (en) * | 1938-03-11 | 1942-04-27 | Celluloid Fabrik Ag Deutsche | Process for the production of films, foils or layers from aqueous emulsions of vinyl polymers |
-
0
- NL NL70446D patent/NL70446C/xx active
-
1950
- 1950-03-09 GB GB5928/50A patent/GB684856A/en not_active Expired
- 1950-03-29 FR FR1095301D patent/FR1095301A/en not_active Expired
- 1950-04-21 DE DER1543A patent/DE875565C/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| FR1095301A (en) | 1955-06-01 |
| NL70446C (en) | |
| DE875565C (en) | 1953-05-04 |
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