US548346A - Arthur ash worth and joshua burger - Google Patents
Arthur ash worth and joshua burger Download PDFInfo
- Publication number
- US548346A US548346A US548346DA US548346A US 548346 A US548346 A US 548346A US 548346D A US548346D A US 548346DA US 548346 A US548346 A US 548346A
- Authority
- US
- United States
- Prior art keywords
- arthur
- joshua
- burger
- worth
- ash
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 235000015220 hamburgers Nutrition 0.000 title 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-M bisulfite Chemical class OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 10
- YXAOOTNFFAQIPZ-UHFFFAOYSA-N 1-nitrosonaphthalen-2-ol Chemical compound C1=CC=CC2=C(N=O)C(O)=CC=C21 YXAOOTNFFAQIPZ-UHFFFAOYSA-N 0.000 description 8
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 8
- 238000004043 dyeing Methods 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- BVKZGUZCCUSVTD-UHFFFAOYSA-N Carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 4
- VYZAMTAEIAYCRO-UHFFFAOYSA-N chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 229910052742 iron Inorganic materials 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- KJCVRFUGPWSIIH-UHFFFAOYSA-N 1-Naphthol Chemical compound C1=CC=C2C(O)=CC=CC2=C1 KJCVRFUGPWSIIH-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 239000003518 caustics Substances 0.000 description 2
- 150000008049 diazo compounds Chemical class 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- KEAYESYHFKHZAL-UHFFFAOYSA-N sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- DWAQJAXMDSEUJJ-UHFFFAOYSA-M sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 description 2
- 229940001607 sodium bisulfite Drugs 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 description 2
- 235000011121 sodium hydroxide Nutrition 0.000 description 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-N sulfonic acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 2
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C205/00—Compounds containing nitro groups bound to a carbon skeleton
- C07C205/13—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by hydroxy groups
- C07C205/20—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by hydroxy groups having nitro groups and hydroxy groups bound to carbon atoms of six-membered aromatic rings
- C07C205/21—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by hydroxy groups having nitro groups and hydroxy groups bound to carbon atoms of six-membered aromatic rings having nitro groups and hydroxy groups bound to carbon atoms of the same non-condensed six-membered aromatic ring
- C07C205/22—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by hydroxy groups having nitro groups and hydroxy groups bound to carbon atoms of six-membered aromatic rings having nitro groups and hydroxy groups bound to carbon atoms of the same non-condensed six-membered aromatic ring having one nitro groups bound to the ring
Definitions
- the new product is very valuable for dyeing and printing purposes, producing with iron mordants valuable green and with chrome mordants brown shades.
- the new dye consisting of grayish to white crystals being easily soluble in water which solution is at first colorless growing darker on standing, is decomposed on addition of caustic alkalies producing green shades with iron mordants and brown shades with chrome mordants and having the properties substantially as heretofore set forth.
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Coloring (AREA)
Description
UNITED STATES PATENT OFFICE.
ARTHUR ASHWORTH AND JOSHUA BURGER, OF MANCHESTER, ENGLAND.
NITROSONAPHTHOL DYE AND PROCESS OF MAKING SAME.
SPECIFICATION forming part of Letters Patent No. 548,346, dated October 22, 1895. Application filed August 2, 1894- Serial No. 519,268. (Specimens) Patented in England June 12, 1898, No. 11,556.
To aZZ whom it may concern.-
Be it known that we, ARTHUR AsHWoRTH and JOSHUA Bl 'RGER,Of Manchester, England, have invented a new and useful Method for the Production of new Coloring-Matters Suitable for Dyeing and Printing, (for which a patent has been received in England, No. 11,556, dated June 12, 1893,) of which the following is a specification.
It has been known some time that by the energetic action of sulphurous acid and its salts on nitrosobetanaphthol an amidonaphtholsulfonic acid was produced. We have, however, discovered that by the moderate action of bisulfites another product is obtained which is of great technical value. To prepare this product, we proceed in the following manner: One part, by weight, of nitrosobetanaphtho], by preference in form ofa finely-divided paste, is mixed with two parts, by Weight, of a solution of bisulfite, of soda of about 60 Twaddle, and the mixture is gently heated on the water-bath to about to centigrade, being continuously stirred. When the nitrosobetanaphthol begins to dissolve, the external heating is discontinued and there is a rise in temperature of about 20 centigrade. After some time the whole mass solidifies,forming a paste of silver-gray crystals, which are our new product. The crystals are filtered,
- pressed, and preferably used as a paste.
In this invention we do not limit ourselves to the use of bisulfite of soda; but other bisulfites acting in the same mannercan be used.
Our new compound is easily soluble in Water, forming a colorless solution, which, however, after standing for some time grows darker.
Addition of caustic soda decomposes the aqueous solution, producing a greenprecipitate of the sodium saltof nitrosobetanaphthol.
The new product is very valuable for dyeing and printing purposes, producing with iron mordants valuable green and with chrome mordants brown shades.
The new product of combination between alpha-nitrosobetanaphthol and sodium bisulfite combines with diazo compounds, producing coloring-matters (dyeing, and printing) with mordants, which, however, we do not claim herein, as they form the subject of application, Serial No. 514,096, filed June 9, 1894.
What we claim as new is v 1. The method of producing a new compound which consists in treating nitrosobeta- NOH naphthol with bisulfites at a temperature of about 40 to 50 centigrade, substantially as heretofore set forth.
2. The new dye consisting of grayish to white crystals being easily soluble in water which solution is at first colorless growing darker on standing, is decomposed on addition of caustic alkalies producing green shades with iron mordants and brown shades with chrome mordants and having the properties substantially as heretofore set forth.
ARTHUR ASH'WORTH. JOSHUA BURGER. Witnesses:
ARTHUR O. HALL, JOHN W. THOMAS.
Publications (1)
Publication Number | Publication Date |
---|---|
US548346A true US548346A (en) | 1895-10-22 |
Family
ID=2617089
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US548346D Expired - Lifetime US548346A (en) | Arthur ash worth and joshua burger |
Country Status (1)
Country | Link |
---|---|
US (1) | US548346A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2841078A (en) * | 1953-03-02 | 1958-07-01 | Comstock & Wescott | Photographic color correction in imbibition printing |
-
0
- US US548346D patent/US548346A/en not_active Expired - Lifetime
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2841078A (en) * | 1953-03-02 | 1958-07-01 | Comstock & Wescott | Photographic color correction in imbibition printing |
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