GB624438A - Improvements in or relating to the stabilization of rubber - Google Patents

Improvements in or relating to the stabilization of rubber

Info

Publication number
GB624438A
GB624438A GB20137/46A GB2013746A GB624438A GB 624438 A GB624438 A GB 624438A GB 20137/46 A GB20137/46 A GB 20137/46A GB 2013746 A GB2013746 A GB 2013746A GB 624438 A GB624438 A GB 624438A
Authority
GB
United Kingdom
Prior art keywords
rubber
per cent
phenol
thiodiarylamine
monosulphide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB20137/46A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bridgestone Firestone Inc
Original Assignee
Firestone Tire and Rubber Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Firestone Tire and Rubber Co filed Critical Firestone Tire and Rubber Co
Publication of GB624438A publication Critical patent/GB624438A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/36Sulfur-, selenium-, or tellurium-containing compounds
    • C08K5/37Thiols
    • C08K5/375Thiols containing six-membered aromatic rings
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/36Sulfur-, selenium-, or tellurium-containing compounds
    • C08K5/45Heterocyclic compounds having sulfur in the ring
    • C08K5/46Heterocyclic compounds having sulfur in the ring with oxygen or nitrogen in the ring

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

A stabilizer for rubber and rubber-like diolefine polymerised materials, particularly butadienestyrene copolymers, comprises a mixture of a thiodiarylamine and a phenol sulphide, the mixture preferably comprising 1 - 98 per cent by weight thiodiarylamine and 2 - 99 per cent phenol sulphide, and ranging from 0.2 to 10 per cent by weight of the rubber or rubber-like material. The phenol sulphides used include the sulphides of hydrocarbon-substituted compounds such as cresol and xylenol, preferred compounds being the monosulphides containing no more than four phenol groups such as diphenol monosulphide, triphenol di (monosulphide) and tetraphenol tri (monosulphide). The thiodiarylamine which may be a hydrocarbon substituted derivative of thiodiphenylamine or may be thiodinaphthylamine, is preferably thiodiphenylamine in amounts up to 5 per cent of the weight of the rubber or rubber-like material.
GB20137/46A 1945-08-21 1946-07-05 Improvements in or relating to the stabilization of rubber Expired GB624438A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US624438XA 1945-08-21 1945-08-21

Publications (1)

Publication Number Publication Date
GB624438A true GB624438A (en) 1949-06-08

Family

ID=22042523

Family Applications (1)

Application Number Title Priority Date Filing Date
GB20137/46A Expired GB624438A (en) 1945-08-21 1946-07-05 Improvements in or relating to the stabilization of rubber

Country Status (1)

Country Link
GB (1) GB624438A (en)

Similar Documents

Publication Publication Date Title
GB655533A (en) Improvements in or relating to stabilized age-resistant polymer compositions
GB646952A (en) Stabilised mineral oils
US3141860A (en) Flame-resistant polyolefine composition
GB496966A (en) An improved manufacture of stabilised hydrocarbon polymers
GB936760A (en) Process for stabilising polymers of ethylenically unsaturated hydrocarbons; novel substituted monophenols suitable for use therein and process for preparing these
GB836664A (en) Stabilized hydrocarbon polymeric materials
GB624438A (en) Improvements in or relating to the stabilization of rubber
GB832024A (en) Stabilized hydrocarbon polymeric materials
GB757949A (en) Improvements in or relating to petroleum resins containing indene
GB758280A (en) Antioxidant for natural or synthetic rubber
FR2359172A1 (en) FABRIC REINFORCED RUBBER MANUFACTURED ITEMS
US2900362A (en) Substituted xylenols as rubber antioxidants
US3062779A (en) Vulcanized rubber stabilized with zinc bis(benzamidazoyl mercaptide)
US2581906A (en) Antiflex-cracking agents in rubber
US2514661A (en) Crack-resistant vulcanized rubber and method for its production
GB482512A (en) Improvements in the stabilisation of polyvinyl ethers
US3761443A (en) Diels alder adduct flame retardants for polymers
GB751630A (en) Production of vulcanized rubber of improved resistance to cracking and compounds for use therein
GB670526A (en) Improvements in or relating to alkyl lead compounds or compositions which are stabilized against decomposition
NL111731C (en)
GB717863A (en) Improvements relating to rubber antioxidants
GB700463A (en) Improvements in or relating to the treatment of rubber
GB843853A (en) Synergistic mixtures of antioxidants for natural and synthetic rubber
GB607326A (en) Improvements in or relating to the production of benzene hexachloride and of insecticides containing it
GB594093A (en) Improvements in or relating to the production of compositions containing derivativesof balata resin or gutta-percha resin or similar resins and to products covered witha protective coating thereof