GB638047A - Improvements in or relating to merocyanine dyestuffs - Google Patents
Improvements in or relating to merocyanine dyestuffsInfo
- Publication number
- GB638047A GB638047A GB1505248A GB1505248A GB638047A GB 638047 A GB638047 A GB 638047A GB 1505248 A GB1505248 A GB 1505248A GB 1505248 A GB1505248 A GB 1505248A GB 638047 A GB638047 A GB 638047A
- Authority
- GB
- United Kingdom
- Prior art keywords
- thio
- ketotetrahydrothiazole
- ethyl
- tetramethinemerocyanine
- iodide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- DZVCFNFOPIZQKX-LTHRDKTGSA-M merocyanine Chemical compound [Na+].O=C1N(CCCC)C(=O)N(CCCC)C(=O)C1=C\C=C\C=C/1N(CCCS([O-])(=O)=O)C2=CC=CC=C2O\1 DZVCFNFOPIZQKX-LTHRDKTGSA-M 0.000 title abstract 2
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 abstract 4
- PQNQOHDLTYFBHE-UHFFFAOYSA-N 1-ethyl-2h-quinoline Chemical compound C1=CC=C2N(CC)CC=CC2=C1 PQNQOHDLTYFBHE-UHFFFAOYSA-N 0.000 abstract 3
- -1 6-membered heterocyclic nitrogen nucleus Chemical class 0.000 abstract 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 abstract 2
- 125000000217 alkyl group Chemical group 0.000 abstract 2
- 125000003710 aryl alkyl group Chemical group 0.000 abstract 2
- DXYYSGDWQCSKKO-UHFFFAOYSA-N methylbenzothiazole Natural products C1=CC=C2SC(C)=NC2=C1 DXYYSGDWQCSKKO-UHFFFAOYSA-N 0.000 abstract 2
- IITIZHOBOIBGBW-UHFFFAOYSA-N 3-ethyl-2h-1,3-benzothiazole Chemical compound C1=CC=C2N(CC)CSC2=C1 IITIZHOBOIBGBW-UHFFFAOYSA-N 0.000 abstract 1
- QVPNVWIHUOTMSS-UHFFFAOYSA-N 3-ethyl-2h-1,3-benzoxazole Chemical compound C1=CC=C2N(CC)COC2=C1 QVPNVWIHUOTMSS-UHFFFAOYSA-N 0.000 abstract 1
- 125000002373 5 membered heterocyclic group Chemical group 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 125000005041 acyloxyalkyl group Chemical group 0.000 abstract 1
- 238000009835 boiling Methods 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 239000000975 dye Substances 0.000 abstract 1
- 125000001183 hydrocarbyl group Chemical group 0.000 abstract 1
- 125000002768 hydroxyalkyl group Chemical group 0.000 abstract 1
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 abstract 1
- 229910017464 nitrogen compound Inorganic materials 0.000 abstract 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B23/00—Methine or polymethine dyes, e.g. cyanine dyes
- C09B23/12—Methine or polymethine dyes, e.g. cyanine dyes the polymethine chain being branched "branched" means that the substituent on the polymethine chain forms a new conjugated system, e.g. most trinuclear cyanine dyes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B23/00—Methine or polymethine dyes, e.g. cyanine dyes
- C09B23/10—The polymethine chain containing an even number of >CH- groups
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Nitrogen And Oxygen Or Sulfur-Condensed Heterocyclic Ring Systems (AREA)
- Plural Heterocyclic Compounds (AREA)
Abstract
Trinuclear polymethine merocyanine dyes are prepared by reacting a compound of the general formula <FORM:0638047/IV (c)/1> wherein R1 is an alkyl, hydroxyalkyl, acyloxyalkyl, aralkyl, hydroxyaralkyl, or acyloxyaralkyl group, R2 is H or a hydrocarbon group, R3 is an alkyl or aralkyl group, X is an acid radical, Q is O or S, n is 0 or 1, and D1 is the residue of a 5- or 6-membered heterocyclic nitrogen nucleus, with a heterocyclic nitrogen compound containing a reactive methylene group. [2 - (3 - Ethylbenzthiazole) - 51 - (3-ethyl-2-thio - 4 - ketotetrahydrothiazole) - g .211 - (1-ethylquinoline) - tetramethinemerocyanine] iodide is prepared by boiling 1-ethylthio-2-a -quinolyl-3-(31 - ethyl - 21 - thio - 41 - ketotetrahydrothiazolylidene)-propene ethiodide and 2-methylbenzthiazole ethiodide in pyridine. [2-(3-Ethylbenzthiazole) - 51 - (3 - ethyl - 2 - thio - 4 - ketotetrahydrothiazole) - g .211 - (1 : 3 : 3 - trimethylindolenine) - tetramethinemerocyanine] iodide, [2-(3-ethylbenzthiazole) - 51 - (3 - methyl - 2 - thio - 4 - ketotetrahydrothiazole) - g .211 - (3 - ethylbenzoxazole) - tetramethinemerocyanine] iodide, [2 - (1-ethylquinoline) - 51 - (3 - ethyl - 2 - thio - 4 - ketotetrahydrothiazole) - g .211 - (1 - ethylquinoline)-tetramethinemerocyanine] iodide, and bis - 5-(3-ethyl - 2 - thio - 4 - ketotetrahydrothiazole) - b - 21-(1 - ethyldihydroquinoline) - trimethinemerocyanine are similarly prepared. Specifications 549,202 and 638,021 are referred to.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB1505248A GB638047A (en) | 1947-06-04 | 1947-06-04 | Improvements in or relating to merocyanine dyestuffs |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB1505248A GB638047A (en) | 1947-06-04 | 1947-06-04 | Improvements in or relating to merocyanine dyestuffs |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB638047A true GB638047A (en) | 1950-05-31 |
Family
ID=10052189
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB1505248A Expired GB638047A (en) | 1947-06-04 | 1947-06-04 | Improvements in or relating to merocyanine dyestuffs |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB638047A (en) |
-
1947
- 1947-06-04 GB GB1505248A patent/GB638047A/en not_active Expired
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