GB654273A - Improvements in polymeric materials and in processes for their production - Google Patents
Improvements in polymeric materials and in processes for their productionInfo
- Publication number
- GB654273A GB654273A GB766548A GB766548A GB654273A GB 654273 A GB654273 A GB 654273A GB 766548 A GB766548 A GB 766548A GB 766548 A GB766548 A GB 766548A GB 654273 A GB654273 A GB 654273A
- Authority
- GB
- United Kingdom
- Prior art keywords
- hydrazine
- polymer
- links
- heating
- ammonia
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
- C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
- C08G73/08—Polyhydrazides; Polytriazoles; Polyaminotriazoles; Polyoxadiazoles
Abstract
The resistance to hydrolysis of linear polymers which contain a substantial proportion of hydrazide (-CO.NH.NH.CO-) or 1,3,4-oxdiazole <FORM:0654273/IV (a)/1> links, is increased by heating them with hydrazine or ammonia. The links are converted to the unsubstituted, or 4 substituted, 1,2,4-triazole type. The initial polymer may be made by reacting a dicarboxylic acid or derivative thereof with 1 to 2 moles of hydrazine for each mole of acid. The treated polymer, preferably in its final form of filament, fibre or film, may be further treated with a polyfunctional after-treating agent, such as the acylating agents or aldehydes described in Specification 613,497. In examples: (1) a hydrolysable polymer was prepared by heating mono-hydrazine sebacate under nitrogen and then heated in an autoclave with (2) aqueous hydrazine hydrate, or (3) aqueous ammonia. Specifications 612,609 and 613,020 also are referred to.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB766548A GB654273A (en) | 1948-03-12 | 1948-03-12 | Improvements in polymeric materials and in processes for their production |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB766548A GB654273A (en) | 1948-03-12 | 1948-03-12 | Improvements in polymeric materials and in processes for their production |
Publications (1)
Publication Number | Publication Date |
---|---|
GB654273A true GB654273A (en) | 1951-06-13 |
Family
ID=9837460
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB766548A Expired GB654273A (en) | 1948-03-12 | 1948-03-12 | Improvements in polymeric materials and in processes for their production |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB654273A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3031779A (en) * | 1958-06-12 | 1962-05-01 | Gar Wood Ind Inc | Front-mounted power control unit for bulldozer |
US3357956A (en) * | 1965-03-30 | 1967-12-12 | Du Pont | Polymeric 1, 3, 4-thiadiazoles and the process for their preparation |
-
1948
- 1948-03-12 GB GB766548A patent/GB654273A/en not_active Expired
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3031779A (en) * | 1958-06-12 | 1962-05-01 | Gar Wood Ind Inc | Front-mounted power control unit for bulldozer |
US3357956A (en) * | 1965-03-30 | 1967-12-12 | Du Pont | Polymeric 1, 3, 4-thiadiazoles and the process for their preparation |
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