GB599472A - Improved method of polymerisation - Google Patents
Improved method of polymerisationInfo
- Publication number
- GB599472A GB599472A GB2407245A GB2407245A GB599472A GB 599472 A GB599472 A GB 599472A GB 2407245 A GB2407245 A GB 2407245A GB 2407245 A GB2407245 A GB 2407245A GB 599472 A GB599472 A GB 599472A
- Authority
- GB
- United Kingdom
- Prior art keywords
- water
- soluble
- salts
- specified
- sulphur
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 150000003839 salts Chemical class 0.000 abstract 7
- 239000011780 sodium chloride Substances 0.000 abstract 7
- 239000005864 Sulphur Substances 0.000 abstract 3
- 239000002253 acid Substances 0.000 abstract 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 abstract 3
- JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 abstract 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 3
- SQGYOTSLMSWVJD-UHFFFAOYSA-N Silver nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 abstract 2
- GEHJYWRUCIMESM-UHFFFAOYSA-L Sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 abstract 2
- 150000002148 esters Chemical class 0.000 abstract 2
- 229910052751 metal Inorganic materials 0.000 abstract 2
- 239000002184 metal Substances 0.000 abstract 2
- JCXJVPUVTGWSNB-UHFFFAOYSA-N nitrogen dioxide Chemical compound O=[N]=O JCXJVPUVTGWSNB-UHFFFAOYSA-N 0.000 abstract 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 2
- LGXVIGDEPROXKC-UHFFFAOYSA-N 1,1-Dichloroethene Chemical compound ClC(Cl)=C LGXVIGDEPROXKC-UHFFFAOYSA-N 0.000 abstract 1
- HQYCOEXWFMFWLR-UHFFFAOYSA-K Vanadium(III) chloride Chemical compound [Cl-].[Cl-].[Cl-].[V+3] HQYCOEXWFMFWLR-UHFFFAOYSA-K 0.000 abstract 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract 1
- 150000001299 aldehydes Chemical class 0.000 abstract 1
- 150000001408 amides Chemical class 0.000 abstract 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 abstract 1
- CURLTUGMZLYLDI-UHFFFAOYSA-N carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 abstract 1
- 239000001569 carbon dioxide Substances 0.000 abstract 1
- 229910002092 carbon dioxide Inorganic materials 0.000 abstract 1
- 229920003086 cellulose ether Polymers 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- HRKQOINLCJTGBK-UHFFFAOYSA-L dioxidosulfate(2-) Chemical compound [O-]S[O-] HRKQOINLCJTGBK-UHFFFAOYSA-L 0.000 abstract 1
- BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 abstract 1
- WBZKQQHYRPRKNJ-UHFFFAOYSA-L disulfite Chemical compound [O-]S(=O)S([O-])(=O)=O WBZKQQHYRPRKNJ-UHFFFAOYSA-L 0.000 abstract 1
- GRWZHXKQBITJKP-UHFFFAOYSA-L dithionite(2-) Chemical compound [O-]S(=O)S([O-])=O GRWZHXKQBITJKP-UHFFFAOYSA-L 0.000 abstract 1
- 150000002191 fatty alcohols Chemical class 0.000 abstract 1
- 150000002238 fumaric acids Chemical class 0.000 abstract 1
- 230000003993 interaction Effects 0.000 abstract 1
- 150000002576 ketones Chemical class 0.000 abstract 1
- 150000002689 maleic acids Chemical class 0.000 abstract 1
- 125000005395 methacrylic acid group Chemical group 0.000 abstract 1
- 150000002825 nitriles Chemical class 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 abstract 1
- 229910052700 potassium Inorganic materials 0.000 abstract 1
- 239000011591 potassium Substances 0.000 abstract 1
- -1 pyrosulphite Chemical compound 0.000 abstract 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 abstract 1
- 230000001603 reducing Effects 0.000 abstract 1
- 229910001961 silver nitrate Inorganic materials 0.000 abstract 1
- 239000000344 soap Substances 0.000 abstract 1
- KEAYESYHFKHZAL-UHFFFAOYSA-N sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 abstract 1
- 229910052708 sodium Inorganic materials 0.000 abstract 1
- 239000011734 sodium Substances 0.000 abstract 1
- VYGBQXDNOUHIBZ-UHFFFAOYSA-L sodium formaldehyde sulphoxylate Chemical compound [Na+].[Na+].O=C.[O-]S[O-] VYGBQXDNOUHIBZ-UHFFFAOYSA-L 0.000 abstract 1
- 235000010265 sodium sulphite Nutrition 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- DHCDFWKWKRSZHF-UHFFFAOYSA-L thiosulfate(2-) Chemical compound [O-]S([S-])(=O)=O DHCDFWKWKRSZHF-UHFFFAOYSA-L 0.000 abstract 1
- HDUMBHAAKGUHAR-UHFFFAOYSA-J titanium(4+);disulfate Chemical class [Ti+4].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O HDUMBHAAKGUHAR-UHFFFAOYSA-J 0.000 abstract 1
- 235000015112 vegetable and seed oil Nutrition 0.000 abstract 1
- 235000019871 vegetable fat Nutrition 0.000 abstract 1
- XTXRWKRVRITETP-UHFFFAOYSA-N vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 abstract 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/28—Oxygen or compounds releasing free oxygen
Abstract
Ethylenic substances are polymerized in aqueous media in the presence of a water-soluble persulphate, a water-soluble salt of an oxy-acid of sulphur with reducing properties and a water-soluble metal salt which increases the speed of interaction between the persulphate and the salt of the oxy-acid of sulphur. Monomers specified are vinyl acetate and chloride, vinylidene chloride, styrene and the esters, amides and nitriles of acrylic, methacrylic, fumaric and maleic acids. Persulphates specified are those of ammonia, potassium and sodium. Salts of oxy-acids of sulphur specified are sodium sulphite, hydrosulphite, sulphoxylate, pyrosulphite, bisulphite, metabisulphite and thiosulphate, and addition compounds of any of these with an aldehyde or ketone, such as sodium formaldehyde sulphoxylate. Specified metal salts are cupric, ferric and titanium sulphates, vanadium chloride and silver nitrate. Salts of the higher state of valency are preferred where such exist. The media may also contain soaps, water-soluble long-chain quaternary ammonium salts, citric acid, disodium hydrogen phosphate, water-soluble esters of the fatty alcohols and salts of sulphonated animal and vegetable fats and oils, and water-soluble cellulose ethers. The polymerization may be carried out in a closed vessel with air or an atmosphere of nitrogen or carbon dioxide present.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH252761D CH252761A (en) | 1945-09-18 | 1946-09-10 | Polymerization process. |
| FR933717D FR933717A (en) | 1945-09-18 | 1946-09-18 | Improved polymerization process |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB599472A true GB599472A (en) | 1948-03-12 |
Family
ID=1738112
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB2407245A Expired GB599472A (en) | 1945-09-18 | 1945-09-18 | Improved method of polymerisation |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB599472A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2683140A (en) * | 1950-12-19 | 1954-07-06 | Du Pont | Polymerization of ethylenically unsaturated compounds with vanadous catalyst |
| DE936358C (en) * | 1949-11-03 | 1955-12-07 | Basf Ag | Process for polymerizing acrylonitrile |
| US2763636A (en) * | 1952-08-25 | 1956-09-18 | Dow Chemical Co | Method of controlling molecular weight of polyacrylonitrile produced in aqueous salt solutions |
| US2813088A (en) * | 1954-09-22 | 1957-11-12 | Wacker Chemie Gmbh | Process for making polymeric nitrogencontaining derivatives of acrylamide or acrylamide and acrylonitrile in a strongly acid aqueous medium |
| US3022266A (en) * | 1954-11-05 | 1962-02-20 | Wacker Chemie Gmbh | Process for the preparation of acrylonitrille copolymers |
-
1945
- 1945-09-18 GB GB2407245A patent/GB599472A/en not_active Expired
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE936358C (en) * | 1949-11-03 | 1955-12-07 | Basf Ag | Process for polymerizing acrylonitrile |
| US2683140A (en) * | 1950-12-19 | 1954-07-06 | Du Pont | Polymerization of ethylenically unsaturated compounds with vanadous catalyst |
| US2763636A (en) * | 1952-08-25 | 1956-09-18 | Dow Chemical Co | Method of controlling molecular weight of polyacrylonitrile produced in aqueous salt solutions |
| US2813088A (en) * | 1954-09-22 | 1957-11-12 | Wacker Chemie Gmbh | Process for making polymeric nitrogencontaining derivatives of acrylamide or acrylamide and acrylonitrile in a strongly acid aqueous medium |
| US3022266A (en) * | 1954-11-05 | 1962-02-20 | Wacker Chemie Gmbh | Process for the preparation of acrylonitrille copolymers |
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