GB640120A - Improvements in or relating to the polymerisation of vinyl and vinylidene chlorides - Google Patents

Improvements in or relating to the polymerisation of vinyl and vinylidene chlorides

Info

Publication number
GB640120A
GB640120A GB9298/48A GB929848A GB640120A GB 640120 A GB640120 A GB 640120A GB 9298/48 A GB9298/48 A GB 9298/48A GB 929848 A GB929848 A GB 929848A GB 640120 A GB640120 A GB 640120A
Authority
GB
United Kingdom
Prior art keywords
vinyl
mono
oleate
pentaerythritol
monolaurate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB9298/48A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
KENNETH HENRY CHARLES BESSANT
Distillers Co Yeast Ltd
Distillers Co Ltd
Original Assignee
KENNETH HENRY CHARLES BESSANT
Distillers Co Yeast Ltd
Distillers Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by KENNETH HENRY CHARLES BESSANT, Distillers Co Yeast Ltd, Distillers Co Ltd filed Critical KENNETH HENRY CHARLES BESSANT
Priority to GB9298/48A priority Critical patent/GB640120A/en
Priority to FR983366D priority patent/FR983366A/en
Priority to DEP38462A priority patent/DE833856C/en
Publication of GB640120A publication Critical patent/GB640120A/en
Priority to GB12576/51A priority patent/GB711355A/en
Priority to FR62856D priority patent/FR62856E/en
Priority to DED12317A priority patent/DE948359C/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F14/02—Monomers containing chlorine
    • C08F14/04—Monomers containing two carbon atoms
    • C08F14/06—Vinyl chloride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F14/02—Monomers containing chlorine
    • C08F14/04—Monomers containing two carbon atoms
    • C08F14/08—Vinylidene chloride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/12—Polymerisation in non-solvents
    • C08F2/16—Aqueous medium
    • C08F2/20—Aqueous medium with the aid of macromolecular dispersing agents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F214/02—Monomers containing chlorine
    • C08F214/04—Monomers containing two carbon atoms
    • C08F214/08—Vinylidene chloride

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
  • Polymerisation Methods In General (AREA)

Abstract

Polymers and copolymers of vinyl chloride and vinylidene chloride are made by polymerizing the monomer or monomers, in aqueous dispersion, in the presence, as a dispersing agent, of up to 5 per cent of a partial ester of a polyhydric alcohol having a maximum of 10 hydroxy groups in the molecule with a fatty acid having at least 4 carbon atoms in the molecule, separating the polymeric material and drying without any intermediate washing step. The partial ester may be condensed with ethylene oxide. Comonomers specified are acrylonitrile, methacrylonitrile, crotonitrile, methyl and ethyl vinyl ketones, cyclohexyl methacrylate, methyl methacrylate, butyl acrylate, dicyclohexyl maleate, butyl itaconate, cyclohexyl itaconate, diethyl itaconate, dibutyl fumarate, vinyl fluoride, vinyl acetate, vinyl methoxybutyrate and vinyl benzoate. The specified partial esters are glyceryl monocaprate, -stearate, -laurate, -oleate, -heptoate; diethylene glycol mono-oleate; pentaerythritol mono- or di-caprate or laurate; sorbitan monolaurate, sorbitan trioleate and sorbitan mono - stearate polyoxyalkalene derivatives. The polymerization is preferably effected in the presence of a peroxide polymerization catalyst such as orthochlorbenzoyl, caprylyl or benzoyl peroxide, or potassium persulphate. The polymerization mixture may also contain methanol, ethanol, n-butanol, lauryl alcohol, monacetin, glycerol, sodium bicarbonate, sodium hypochlorite or triethanolamine stearate. Plasticizers such as dimethylbenzylether and alpha, alpha1-diphenyl diethyl ether may be incorporated into the polymers and the compositions extruded. Specification 622,481 (as open to inspection under Sect. 91) is referred to.ALSO:Esters of polyhydric alcohols suitable for use as dispersing agents in polymerization reactions are pentaerythritol dicaprate, dilaurate and monolaurate, and the condensation product of ethylene oxide with glycerol monostearate, mono-oleate, monolaurate and diethyleneglycol mono-oleate. Pentaerythritol dicaprate and dilaurate are made by direct esterification under 15 mms. pressure followed by extraction with carbon tetrachloride. Pentaerythritol monolaurate is made by esterification of the theoretical amounts of acid and alcohol in phenol as the solvent and paratoluenesulphonic acid as catalyst. The ethylene oxide condensation products are made by heating the partial ester, ethylene oxide and sodium methoxide in a closed stainless steel tube, to give products which are water-soluble syrups or waxes. Specification 622,481 (as open to inspection under Sect. 91), [Group IV (a)], is referred to.
GB9298/48A 1948-04-02 1948-04-02 Improvements in or relating to the polymerisation of vinyl and vinylidene chlorides Expired GB640120A (en)

Priority Applications (6)

Application Number Priority Date Filing Date Title
GB9298/48A GB640120A (en) 1948-04-02 1948-04-02 Improvements in or relating to the polymerisation of vinyl and vinylidene chlorides
FR983366D FR983366A (en) 1948-04-02 1949-03-21 Improvements to vinyl chloride and vinylidene polymerization processes
DEP38462A DE833856C (en) 1948-04-02 1949-04-01 Process for the polymerization of vinyl and vinylidene chlorides
GB12576/51A GB711355A (en) 1948-04-02 1951-05-29 Improvements in or relating to the polymerisation of vinyl and vinylidene chlorides
FR62856D FR62856E (en) 1948-04-02 1952-05-05 Improvements to vinyl chloride and vinylidene polymerization processes
DED12317A DE948359C (en) 1948-04-02 1952-05-20 Process for polymerizing vinyl and vinylidene chloride

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB9298/48A GB640120A (en) 1948-04-02 1948-04-02 Improvements in or relating to the polymerisation of vinyl and vinylidene chlorides
GB12576/51A GB711355A (en) 1948-04-02 1951-05-29 Improvements in or relating to the polymerisation of vinyl and vinylidene chlorides

Publications (1)

Publication Number Publication Date
GB640120A true GB640120A (en) 1950-07-12

Family

ID=42671630

Family Applications (2)

Application Number Title Priority Date Filing Date
GB9298/48A Expired GB640120A (en) 1948-04-02 1948-04-02 Improvements in or relating to the polymerisation of vinyl and vinylidene chlorides
GB12576/51A Expired GB711355A (en) 1948-04-02 1951-05-29 Improvements in or relating to the polymerisation of vinyl and vinylidene chlorides

Family Applications After (1)

Application Number Title Priority Date Filing Date
GB12576/51A Expired GB711355A (en) 1948-04-02 1951-05-29 Improvements in or relating to the polymerisation of vinyl and vinylidene chlorides

Country Status (3)

Country Link
DE (2) DE833856C (en)
FR (2) FR983366A (en)
GB (2) GB640120A (en)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE912507C (en) * 1952-03-30 1954-05-31 Wacker Cheime G M B H Process for the polymerization of vinyl chloride
DE968141C (en) * 1954-07-25 1958-01-16 Hoechst Ag Process for the production of aqueous dispersions of thermally stable polymers and copolymers of vinyl chloride
DE1077427B (en) * 1956-12-12 1960-03-10 Hoechst Ag Process for the production of stable latexes from polymers or copolymers of vinyl chloride
BE593115A (en) * 1959-07-18
DE1745713B1 (en) * 1960-03-30 1971-12-30 Hoechst Ag PROCESS FOR THE PREPARATION OF MIXED POLYMERIZES OF VINYL CHLORIDE
DE3011645A1 (en) * 1980-03-26 1981-10-01 Henkel KGaA, 4000 Düsseldorf DISPERSING AGENTS FOR THE POLYMERIZATION OF VINYL CHLORIDE AND THEIR USE
JP2743945B2 (en) * 1990-02-16 1998-04-28 信越化学工業株式会社 Method for producing vinyl chloride polymer
EP0563794B1 (en) * 1992-03-30 1996-12-27 Sumitomo Chemical Company Limited Method of producing vinyl chloride resins

Also Published As

Publication number Publication date
FR983366A (en) 1951-06-22
DE833856C (en) 1952-03-13
DE948359C (en) 1956-08-30
FR62856E (en) 1955-06-27
GB711355A (en) 1954-06-30

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