GB595065A - Process for the production of water-soluble condensation products, and the resulting products - Google Patents
Process for the production of water-soluble condensation products, and the resulting productsInfo
- Publication number
- GB595065A GB595065A GB12196/44A GB1219644A GB595065A GB 595065 A GB595065 A GB 595065A GB 12196/44 A GB12196/44 A GB 12196/44A GB 1219644 A GB1219644 A GB 1219644A GB 595065 A GB595065 A GB 595065A
- Authority
- GB
- United Kingdom
- Prior art keywords
- water
- amino
- diaminostilbene
- bis
- triazinyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000047 product Substances 0.000 title abstract 4
- 239000007859 condensation product Substances 0.000 title abstract 2
- 238000004519 manufacturing process Methods 0.000 title 1
- 238000000034 method Methods 0.000 title 1
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 abstract 9
- 239000002253 acid Substances 0.000 abstract 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract 4
- 239000007858 starting material Substances 0.000 abstract 3
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 abstract 2
- 239000012670 alkaline solution Substances 0.000 abstract 2
- 229910021529 ammonia Inorganic materials 0.000 abstract 2
- -1 m - sulphophenyl- Chemical group 0.000 abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 2
- JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical group C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 abstract 1
- GOJUJUVQIVIZAV-UHFFFAOYSA-N 2-amino-4,6-dichloropyrimidine-5-carbaldehyde Chemical group NC1=NC(Cl)=C(C=O)C(Cl)=N1 GOJUJUVQIVIZAV-UHFFFAOYSA-N 0.000 abstract 1
- ZAJAQTYSTDTMCU-UHFFFAOYSA-N 3-aminobenzenesulfonic acid Chemical compound NC1=CC=CC(S(O)(=O)=O)=C1 ZAJAQTYSTDTMCU-UHFFFAOYSA-N 0.000 abstract 1
- XFDUHJPVQKIXHO-UHFFFAOYSA-N 3-aminobenzoic acid Chemical compound NC1=CC=CC(C(O)=O)=C1 XFDUHJPVQKIXHO-UHFFFAOYSA-N 0.000 abstract 1
- 125000003277 amino group Chemical group 0.000 abstract 1
- 239000007864 aqueous solution Substances 0.000 abstract 1
- 238000009835 boiling Methods 0.000 abstract 1
- 230000005494 condensation Effects 0.000 abstract 1
- 238000009833 condensation Methods 0.000 abstract 1
- 238000004043 dyeing Methods 0.000 abstract 1
- 150000004820 halides Chemical class 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 230000007935 neutral effect Effects 0.000 abstract 1
- 239000011368 organic material Substances 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 abstract 1
- 239000011780 sodium chloride Substances 0.000 abstract 1
- 159000000000 sodium salts Chemical class 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- 125000001424 substituent group Chemical group 0.000 abstract 1
- 239000004753 textile Substances 0.000 abstract 1
- 239000004552 water soluble powder Substances 0.000 abstract 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/39—Aldehyde resins; Ketone resins; Polyacetals
- D06M15/423—Amino-aldehyde resins
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Plural Heterocyclic Compounds (AREA)
- Coloring (AREA)
Abstract
Water-soluble condensation products are prepared by reacting formaldehyde or a substance, e.g. a polymer thereof which yields formaldehyde under the reaction conditions in neutral or alkaline solution with an N : N1-bis-[1,3,5-triazinyl-(6)] derivative of 4,41-diaminostilbene-2,21-disulphonic acid, the triazine rings each containing at least one free amino group and, if desired, further substituents comprising one or more water-solubilizing groups. The products have good affinity for cellulosic materials and may be used to improve the fastness to water of dyeings, for textile dressings, e.g. crease-proof dressings resistant to boiling water. The products exhibit in ultra-violet light strong blue-white fluorescence and may be used to brighten or lighten the appearance of organic materials having a white to yellowish white appearance. The examples describe the condensation with 30 per cent formaldehyde of (1) and (2) 4 : 41-(N.N1-bis-[2,4-diamino-1,3,5-triazinyl-(6)]) -diaminostilbene-2,21-disulphonic acid in weakly alkaline solution. The product can be used in aqueous solution or can be precipitated as a water-soluble powder by addition of sodium chloride; (3) 4,41-(N.N1-bis-[2 - amino - 4 - (m - sulphophenyl-) amino- 1,3,5-triazinyl - (6)])-diaminostilbene-2,21-disulphonic acid; (4) 4,41-(N,N1-bis-[2-amino-4-(m-carboxyphenyl-)amino - 1,3,5 - triazynl - (6)]) - diaminostilbene-2,21-disulphonic acid. The starting material of examples (1) and (2) is obtained from the sodium salt of 4,41-diaminostilbene-2,21-disulphonic acid and 2 molecular proportions of cyanuric halide. Further reaction with ammonia and 1-aminobenzene-3-sulphonic acid yields the starting material of example (3) or with ammonia and 1-aminobenzene-3-carboxylic acid the starting material of example (4). It is stated that the 2-amino-4-phenylamino-1,3,5-triazinyl derivative may be similarly prepared. U.S.A. Specification 2,089,413 is referred to.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH595065X | 1943-06-28 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB595065A true GB595065A (en) | 1947-11-26 |
Family
ID=4522378
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB12196/44A Expired GB595065A (en) | 1943-06-28 | 1944-06-27 | Process for the production of water-soluble condensation products, and the resulting products |
Country Status (5)
| Country | Link |
|---|---|
| CH (1) | CH237394A (en) |
| FR (1) | FR905534A (en) |
| GB (1) | GB595065A (en) |
| IT (1) | IT421447A (en) |
| NL (1) | NL62874C (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3072454A (en) * | 1960-07-07 | 1963-01-08 | American Cyanamid Co | Reactive dyes containing methylolamide triazine groups |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2703801A (en) * | 1955-03-08 | Fluorescent agents | ||
| GB718119A (en) * | 1951-12-07 | 1954-11-10 | Ilford Ltd | Improvements in or relating to a process for improving the whiteness or colour of materials |
| TWI252270B (en) * | 2000-07-20 | 2006-04-01 | Ciba Sc Holding Ag | A method for the fluorescent whitening of cotton |
-
0
- NL NL62874D patent/NL62874C/xx active
- IT IT421447D patent/IT421447A/it unknown
-
1943
- 1943-06-28 CH CH237394D patent/CH237394A/en unknown
-
1944
- 1944-06-27 FR FR905534D patent/FR905534A/en not_active Expired
- 1944-06-27 GB GB12196/44A patent/GB595065A/en not_active Expired
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3072454A (en) * | 1960-07-07 | 1963-01-08 | American Cyanamid Co | Reactive dyes containing methylolamide triazine groups |
Also Published As
| Publication number | Publication date |
|---|---|
| IT421447A (en) | |
| FR905534A (en) | 1945-12-06 |
| CH237394A (en) | 1945-04-30 |
| NL62874C (en) |
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