GB651657A - A process for the concentration of partially polymerised esters - Google Patents
A process for the concentration of partially polymerised estersInfo
- Publication number
- GB651657A GB651657A GB10494/48A GB1049448A GB651657A GB 651657 A GB651657 A GB 651657A GB 10494/48 A GB10494/48 A GB 10494/48A GB 1049448 A GB1049448 A GB 1049448A GB 651657 A GB651657 A GB 651657A
- Authority
- GB
- United Kingdom
- Prior art keywords
- phases
- polymer
- isopropanol
- liquids
- ester
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F18/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
- C08F18/02—Esters of monocarboxylic acids
- C08F18/04—Vinyl esters
- C08F18/08—Vinyl acetate
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
Polymers of a polymerizable organic ester which, when completely polymerized, gives rise to cross linkage between polymer molecules, are concentrated by contacting a partial polymer of the ester with a mixture of two liquids so as to form two phases, the proportion in which the polymer is divided between the two phases being different from the proportion in which the unpolymerized ester is divided between the two phases and separating the two phases. The process is particularly applicable to diallyl phthalate which preferably is polymerized to an extent of from 20 to 40 per cent. The two liquids may be acetone and water, benzene and isopropanol, acetone and isopropanol, methyl ethyl ketone and water, methyl ethyl ketone and isopropanol, or toluene and methyl alcohol. After separation of the two phases the lower phase, which contains most of the polymer, may be treated with a fresh quantity of a mixture of the same two liquids again to form two phases, and the phases formed then separated.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US651657XA | 1947-04-21 | 1947-04-21 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB651657A true GB651657A (en) | 1951-04-04 |
Family
ID=22060759
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB10494/48A Expired GB651657A (en) | 1947-04-21 | 1948-04-15 | A process for the concentration of partially polymerised esters |
Country Status (4)
Country | Link |
---|---|
BE (1) | BE481995A (en) |
DE (1) | DE840762C (en) |
FR (1) | FR965013A (en) |
GB (1) | GB651657A (en) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BE590472A (en) * | 1959-05-06 | |||
DE1123111B (en) * | 1960-10-26 | 1962-02-01 | Goldschmidt Ag Th | Process for the polymerization of allyl esters of saturated polybasic acids |
CH431998A (en) * | 1963-10-25 | 1967-03-15 | Ciba Geigy | Process for the preparation of solutions of prepolymers of a diallyl phthalate |
-
0
- FR FR965013D patent/FR965013A/fr not_active Expired
- BE BE481995D patent/BE481995A/xx unknown
-
1948
- 1948-04-15 GB GB10494/48A patent/GB651657A/en not_active Expired
- 1948-10-02 DE DEP14717A patent/DE840762C/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
DE840762C (en) | 1952-06-23 |
FR965013A (en) | 1950-08-31 |
BE481995A (en) |
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