GB646171A - Manufacture of vat dyestuffs - Google Patents

Manufacture of vat dyestuffs

Info

Publication number
GB646171A
GB646171A GB30578/47A GB3057847A GB646171A GB 646171 A GB646171 A GB 646171A GB 30578/47 A GB30578/47 A GB 30578/47A GB 3057847 A GB3057847 A GB 3057847A GB 646171 A GB646171 A GB 646171A
Authority
GB
United Kingdom
Prior art keywords
benzoic acid
quinoline
pyridine
amino
acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB30578/47A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF Schweiz AG
Original Assignee
Ciba AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ciba AG filed Critical Ciba AG
Publication of GB646171A publication Critical patent/GB646171A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09BORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B1/00Dyes with anthracene nucleus not condensed with any other ring
    • C09B1/16Amino-anthraquinones
    • C09B1/20Preparation from starting materials already containing the anthracene nucleus
    • C09B1/36Dyes with acylated amino groups
    • C09B1/44Dyes with acylated amino groups the acyl groups being residues of a heterocyclic carboxylic acid

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Benzoic acid - 4 - (N - dimethyl) - sulphonamide, benzoic acid - 4 - sulphopiperidide, and benzoic acid - 4 - sulphomorpholide are converted to their acid chlorides by reaction with thionyl chloride.ALSO:1 - Acylamino - 4 - [(N - dialkyl) - sulphonamidobenzoylamino] - anthraquinones or 1-acylamino - 4 - [(N - dialkylene) - sulphonamidobenzoylamino]-anthraquinones in which the alkylene residues are interconnected to form a ring, are made by a process wherein a 1-amino-4-acylaminoanthraquinone is treated with an acylating agent, and these reactants are so chosen that the product contains in one amino group the residue of a pyridine carboxylic acid or of a quinoline carboxylic acid and in the other amino group the residue of an N-dialkylsulphonamido-benzoic acid or of an N-dialkylene sulphonamido-benzoic acid in which the alkylene residues are interconnected to form a ring. The anthraquinone may contain a further substituent, e.g. a b -halogen atom. The 1-amino - 4 - acylaminoanthraquinones may be prepared by acylation of a 1-nitro-4-aminoanthraquinone, and reduction of the nitro group. The products dye wool, silk, cotton, linen, regenerated cellulose, and polyvinyl fibres pink shades. In examples: 1-(p-sulphodimethylamido - benzoylamino) - 4 - aminoanthraquinone is reacted with (1) pyridine-b -carboxylic acid chloride, and (2) quinoline-6-carboxylic acid chloride, and (3) the corresponding 7-chloranthraquinone is reacted with quinoline - 6 - carboxylic acid chloride. Also in examples, benzoic acid 4-(N-dimethyl)-sulphonamide, benzoic acid 4-sulphopiperidide, and benzoic acid 4-sulphomorpholide are each connected to their chlorides and these are reacted with (4) 1 - (pyridine - 31 - carboylamino)-, and (5) 1 - (quinoline - 61 - carboylamino) - 4-amino - 6 - chloranthraquinone. Other products are listed. The Specification as open extended to heterocyclic carboxylic acids generally as well as pyridine and quinoline carboxylic acids, and specified thiophene and furane carboxylic acids.
GB30578/47A 1946-11-18 1947-11-18 Manufacture of vat dyestuffs Expired GB646171A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CH646171X 1946-11-18

Publications (1)

Publication Number Publication Date
GB646171A true GB646171A (en) 1950-11-15

Family

ID=4525772

Family Applications (1)

Application Number Title Priority Date Filing Date
GB30578/47A Expired GB646171A (en) 1946-11-18 1947-11-18 Manufacture of vat dyestuffs

Country Status (1)

Country Link
GB (1) GB646171A (en)

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