GB666644A - A process for the application of substances, particularly colouring matters and stabilisers, in or on reaction products of high molecular weight - Google Patents

A process for the application of substances, particularly colouring matters and stabilisers, in or on reaction products of high molecular weight

Info

Publication number
GB666644A
GB666644A GB23894/48A GB2389448A GB666644A GB 666644 A GB666644 A GB 666644A GB 23894/48 A GB23894/48 A GB 23894/48A GB 2389448 A GB2389448 A GB 2389448A GB 666644 A GB666644 A GB 666644A
Authority
GB
United Kingdom
Prior art keywords
allyl
butadiene
substances
sulphur dioxide
molecular weight
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB23894/48A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bataafsche Petroleum Maatschappij NV
Original Assignee
Bataafsche Petroleum Maatschappij NV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bataafsche Petroleum Maatschappij NV filed Critical Bataafsche Petroleum Maatschappij NV
Publication of GB666644A publication Critical patent/GB666644A/en
Expired legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/02—Material containing basic nitrogen
    • D06P3/04—Material containing basic nitrogen containing amide groups
    • D06P3/06—Material containing basic nitrogen containing amide groups using acid dyes
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/02—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D01F6/24—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds from polymers of aliphatic compounds with more than one carbon-to-carbon double bond
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
    • D06P1/642—Compounds containing nitrogen
    • D06P1/649—Compounds containing carbonamide, thiocarbonamide or guanyl groups
    • D06P1/6491—(Thio)urea or (cyclic) derivatives
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/90—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dyes dissolved in organic solvents or aqueous emulsions thereof
    • D06P1/92—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dyes dissolved in organic solvents or aqueous emulsions thereof in organic solvents
    • D06P1/922—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dyes dissolved in organic solvents or aqueous emulsions thereof in organic solvents hydrocarbons
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/90—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dyes dissolved in organic solvents or aqueous emulsions thereof
    • D06P1/92—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dyes dissolved in organic solvents or aqueous emulsions thereof in organic solvents
    • D06P1/928—Solvents other than hydrocarbons
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Artificial Filaments (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Pyridine Compounds (AREA)
  • Plural Heterocyclic Compounds (AREA)

Abstract

The reaction products of sulphur dioxide with polymers and copolymers of conjugated dienes having a molecular weight greater than 5000 are treated with colouring matters or textile assistants while the reaction products are in the swollen state. The textile assistants are defined as stabilizers, or compounds which improve moisture absorption, render the product water-repellent, reduce combustibility, or affect the gloss or the handle of the reaction product. The polymerized substances may be polymers of butadiene p and pentadiene, methyl butadiene, dimethyl butadiene, and chloro-prene, and copolymers of these substances with isobutylene, styrene, vinyl chloride, vinyl esters, acrylic acid, methacrylic acid, acrylonitrile, or methacrylonitrile. The polymerized substances may be reacted with sulphur dioxide in the presence of a low molecular weight unsaturated compound such as butadiene, 1,5-hexadiene, allyl alcohol, allyl chloride, allyl acetate, allyl capronate, allyl isothiocyanate, allyl oleate, o-diallyl phthalate or diallyl adipate. Swelling is preferably effected by reacting the sulphur dioxide and polymerized material in solvents such as ethanol and a mixture of benzene and toluene respectively, alternatively, after reaction, swelling may be effected to a lesser extent with the aid of dichloroethane or chloroform, or by sulphuric acid, phosphoric acid or a solution of caustic soda. Specification 666,640, [Group V], is referred to.ALSO:The reaction products of sulphur dioxide with polymers and copolymers of conjugated dienes having a molecular weight greater than 5000 are treated with colouring matters or textile assistants while the reaction products are in the swollen state. The textile assistants are defined as stabilizers, or compounds which improve moisture absorption, render the product water-repellent, reduce combustibility, or affect the gloss or the handle of the reaction product. The polymerized substances may be natural rubber, polymers of butadiene and pentadiene, methyl butadiene, dimethyl butadiene, and chloroprene, and copolymers of these substances with isobutylene, styrene, vinyl chloride, vinyl esters, acrylic acid, methacrylic acid, acrylonitrile, or methacrylonitrile. The polymerized substances may be reacted with sulphur dioxide in the presence of a low molecular weight unsaturated compound such as butadiene, 1,5-hexadiene, allyl alcohol, allyl chloride, allyl acetate, allyl capronate, allyl isothiocyanate, allyl oleate, O-diallyl phthalate or diallyl adipate. Swelling is preferably effected by reacting the sulphur dioxide and polymerized material in solvents such as ethanol and a mixture of benzene and toluene respectively, alternatively after reaction swelling may be effected to a lesser extent with the aid of dichloroethane or chloroform, or by sulphuric acid, phosphoric acid or a solution of caustic soda. In examples a swollen thread was produced by spinning by extrusion at -5 DEG C., the reaction product of a solution of rubber and tetraline peroxide in benzene and toluene, and sulphur dioxide in alcohol, and this thread was then soaked in a bath containing either "Supraminrot B" or "Noir acetoquinone N.BN" or Congo Red in water, or "Oil Orange N" in benzene, or in N, N1 diphenyl thiourea in ethanol. Specification 666,640, [Group V], is referred to.
GB23894/48A 1948-04-16 1948-09-10 A process for the application of substances, particularly colouring matters and stabilisers, in or on reaction products of high molecular weight Expired GB666644A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
NL139976A NL71108C (en) 1948-04-16 1948-04-16

Publications (1)

Publication Number Publication Date
GB666644A true GB666644A (en) 1952-02-13

Family

ID=40561747

Family Applications (3)

Application Number Title Priority Date Filing Date
GB23894/48A Expired GB666644A (en) 1948-04-16 1948-09-10 A process for the application of substances, particularly colouring matters and stabilisers, in or on reaction products of high molecular weight
GB15519/50A Expired GB680492A (en) 1948-04-16 1950-06-21 Process for the application of substances, in particular dye-stuffs and stabilizers, in or on reaction products of macro-molecular, poly-unsaturated compounds with sulphur dioxide
GB15518/50A Expired GB680491A (en) 1948-04-16 1950-06-21 Process for the incorporation or application of substances, in particular dye-stuffsand stabilizers, in or on to reaction products of sulphur dioxide with polymers or co-polymers of conjugated dienes

Family Applications After (2)

Application Number Title Priority Date Filing Date
GB15519/50A Expired GB680492A (en) 1948-04-16 1950-06-21 Process for the application of substances, in particular dye-stuffs and stabilizers, in or on reaction products of macro-molecular, poly-unsaturated compounds with sulphur dioxide
GB15518/50A Expired GB680491A (en) 1948-04-16 1950-06-21 Process for the incorporation or application of substances, in particular dye-stuffsand stabilizers, in or on to reaction products of sulphur dioxide with polymers or co-polymers of conjugated dienes

Country Status (5)

Country Link
DE (1) DE875406C (en)
FR (3) FR971620A (en)
GB (3) GB666644A (en)
LU (1) LU29203A1 (en)
NL (1) NL71108C (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1060215A (en) * 1952-07-08 1954-03-31 Rhodiaceta New process for coloring yarns in polymers or copolymers based on acrylonitrile

Also Published As

Publication number Publication date
FR971620A (en) 1951-01-19
GB680492A (en) 1952-10-08
FR60687E (en) 1954-11-22
FR60432E (en) 1954-11-02
NL71108C (en) 1952-01-15
GB680491A (en) 1952-10-08
DE875406C (en) 1953-05-04
LU29203A1 (en)

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