GB651420A - Improvements in or relating to emulsions of copolymers of methyl methacrylate and tothe use of such emulsions - Google Patents
Improvements in or relating to emulsions of copolymers of methyl methacrylate and tothe use of such emulsionsInfo
- Publication number
- GB651420A GB651420A GB445248A GB445248A GB651420A GB 651420 A GB651420 A GB 651420A GB 445248 A GB445248 A GB 445248A GB 445248 A GB445248 A GB 445248A GB 651420 A GB651420 A GB 651420A
- Authority
- GB
- United Kingdom
- Prior art keywords
- sodium
- methyl
- methyl methacrylate
- emulsion
- lauryl sulphate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0016—Plasticisers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Treatment And Processing Of Natural Fur Or Leather (AREA)
Abstract
A coating and impregnating composition, especially for leather, comprises an aqueous emulsion of a copolymer of methyl methacrylate and styrene containing 1 to 60 per cent of styrene and a non-polar poasticizer, i.e. a compound having a low polarity and comprising a polar group and a hydrocarbon chain of at least 8 carbon atoms, e.g. methyl acetyl-, butyl acetyl- and methyl phthalyl-methyl ricinoleates, dibutyl sebacate and di-(ethylhexyl)-phthalates. The plasticizer may be added to the monomeric mixture before or after emulsification and subsequent polymerization, e.g. as described in Specification 607,704, or it may be emulsified with the copolymer emulsion, e.g. as a separate emulsion. Examples describe the emulsion polymerization of equal weights of methyl methacrylate and styrene in the presence of the plasticizer and (1) wool wax alcohols, sodium lauryl sulphate and hydrogen peroxide; (2), (3), (4) sodium persulphate, sodium lauryl sulphate, the sodium methacrylate-methyl methacrylate copolymer described in Specification 648,001 and aqueous ammonia; (5) the sodium salt of dibutyl naphthalene sulphonic acid; and (6) a sodium alkyl benzene sulphonate in place of sodium lauryl sulphate.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB445248A GB651420A (en) | 1948-02-16 | 1948-02-16 | Improvements in or relating to emulsions of copolymers of methyl methacrylate and tothe use of such emulsions |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB445248A GB651420A (en) | 1948-02-16 | 1948-02-16 | Improvements in or relating to emulsions of copolymers of methyl methacrylate and tothe use of such emulsions |
Publications (1)
Publication Number | Publication Date |
---|---|
GB651420A true GB651420A (en) | 1951-04-04 |
Family
ID=9777447
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB445248A Expired GB651420A (en) | 1948-02-16 | 1948-02-16 | Improvements in or relating to emulsions of copolymers of methyl methacrylate and tothe use of such emulsions |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB651420A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1235496B (en) * | 1962-01-11 | 1967-03-02 | Bayer Ag | Process for treating leather |
US4190687A (en) | 1972-05-09 | 1980-02-26 | Sumitomo Chemical Company, Limited | Method for treating leather |
-
1948
- 1948-02-16 GB GB445248A patent/GB651420A/en not_active Expired
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1235496B (en) * | 1962-01-11 | 1967-03-02 | Bayer Ag | Process for treating leather |
US4190687A (en) | 1972-05-09 | 1980-02-26 | Sumitomo Chemical Company, Limited | Method for treating leather |
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