GB437446A - Improvements in or relating to aqueous vinyl resin dispersions or emulsions and to their manufacture and use - Google Patents
Improvements in or relating to aqueous vinyl resin dispersions or emulsions and to their manufacture and useInfo
- Publication number
- GB437446A GB437446A GB1266434A GB1266434A GB437446A GB 437446 A GB437446 A GB 437446A GB 1266434 A GB1266434 A GB 1266434A GB 1266434 A GB1266434 A GB 1266434A GB 437446 A GB437446 A GB 437446A
- Authority
- GB
- United Kingdom
- Prior art keywords
- water
- production
- groups
- coatings
- concentration
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F20/62—Monocarboxylic acids having ten or more carbon atoms; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F6/00—Post-polymerisation treatments
- C08F6/14—Treatment of polymer emulsions
- C08F6/20—Concentration
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
Abstract
Stable, highly concentrated (i.e. over 30 per cent, e.g. 50--65 per cent) aqueous dispersions or emulsions of water-insoluble polymers or mixed polymers of unsaturated organic compounds containing one olefinic double linkage, e.g. acrylic acid and its homologues and derivatives thereof, vinyl esters, ethers and halides and styrols, are manufactured by concentrating an aqueous dispersion or emulsion of one or more of the said polymers containing one or more hydrophile groups (i.e. groups which give rise to water solubility in soaps, e.g. the groups COO Na, COOK and COONH4) in the substances constituting the disperse phase. The hydrophile group or groups may be introduced into the molecule of the polymer or polymers before, during or after polymerization. Thus the polymerization of emulsions of monomeric bodies may be carried out in the presence of small quantities of unsaturated substances containing hydrophile groups, such as water soluble monomeric salts of polymerizable acids, e.g. sodium acrylate. Alternatively compounds containing saponifiable groups may be partially saponified by the action of relatively small quantities of alkali before, during or after polymerization or emulsification. The concentration may be effected by centrifuging or by evaporation or both, if desired with the assistance of further chemical reagents. Specifically heavy solvents or swelling agents for the polymers may be added before concentration, whilst softening agents, e.g. phthalic acid esters, natural and artificial resins, oils, dyestuffs or other colouring matters and solvents may be added before, during or after polymerization and/or concentration. The products, if necessary after dilution with water to the desired viscosity may be employed for the production of coatings or layers on suitable surfaces, e.g. wood, metal, glass, leather or paper, for the production of films, e.g. for safety glass, for the production of intermediate layers of all kinds, as lacquers, impregnating agents for textiles and other porous material and for the production of electrical insulating materials. The films and coatings may be rendered resistant to water by treatment with acids or solution of salts which form water-insoluble salts with the hydrophile groups. In examples: (1) acrylic acid methyl and ethyl esters are polymerized in emulsion in water containing Turkey red oil, hydrogen peroxide and sodium acrylate, and the resulting dispersion is centrifuged; (2) a 25 per cent dispersion of polyacrylic acid methyl ester is warmed with a small amount of caustic soda and then centrifuged; the product, diluted to 50 per cent concentration, is suitable for the production of coatings on wood or other surfaces by painting or dipping; (3) as in (2) except that the concentration is effected by evaporation in vacuo; the product may be employed for the production of coatings on wood, metal and other materials which coatings may be rendered less sensitive to water by treatment with alum solution or dilute hydrochloric acid; (4) as in (3) except that the saponifying agent is ammonia; films and coatings from the product may be made resistant to water by heating; (5) acrylic acid methyl ester is polymerized in emulsion in water containing Turkey red oil, hydrogen peroxide and acrylic acid and the product is neutralized with ammonia and concentrated by evaporation in vacuo. The Provisional Specification comprises also the concentration of the emulsions or dispersions by mechanical means alone. In an additional example, a 25 per cent dispersion of polyacrylic acid methyl ester is shaken up with a softening agent and then centrifuged. The product is suitable for the production of films, especially for safety glass.ALSO:Stable, highly concentrated (i.e. over 30 per cent. e.g. 50--65 per cent) aqueous dispersions or emulsions of water-insoluble polymers or mixed polymers of unsaturated organic compounds containing one olefinic double linkage, e.g. acrylic acid and its homologues and derivatives thereof, vinyl esters, ethers and halides and styrols, are manufactured by concentrating an aqueous dispersion or emulsion of one or more of the said polymers containing one or more hydrophile groups (i.e. groups which give rise to water solubility in soaps, e.g. the groups COONa, COOK and COONH4) in the substances constituting the disperse phase. The hydrophile group or groups may be introduced into the molecule of the polymer or polymers before, during or after polymerization. Thus the polymerization of emulsions of monomeric bodies may be carried out in the presence of small quantities of unsaturated substances containing hydrophile groups, such as water soluble monomeric salts of polymerizable acids, e.g. sodium acrylate. Alternatively compounds containing saponifiable groups may be partially saponified by the action of relatively small quantities of alkali before, during or after polymerization or emulsification. The concentration may be effected by centrifuging or by evaporation or both, if desired with the assistance of further chemical reagents. Specifically heavy solvents or swelling agents for the polymers may be added before concentration, whilst softening agents, e.g. phthalic acid esters, natural and artificial resins, oils, dyestuffs or other colouring matters and solvents may be added before, during or after polymerization and/or concentration. The products, if necessary after dilution with water to the desired biscosity, may be employed for the production of coatings or layers on suitable surfaces, e.g. wood, metal, glass, leather or paper, for the production of films, e.g. for safety glass, for the production of intermediate layers of all kinds, as lacquers, impregnating agents for textiles and other porous material and for the production of electrical insulating materials. The films and coatings may be rendered resistant to water by treatment with acids or solutions of salts which form water-insoluble salts with the hydrophile groups. In example: (1) acrylic acid methyl and ethyl esters are polymerized in emulsion in water containing turkey red oil, hydrogen peroxide and sodium acrylate, and the resulting dispersion is centrifuged; (2) a 25 per cent dispersion of polyacrylic acid methyl ester is warmed with a small amount of caustic soda and then centrifuged; the product, diluted to 50 per cent concentration, is suitable for the production of coatings on wood or other surfaces by painting or dipping; (3) as in (2) except that the concentration is effected by evaporation in vacuo; the product may be employed for the production of coatings on wood, metal and other materials, which coatings may be rendered less sensitive to water by treatment with alum solution or dilute hydrochloric acid; (4) as in (3) except that the saponifying agent is ammonia; films and coatings from the product may be made resistant to water by heating; (5) acrylic acid methyl ester is polymerized in emulsion in water containing turkey red oil, hydrogen peroxide and acrylic acid and the product is neutralized with ammonia and concentrated by evaporation in vacuo. The Provisional Specification comprises also the concentration of the emulsions or dispersions by mechanical means alone. In an additional example, a 25 per cent dispersion of polyacrylic acid methyl ester is shaken up with a softening agent and then centrifuged. The product is suitable for the production of films, especially for safety glass.
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB1266434A GB437446A (en) | 1934-04-26 | 1934-04-26 | Improvements in or relating to aqueous vinyl resin dispersions or emulsions and to their manufacture and use |
DER93018D DE733995C (en) | 1934-04-26 | 1935-04-03 | Process for the production of stable, highly concentratable aqueous dispersions from water-insoluble emulsion polymers of acrylic or vinyl resins |
FR789166D FR789166A (en) | 1934-04-26 | 1935-04-20 | Vinyl resin dispersions |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB1266434A GB437446A (en) | 1934-04-26 | 1934-04-26 | Improvements in or relating to aqueous vinyl resin dispersions or emulsions and to their manufacture and use |
Publications (1)
Publication Number | Publication Date |
---|---|
GB437446A true GB437446A (en) | 1935-10-28 |
Family
ID=10008857
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB1266434A Expired GB437446A (en) | 1934-04-26 | 1934-04-26 | Improvements in or relating to aqueous vinyl resin dispersions or emulsions and to their manufacture and use |
Country Status (3)
Country | Link |
---|---|
DE (1) | DE733995C (en) |
FR (1) | FR789166A (en) |
GB (1) | GB437446A (en) |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE743945C (en) * | 1940-06-12 | 1944-01-06 | Ig Farbenindustrie Ag | Process for the production of films, coatings, impregnations and the like like |
DE744318C (en) * | 1940-07-26 | 1944-06-17 | Ig Farbenindustrie Ag | Process for the production of high percentage stable emulsions |
US2528469A (en) * | 1948-02-24 | 1950-10-31 | Shell Dev | Granular polymerization of vinyl chloride |
DE751576C (en) * | 1936-08-29 | 1953-02-23 | Aeg | Electrical conductor with an insulating coating produced by applying an insulating varnish |
US2671065A (en) * | 1950-03-30 | 1954-03-02 | Minnesota Mining & Mfg | Polyvinyl acetate dispersion and method of making utilizing polyacrylic acid and monomer soluble and monomer insoluble catalyst |
US2727835A (en) * | 1952-07-31 | 1955-12-20 | Monsanto Chemicals | Process of sizing synthetic yarn with hydrolyzed polyalkyl acrylates |
US2827385A (en) * | 1954-10-25 | 1958-03-18 | Bruce E L Co | Quick seiting cement |
US4030970A (en) * | 1973-05-31 | 1977-06-21 | Sanyo Chemical Industries, Ltd. | Surface sizing of paper with an acrylic copolymer where scum formation is minimized |
US4115331A (en) * | 1973-05-31 | 1978-09-19 | Sanyo Chemical Industries, Ltd. | Surface sizing compositions for paper |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE980059C (en) * | 1951-04-09 | 1970-09-10 | Ciba Geigy | Process for the production of acidic, stable, aqueous dispersions of at least internal copolymers |
DE1009809B (en) * | 1954-11-10 | 1957-06-06 | Basf Ag | Process for the production of polyvinyl betaines |
US3029225A (en) * | 1956-02-20 | 1962-04-10 | Bjorksten Res Lab Inc | Temperature and solvent resistance of elastomers |
-
1934
- 1934-04-26 GB GB1266434A patent/GB437446A/en not_active Expired
-
1935
- 1935-04-03 DE DER93018D patent/DE733995C/en not_active Expired
- 1935-04-20 FR FR789166D patent/FR789166A/en not_active Expired
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE751576C (en) * | 1936-08-29 | 1953-02-23 | Aeg | Electrical conductor with an insulating coating produced by applying an insulating varnish |
DE743945C (en) * | 1940-06-12 | 1944-01-06 | Ig Farbenindustrie Ag | Process for the production of films, coatings, impregnations and the like like |
DE744318C (en) * | 1940-07-26 | 1944-06-17 | Ig Farbenindustrie Ag | Process for the production of high percentage stable emulsions |
US2528469A (en) * | 1948-02-24 | 1950-10-31 | Shell Dev | Granular polymerization of vinyl chloride |
US2671065A (en) * | 1950-03-30 | 1954-03-02 | Minnesota Mining & Mfg | Polyvinyl acetate dispersion and method of making utilizing polyacrylic acid and monomer soluble and monomer insoluble catalyst |
US2727835A (en) * | 1952-07-31 | 1955-12-20 | Monsanto Chemicals | Process of sizing synthetic yarn with hydrolyzed polyalkyl acrylates |
US2827385A (en) * | 1954-10-25 | 1958-03-18 | Bruce E L Co | Quick seiting cement |
US4030970A (en) * | 1973-05-31 | 1977-06-21 | Sanyo Chemical Industries, Ltd. | Surface sizing of paper with an acrylic copolymer where scum formation is minimized |
US4115331A (en) * | 1973-05-31 | 1978-09-19 | Sanyo Chemical Industries, Ltd. | Surface sizing compositions for paper |
Also Published As
Publication number | Publication date |
---|---|
DE733995C (en) | 1943-04-06 |
FR789166A (en) | 1935-10-24 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US2068424A (en) | Production of polymerization products | |
US2187817A (en) | Interpolymerization products of vinyl chloride and esters of maleic acid | |
GB437446A (en) | Improvements in or relating to aqueous vinyl resin dispersions or emulsions and to their manufacture and use | |
US2227163A (en) | Aqueous emoulsions of polymerization products and a process of preparaing them | |
DE923333C (en) | Polymerization process | |
US2346755A (en) | Emulsion composition | |
DE1495706A1 (en) | Process for the production of crosslinked polymers | |
GB373643A (en) | Improvements in the manufacture and production of polymerisation products | |
US2182316A (en) | Interpolymerization of fumaric esters and isobutylene | |
GB427494A (en) | Improvements in or relating to plastic materials and to methods of production thereof | |
GB428941A (en) | Process of protecting medicaments from the action of stomach-juices | |
GB434783A (en) | Manufacture of products of polymerisation | |
US2422646A (en) | Aqueous emulsions and a process of preparing them | |
DE863413C (en) | Process for the production of copolymers | |
GB438050A (en) | Manufacture of polyvinyl esters | |
GB484088A (en) | Improvements in or relating to the manufacture of chlorinated artificial masses | |
GB469319A (en) | Manufacture of polymerisation products | |
US2978346A (en) | Paint latices from super bodied oils | |
DE874664C (en) | Process for the production of polyvinyl alcohol or its water-soluble derivatives | |
US2118946A (en) | Mixed polymerization products | |
US2242529A (en) | Method of producing resin soap | |
US2247351A (en) | Prolamine composition | |
GB369725A (en) | Improvements in the manufacture and production of conversion products of rubber | |
GB387736A (en) | Improvements in coating absorbent materials | |
US1395242A (en) | Colloidal suspension op polymers and process of making the same |