GB680281A - Methods of improving the corrosion resistance of ferrous articles - Google Patents

Methods of improving the corrosion resistance of ferrous articles

Info

Publication number
GB680281A
GB680281A GB4134/49A GB413449A GB680281A GB 680281 A GB680281 A GB 680281A GB 4134/49 A GB4134/49 A GB 4134/49A GB 413449 A GB413449 A GB 413449A GB 680281 A GB680281 A GB 680281A
Authority
GB
United Kingdom
Prior art keywords
article
silicate
hydrocarbon
per cent
vapour
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB4134/49A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
British Thomson Houston Co Ltd
Original Assignee
British Thomson Houston Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by British Thomson Houston Co Ltd filed Critical British Thomson Houston Co Ltd
Publication of GB680281A publication Critical patent/GB680281A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/05Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
    • C23C22/06Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
    • C23C22/48Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 not containing phosphates, hexavalent chromium compounds, fluorides or complex fluorides, molybdates, tungstates, vanadates or oxalates
    • C23C22/50Treatment of iron or alloys based thereon
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2222/00Aspects relating to chemical surface treatment of metallic material by reaction of the surface with a reactive medium
    • C23C2222/20Use of solutions containing silanes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Chemical Treatment Of Metals (AREA)
  • Paints Or Removers (AREA)

Abstract

Ferrous articles are coated with a thin adherent film comprising an alkali-metal silicate and then exposed to the vapours of a hydrocarbon-substituted halogenosilane. The silicate coating composition may comprise potassium, sodium or lithium silicates, and 10-90 per cent phosphoric acid and/or 5-40 per cent zinc chromate or chromium oxide, each percentage being expressed by weight based on the alkalimetal silicate, may be included. The hydrocarbon - substituted halogenosilane may be methyl or ethyl chlorosilane, or a mixture thereof, or a mixture with silicon tetrachloride; as described in Specifications 572,740, [Group II], and 575,696, [Group VIII]. The silicate may be applied by dipping the article, which may be at a temperature above 50 DEG C into, or spraying it with, a 3-15 per cent aqueous solution thereof; the article may then be baked at 60-150 DEG C for 10-30 minutes, and exposed to the vapour of the hydrocarbon-substituted halogenosilane; if desired, prior to exposure to such vapour and after baking, the article may be subjected to the action of water vapour. Finally, the article is heated at 60-125 DEG C for 15-180 minutes.ALSO:Ferrous articles are coated with a thin adherent film comprising an alkali-metal silicate and then exposed to the vapours of a hydrocarbon-substituted halogenosilane. The silicate coating composition may comprise potassium, sodium or lithium silicates, and 10-90 per cent phosphoric acid and/or 5-40 per cent zinc chromate or chromium oxide, each percentage being expressed by weight based on the alkalimetal silicate, may be included. The hydrocarbon-substituted halogenosilane may be methyl or ethyl chlorosilane, or a mixture thereof, or a mixture with silicon tetrachloride; as described in Specifications 572,740 and 575,696, [Group VIII]. The silicate may be applied by dipping the article, which may be at a temperature above 50 DEG C into, or spraying it with, a 3-15 per cent aqueous solution thereof; the article may then be baked at 60-150 DEG C for 10-30 minutes, and exposed to the vapour of the hydrocarbon-substituted halogenosilane; if desired, prior to exposure to such vapour and after baking, the article may be subjected to the action of water vapour. Finally, the article is heated at 60-125 DEG C for 15-180 minutes.
GB4134/49A 1948-02-18 1949-02-15 Methods of improving the corrosion resistance of ferrous articles Expired GB680281A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US680281XA 1948-02-18 1948-02-18

Publications (1)

Publication Number Publication Date
GB680281A true GB680281A (en) 1952-10-01

Family

ID=22079971

Family Applications (1)

Application Number Title Priority Date Filing Date
GB4134/49A Expired GB680281A (en) 1948-02-18 1949-02-15 Methods of improving the corrosion resistance of ferrous articles

Country Status (1)

Country Link
GB (1) GB680281A (en)

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