GB576190A - Improvements in or relating to the manufacture of fluorinated derivatives of aliphatic hydrocarbons - Google Patents
Improvements in or relating to the manufacture of fluorinated derivatives of aliphatic hydrocarbonsInfo
- Publication number
- GB576190A GB576190A GB624244A GB624244A GB576190A GB 576190 A GB576190 A GB 576190A GB 624244 A GB624244 A GB 624244A GB 624244 A GB624244 A GB 624244A GB 576190 A GB576190 A GB 576190A
- Authority
- GB
- United Kingdom
- Prior art keywords
- fluoro
- pressure
- cooled
- tetrachloroethane
- aliphatic hydrocarbons
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
- C07C17/20—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms
- C07C17/202—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms two or more compounds being involved in the reaction
- C07C17/206—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms two or more compounds being involved in the reaction the other compound being HX
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Fluorinated derivatives of aliphatic hydrocarbons are prepared by reacting a halogenated derivative of an aliphatic hydrocarbon, containing in the molecule two or more carbon atoms and at least four atoms of halogen other than fluorine of which three are attached to one carbon atom, and containing no other substituents, with substantially anhydrous hydrogen fluoride in the absence of a catalyst and at elevated temperature and pressure. In the examples, asym-tetrachloroethane, pentachloroethane and hexachloropropylene are separately heated with hydrogen fluoride in pressure vessels bearing a water cooled reflux condenser surmounted by a controllable pressure release valve. The vessels are cooled, the pressure released and the contents distilled giving respectively, 1-fluoro-1,1,2,-tri-chloroethane; 1-fluoro-1,1,2,2-tetrachloroethane and in the last case fractions consisting of 1,1,1-trifluoro-2,3,3-trichloropropene-2, 1,1-difluoro-1,2, 3,3-tetrachloropropene-2; and 1-fluoro-1,1,2, 3,3-pentachloropropene-2. Using other reactants, the reflux condenser may be cooled with refrigerated brine. The gaseous products which are obtained are passed through absorbents and then condensed. Specification 466,509 is referred to.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB624244A GB576190A (en) | 1944-04-04 | 1944-04-04 | Improvements in or relating to the manufacture of fluorinated derivatives of aliphatic hydrocarbons |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB624244A GB576190A (en) | 1944-04-04 | 1944-04-04 | Improvements in or relating to the manufacture of fluorinated derivatives of aliphatic hydrocarbons |
Publications (1)
Publication Number | Publication Date |
---|---|
GB576190A true GB576190A (en) | 1946-03-22 |
Family
ID=9810990
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB624244A Expired GB576190A (en) | 1944-04-04 | 1944-04-04 | Improvements in or relating to the manufacture of fluorinated derivatives of aliphatic hydrocarbons |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB576190A (en) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2558703A (en) * | 1948-01-06 | 1951-06-26 | Hooker Electrochemical Co | Preparation of trifluorotrichloropropene |
US2612529A (en) * | 1949-01-12 | 1952-09-30 | Socony Vacuum Oil Co Inc | Higher molecular weight fluorinecontaining compounds |
DE931465C (en) * | 1952-01-16 | 1955-08-08 | Wacker Chemie Gmbh | Process for the production of difluorotrichloroethane |
US3183276A (en) * | 1960-03-16 | 1965-05-11 | Edison Soc | Process for the production of fluorinated organic compounds |
WO2000071496A1 (en) * | 1999-05-21 | 2000-11-30 | Atofina | Method for making 1,1-difluoroethane |
-
1944
- 1944-04-04 GB GB624244A patent/GB576190A/en not_active Expired
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2558703A (en) * | 1948-01-06 | 1951-06-26 | Hooker Electrochemical Co | Preparation of trifluorotrichloropropene |
US2612529A (en) * | 1949-01-12 | 1952-09-30 | Socony Vacuum Oil Co Inc | Higher molecular weight fluorinecontaining compounds |
DE931465C (en) * | 1952-01-16 | 1955-08-08 | Wacker Chemie Gmbh | Process for the production of difluorotrichloroethane |
US3183276A (en) * | 1960-03-16 | 1965-05-11 | Edison Soc | Process for the production of fluorinated organic compounds |
WO2000071496A1 (en) * | 1999-05-21 | 2000-11-30 | Atofina | Method for making 1,1-difluoroethane |
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