GB677325A - A lubricating composition - Google Patents

A lubricating composition

Info

Publication number
GB677325A
GB677325A GB16784/48A GB1678448A GB677325A GB 677325 A GB677325 A GB 677325A GB 16784/48 A GB16784/48 A GB 16784/48A GB 1678448 A GB1678448 A GB 1678448A GB 677325 A GB677325 A GB 677325A
Authority
GB
United Kingdom
Prior art keywords
salts
sulphonic acid
phenol
oil
organic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB16784/48A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bataafsche Petroleum Maatschappij NV
Original Assignee
Bataafsche Petroleum Maatschappij NV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bataafsche Petroleum Maatschappij NV filed Critical Bataafsche Petroleum Maatschappij NV
Publication of GB677325A publication Critical patent/GB677325A/en
Expired legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M1/00—Liquid compositions essentially based on mineral lubricating oils or fatty oils; Their use as lubricants
    • C10M1/08—Liquid compositions essentially based on mineral lubricating oils or fatty oils; Their use as lubricants with additives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/14—Synthetic waxes, e.g. polythene waxes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/16—Paraffin waxes; Petrolatum, e.g. slack wax
    • C—CHEMISTRY; METALLURGY
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    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/17—Fisher Tropsch reaction products
    • C—CHEMISTRY; METALLURGY
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    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02—Hydroxy compounds
    • C10M2207/021—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
    • C—CHEMISTRY; METALLURGY
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    • C10M2207/02—Hydroxy compounds
    • C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
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    • C10M2207/025—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings with condensed rings
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    • C10M2207/026—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings with tertiary alkyl groups
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    • C10M2207/027—Neutral salts thereof
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    • C10M2207/121—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms
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    • C10M2207/121—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms
    • C10M2207/122—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms monocarboxylic
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    • C10M2207/123—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms polycarboxylic
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    • C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
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    • C10M2207/142—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings polycarboxylic
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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Abstract

A lubricating composition which is substantially non-corrosive comprises a major proportion of an aleaginous material and either (a) a polyvalent metal salt of an organic sulphonic acid together with an oxidation inhibitor, which is an arylamine and/or a phenol, in an amount less than one-sixth of the amount of the polyvalent metal salt of an organic sulphonic acid, or (b) a metal salt of a phenol formaldehyde condensation product, the metal salt in either case being present in a proportion greater than that which will give the composition an ash content of 0.8 per cent as determined according to the method of A.S.T.M. Designation ES-43a of 1945. Oleaginous materials mentioned are mineral oils, polymerized olefins, copolymers of alkylene glycols and alkylene oxides, organic esters (e.g. di-2-ethylhexyl sebacate, dioctyl phthalate or trioctyl phosphate), polymeric tetrahydrofuran and polyalkyl silicone polymers (e.g. dimethyl silicone polymer). Mixtures of oils may be employed and a minor proportion of a fatty oil such as castor oil or lard oil may be mixed with a hydrocarbon oil or with a hydrocarbon oil-synthetic oil mixture. Where the oleaginous material is an ester of an aliphatic dibasic acid of the type referred to in Specification 600,325, the use of mixture (a) is excluded. The metal salts which may be employed include both the normal salts and the basic salts. Mixtures of salts may be used. Suitable metal salts include the lithium and sodium salts of phenol formaldehyde condensation products, and the calcium, barium, magnesium, strontium, aluminium, tin, lead, vanadium, bismuth, chromium, molybdenum, manganese, iron, cobalt and nickel salts of both organic sulphonic acids and phenol formaldehyde condensation products. Examples of organic sulphonic acids, from which the polyvalent metal salts may be derived, are petroleum sulphonic acid, triisopropyl naphthalene sulphonic acid, diaryl naphthalene sulphonic acid, diwax benzene sulphonic acid, diwax naphthalene sulphonic acid, benzene disulphonic acid and lauryl sulphonic acid. Suitable phenol formaldehyde condensation products, the metal salts of which may be used, are octylphenol formaldehyde condensation products. Specific examples of suitable oxidation inhibitors of the arylamine type are phenyl-a- and b -naphthylamine. Preferred oxidation inhibitors of the phenol type are alkyl-substituted hydroxy aromatic compounds such as 2, 6-dimethylphenol, 2, 4-dimethyl-6-tert.-butylphenol, 2, 4-dimethyl-6-tert.-octylphenol and 2, 6-di-tert.-butyl-4-methylphenol. The lubricating composition may contain other oxidation or corrosion inhibitors, particularly organic carboxylic acids (e.g. gallic, tannic and octyl succinic acids), partial esters of polyhydric alcohols (e.g. glyceryl mono-oleate), sulphur compounds (e.g. sulphurized oleic acid and sulphurized sperm oil), phosphorus-containing compounds (e.g. triphenyl phosphite, tricresyl phosphate and lecithin), compounds containing both sulphur and nitrogen (e.g. dianiline disulphide), compounds containing both sulphur and phosphorus (e.g. the reaction products of phosphorus sulphide and a phenol or a poly-olefin), and halogen-containing organic compounds. In the examples, mineral lubricating oil compositions are described containing (1) normal or basic calcium petroleum sulphonate and phenyl-a-naphthylamine, (2) basic calcium petroleum sulphonate, phenyl-a-naphthylamine and 2, 6-di-tert.-butyl-4-methyl phenol and (3) calcium salt of an alkyl phenol formaldehyde condensation product. The Specification as open to inspection under Sect. 91 refers to a lubricating composition comprising a major proportion of an oleaginous material and a metallic salt of an acidic organic compound in a proportion that is greater than the amount at which the maximum corrosion and wear is caused by the presence of the salt. A list of suitable metallic salts and also a list of additional substances which may be present in the lubricating composition is given. In further examples, mineral lubricatin oil compositions are described which contain the calcium or barium salt of an alkyl phenol sulphide. This subject-matter does not appear in the Specification as accepted.
GB16784/48A 1947-07-01 1948-06-22 A lubricating composition Expired GB677325A (en)

Applications Claiming Priority (1)

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US758430A US2629693A (en) 1947-07-01 1947-07-01 Lubricating composition

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GB677325A true GB677325A (en) 1952-08-13

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US (1) US2629693A (en)
DE (1) DE875556C (en)
FR (1) FR968596A (en)
GB (1) GB677325A (en)
NL (2) NL71395C (en)

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GB779698A (en) * 1952-12-10 1957-07-24 Exxon Research Engineering Co Lubricant
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DE949589C (en) * 1953-09-17 1956-09-20 Wakefield & Co Ltd C C Lubricating oils
US2763613A (en) * 1953-10-29 1956-09-18 Shell Dev Lubricating oil containing dicyclopentadienyl iron and an oil soluble organic divalent metal salt
US2763617A (en) * 1953-10-29 1956-09-18 Shell Dev Lubricating oil containing dicyclopentadienyl iron and a wear inhibiting agent
US2882227A (en) * 1954-02-23 1959-04-14 Sinclair Refining Co Corrosion prevention method and composition
US2830950A (en) * 1954-06-18 1958-04-15 Continental Oil Co Lubricating compositions
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NL77062C (en) 1955-01-15
US2629693A (en) 1953-02-24
NL71395C (en) 1952-12-15
DE875556C (en) 1953-05-04
FR968596A (en) 1950-11-30

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