US1630101A - Rustproofing oil - Google Patents

Rustproofing oil Download PDF

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Publication number
US1630101A
US1630101A US15357A US1535725A US1630101A US 1630101 A US1630101 A US 1630101A US 15357 A US15357 A US 15357A US 1535725 A US1535725 A US 1535725A US 1630101 A US1630101 A US 1630101A
Authority
US
United States
Prior art keywords
oil
heavier
soap
rust
soaps
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US15357A
Inventor
Robert E Wilkin
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Standard Oil Co
Original Assignee
Standard Oil Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Standard Oil Co filed Critical Standard Oil Co
Priority to US15357A priority Critical patent/US1630101A/en
Application granted granted Critical
Publication of US1630101A publication Critical patent/US1630101A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M135/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing sulfur, selenium or tellurium
    • C10M135/08—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing sulfur, selenium or tellurium containing a sulfur-to-oxygen bond
    • C10M135/10—Sulfonic acids or derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31678—Of metal
    • Y10T428/31714—Next to natural gum, natural oil, rosin, lac or wax

Definitions

  • a highly effective rust preventing or slushing oil may be produced by the addition to a hydrocarbon oil heavier than gas oil of upwards of 3% of a soap of an oil-soluble sulfonic acid resulting from the treatment of petroleum oils with strong sulfuric acid (66 Baum fuming acid, for example).
  • a light hydrocarbon oil such as straw oil
  • 5% of such soaps preferably have prepared an oil which, in an exceedingly thin film on an iron or steel surface, shows no sign of rust after more than 10 days immersion in water, the water being changed daily.
  • soap may be employed.
  • the oil must be substantially water-free.
  • The-method of protecting ferrous metal surfaces-against rust and corrosion which consists in applying to the surface thereof a thin film of a hydrocarbon oil, heavier than gas oil, containing upwards of 3% of soaps of oil soluble sulfonic acids derived from the treament of petroleum oils with strong sulfonic acid.
  • the method of protecting ferrous metal surfaces from rust and corrosion which comprises applying to such surfaces a film of a hydrocarbon oil, heavier than gas oil, containing 3 to 35% of soaps of oil soluble sulfonic acids derived from the treatment of f petrolemn oils with strong sulfuric acid.
  • a highly effective rust preventing or slushing oil may be produced by the addition to a hydrocarbon oil heavier than gas oil of upwards of 3% of a soap of an oil-soluble sulfonic acid resulting from the treatment of petroleum oils with strong sulfuric acid (66 Baum fuming acid, for example).
  • a light hydrocarbon oil such as straw oil
  • 5% of such soaps preferably have prepared an oil which, in an exceedingly thin film on an iron or steel surface, shows no sign of rust after more than 10 days immersion in water, the water being changed daily.
  • soap may be employed.
  • the oil must be substantially water-free.
  • The-method of protecting ferrous metal surfaces-against rust and corrosion which consists in applying to the surface thereof a thin film of a hydrocarbon oil, heavier than gas oil, containing upwards of 3% of soaps of oil soluble sulfonic acids derived from the treament of petroleum oils with strong sulfonic acid.
  • the method of protecting ferrous metal surfaces from rust and corrosion which comprises applying to such surfaces a film of a hydrocarbon oil, heavier than gas oil, containing 3 to 35% of soaps of oil soluble sulfonic acids derived from the treatment of f petrolemn oils with strong sulfuric acid.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Description

' the soda soap), I
Patented May 24, 1927.
UNITED STATES PATENT OFFICE.
ROBERT E. WILKIN, OF
WRITING, INDIANA,
ASSIGNOR TO STANDARD OIL COMYANY,
BUSTPROOFING OIL.
No Drawing.
I have found that a highly effective rust preventing or slushing oil may be produced by the addition to a hydrocarbon oil heavier than gas oil of upwards of 3% of a soap of an oil-soluble sulfonic acid resulting from the treatment of petroleum oils with strong sulfuric acid (66 Baum fuming acid, for example). Thus, by the addition to a light hydrocarbon oil, such as straw oil, of 5% of such soaps (preferably have prepared an oil which, in an exceedingly thin film on an iron or steel surface, shows no sign of rust after more than 10 days immersion in water, the water being changed daily. I have also prepared oil with even better characteristics from a heavier lubricating oil (700 sec. Sayholt viscosit at 100 F.) by the addition 0 HM, of suct soap. From 3 to 35% of the Application flied March 13, 1925. Serial No. 15,357.
soap may be employed. The oil must be substantially water-free.
I claim:
1. The-method of protecting ferrous metal surfaces-against rust and corrosion which consists in applying to the surface thereof a thin film of a hydrocarbon oil, heavier than gas oil, containing upwards of 3% of soaps of oil soluble sulfonic acids derived from the treament of petroleum oils with strong sulfonic acid.
2. The method of protecting ferrous metal surfaces from rust and corrosion which comprises applying to such surfaces a film of a hydrocarbon oil, heavier than gas oil, containing 3 to 35% of soaps of oil soluble sulfonic acids derived from the treatment of f petrolemn oils with strong sulfuric acid.
ROBERT E. WILKIN.
CERTlFlGATE 0F CORRECTION.
Patent No. 1,630, 101.
Granted May 24, 1927, to
ROBERT E. WlLKlN.
It is hereby certified that error appears in the printed specification of the above numbered patent requiring correction as follows:
Line 30. claim 1, for
the word "sultonic" read "sulfuric"; and that the said Letters Patent should be read with this correction therein that the same may conform to the record of the case in the Patent Office.
Signed and sealed this 13th day of May, A. D. 1930.
(Seal) M. J. Moore, Acting Commissioner of Patents.
' the soda soap), I
Patented May 24, 1927.
UNITED STATES PATENT OFFICE.
ROBERT E. WILKIN, OF
WRITING, INDIANA,
ASSIGNOR TO STANDARD OIL COMYANY,
BUSTPROOFING OIL.
No Drawing.
I have found that a highly effective rust preventing or slushing oil may be produced by the addition to a hydrocarbon oil heavier than gas oil of upwards of 3% of a soap of an oil-soluble sulfonic acid resulting from the treatment of petroleum oils with strong sulfuric acid (66 Baum fuming acid, for example). Thus, by the addition to a light hydrocarbon oil, such as straw oil, of 5% of such soaps (preferably have prepared an oil which, in an exceedingly thin film on an iron or steel surface, shows no sign of rust after more than 10 days immersion in water, the water being changed daily. I have also prepared oil with even better characteristics from a heavier lubricating oil (700 sec. Sayholt viscosit at 100 F.) by the addition 0 HM, of suct soap. From 3 to 35% of the Application flied March 13, 1925. Serial No. 15,357.
soap may be employed. The oil must be substantially water-free.
I claim:
1. The-method of protecting ferrous metal surfaces-against rust and corrosion which consists in applying to the surface thereof a thin film of a hydrocarbon oil, heavier than gas oil, containing upwards of 3% of soaps of oil soluble sulfonic acids derived from the treament of petroleum oils with strong sulfonic acid.
2. The method of protecting ferrous metal surfaces from rust and corrosion which comprises applying to such surfaces a film of a hydrocarbon oil, heavier than gas oil, containing 3 to 35% of soaps of oil soluble sulfonic acids derived from the treatment of f petrolemn oils with strong sulfuric acid.
ROBERT E. WILKIN.
CERTlFlGATE 0F CORRECTION.
Patent No. 1,630, 101.
Granted May 24, 1927, to
ROBERT E. WlLKlN.
It is hereby certified that error appears in the printed specification of the above numbered patent requiring correction as follows:
Line 30. claim 1, for
the word "sultonic" read "sulfuric"; and that the said Letters Patent should be read with this correction therein that the same may conform to the record of the case in the Patent Office.
Signed and sealed this 13th day of May, A. D. 1930.
(Seal) M. J. Moore, Acting Commissioner of Patents.
US15357A 1925-03-13 1925-03-13 Rustproofing oil Expired - Lifetime US1630101A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US15357A US1630101A (en) 1925-03-13 1925-03-13 Rustproofing oil

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US15357A US1630101A (en) 1925-03-13 1925-03-13 Rustproofing oil

Publications (1)

Publication Number Publication Date
US1630101A true US1630101A (en) 1927-05-24

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US (1) US1630101A (en)

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2417281A (en) * 1944-11-10 1947-03-11 Standard Oil Dev Co Instrument lubricant
US2421672A (en) * 1944-01-21 1947-06-03 Union Oil Co Rust preventive composition
US2434490A (en) * 1944-12-30 1948-01-13 Standard Oil Dev Co Rust preventive lubricating oil compositions
US2467164A (en) * 1944-07-29 1949-04-12 Dow Chemical Co Acid inhibitors
US2533300A (en) * 1945-12-31 1950-12-12 Sinclair Refining Co Morpholine mahogany sulfonate as a rust inhibitor for petroleum oils
US2533303A (en) * 1947-10-09 1950-12-12 Sinclair Refining Co Prevention of rust
US2577626A (en) * 1947-06-20 1951-12-04 Standard Oil Dev Co Preventing corrosion of metals
US2583399A (en) * 1951-03-05 1952-01-22 Shell Dev Corrosion prevention method
US2586709A (en) * 1949-08-03 1952-02-19 Standard Oil Dev Co Method for suppressing the corrosion of copper-containing alloys in the presence of ammonium salts
US2629693A (en) * 1947-07-01 1953-02-24 Shell Dev Lubricating composition
US2764721A (en) * 1952-06-09 1956-09-25 Eleanor De Hass Johnson Electromagneto energy conversion
US2864726A (en) * 1955-11-17 1958-12-16 Pure Oil Co Protective coating for ferrous type metal
US4495225A (en) * 1984-03-21 1985-01-22 Economics Laboratory, Inc. Method and composition for the prevention or inhibition of corrosion
US4675215A (en) * 1985-09-27 1987-06-23 Economics Laboratory, Inc. Method and composition for the inhibition of corrosion
US4749412A (en) * 1985-09-27 1988-06-07 Drew Chemical Corporation Method and composition for the inhibition of corrosion

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2421672A (en) * 1944-01-21 1947-06-03 Union Oil Co Rust preventive composition
US2467164A (en) * 1944-07-29 1949-04-12 Dow Chemical Co Acid inhibitors
US2417281A (en) * 1944-11-10 1947-03-11 Standard Oil Dev Co Instrument lubricant
US2434490A (en) * 1944-12-30 1948-01-13 Standard Oil Dev Co Rust preventive lubricating oil compositions
US2533300A (en) * 1945-12-31 1950-12-12 Sinclair Refining Co Morpholine mahogany sulfonate as a rust inhibitor for petroleum oils
US2577626A (en) * 1947-06-20 1951-12-04 Standard Oil Dev Co Preventing corrosion of metals
US2629693A (en) * 1947-07-01 1953-02-24 Shell Dev Lubricating composition
US2533303A (en) * 1947-10-09 1950-12-12 Sinclair Refining Co Prevention of rust
US2586709A (en) * 1949-08-03 1952-02-19 Standard Oil Dev Co Method for suppressing the corrosion of copper-containing alloys in the presence of ammonium salts
US2583399A (en) * 1951-03-05 1952-01-22 Shell Dev Corrosion prevention method
US2764721A (en) * 1952-06-09 1956-09-25 Eleanor De Hass Johnson Electromagneto energy conversion
US2864726A (en) * 1955-11-17 1958-12-16 Pure Oil Co Protective coating for ferrous type metal
US4495225A (en) * 1984-03-21 1985-01-22 Economics Laboratory, Inc. Method and composition for the prevention or inhibition of corrosion
US4675215A (en) * 1985-09-27 1987-06-23 Economics Laboratory, Inc. Method and composition for the inhibition of corrosion
US4749412A (en) * 1985-09-27 1988-06-07 Drew Chemical Corporation Method and composition for the inhibition of corrosion

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