GB570880A - Improvements in textile fabrics consisting of or containing cellulose ester fibres - Google Patents
Improvements in textile fabrics consisting of or containing cellulose ester fibresInfo
- Publication number
- GB570880A GB570880A GB15718/43A GB1571843A GB570880A GB 570880 A GB570880 A GB 570880A GB 15718/43 A GB15718/43 A GB 15718/43A GB 1571843 A GB1571843 A GB 1571843A GB 570880 A GB570880 A GB 570880A
- Authority
- GB
- United Kingdom
- Prior art keywords
- acid
- water
- fabric
- amino
- cellulose
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000004744 fabric Substances 0.000 title abstract 8
- 229920002678 cellulose Polymers 0.000 title abstract 5
- 239000004753 textile Substances 0.000 title abstract 2
- 239000000463 material Substances 0.000 abstract 8
- 239000002253 acid Substances 0.000 abstract 5
- 239000000975 dye Substances 0.000 abstract 5
- 239000003795 chemical substances by application Substances 0.000 abstract 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 abstract 3
- AQXYVFBSOOBBQV-UHFFFAOYSA-N 1-amino-4-hydroxyanthracene-9,10-dione Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C(O)=CC=C2N AQXYVFBSOOBBQV-UHFFFAOYSA-N 0.000 abstract 2
- LHYQAEFVHIZFLR-UHFFFAOYSA-L 4-(4-diazonio-3-methoxyphenyl)-2-methoxybenzenediazonium;dichloride Chemical compound [Cl-].[Cl-].C1=C([N+]#N)C(OC)=CC(C=2C=C(OC)C([N+]#N)=CC=2)=C1 LHYQAEFVHIZFLR-UHFFFAOYSA-L 0.000 abstract 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract 2
- 241000416162 Astragalus gummifer Species 0.000 abstract 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 abstract 2
- DMBHHRLKUKUOEG-UHFFFAOYSA-N N-phenyl aniline Natural products C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 abstract 2
- 235000021355 Stearic acid Nutrition 0.000 abstract 2
- 229920001615 Tragacanth Polymers 0.000 abstract 2
- 239000007864 aqueous solution Substances 0.000 abstract 2
- 239000001913 cellulose Substances 0.000 abstract 2
- 229920002301 cellulose acetate Polymers 0.000 abstract 2
- 230000008878 coupling Effects 0.000 abstract 2
- 238000010168 coupling process Methods 0.000 abstract 2
- 238000005859 coupling reaction Methods 0.000 abstract 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 abstract 2
- 239000007788 liquid Substances 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 abstract 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 abstract 2
- 238000007127 saponification reaction Methods 0.000 abstract 2
- 239000000243 solution Substances 0.000 abstract 2
- 239000000126 substance Substances 0.000 abstract 2
- KNXVOGGZOFOROK-UHFFFAOYSA-N trimagnesium;dioxido(oxo)silane;hydroxy-oxido-oxosilane Chemical compound [Mg+2].[Mg+2].[Mg+2].O[Si]([O-])=O.O[Si]([O-])=O.[O-][Si]([O-])=O.[O-][Si]([O-])=O KNXVOGGZOFOROK-UHFFFAOYSA-N 0.000 abstract 2
- 239000001993 wax Substances 0.000 abstract 2
- KEQGZUUPPQEDPF-UHFFFAOYSA-N 1,3-dichloro-5,5-dimethylimidazolidine-2,4-dione Chemical compound CC1(C)N(Cl)C(=O)N(Cl)C1=O KEQGZUUPPQEDPF-UHFFFAOYSA-N 0.000 abstract 1
- 239000005995 Aluminium silicate Substances 0.000 abstract 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 abstract 1
- 229920000742 Cotton Polymers 0.000 abstract 1
- 235000021314 Palmitic acid Nutrition 0.000 abstract 1
- CYTYCFOTNPOANT-UHFFFAOYSA-N Perchloroethylene Chemical group ClC(Cl)=C(Cl)Cl CYTYCFOTNPOANT-UHFFFAOYSA-N 0.000 abstract 1
- 239000012932 acetate dye Substances 0.000 abstract 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 abstract 1
- 235000012211 aluminium silicate Nutrition 0.000 abstract 1
- 229910021529 ammonia Inorganic materials 0.000 abstract 1
- 150000003863 ammonium salts Chemical class 0.000 abstract 1
- 229940088990 ammonium stearate Drugs 0.000 abstract 1
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 abstract 1
- 239000011260 aqueous acid Substances 0.000 abstract 1
- JPNZKPRONVOMLL-UHFFFAOYSA-N azane;octadecanoic acid Chemical compound [NH4+].CCCCCCCCCCCCCCCCCC([O-])=O JPNZKPRONVOMLL-UHFFFAOYSA-N 0.000 abstract 1
- 239000000987 azo dye Substances 0.000 abstract 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 abstract 1
- 150000008280 chlorinated hydrocarbons Chemical class 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 150000008049 diazo compounds Chemical class 0.000 abstract 1
- 235000014113 dietary fatty acids Nutrition 0.000 abstract 1
- 230000000694 effects Effects 0.000 abstract 1
- 150000002148 esters Chemical class 0.000 abstract 1
- 230000008020 evaporation Effects 0.000 abstract 1
- 238000001704 evaporation Methods 0.000 abstract 1
- 239000003925 fat Substances 0.000 abstract 1
- 239000000194 fatty acid Substances 0.000 abstract 1
- 229930195729 fatty acid Natural products 0.000 abstract 1
- 150000004665 fatty acids Chemical class 0.000 abstract 1
- -1 fuller's earth Chemical compound 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 abstract 1
- QTWZICCBKBYHDM-UHFFFAOYSA-N leucomethylene blue Chemical compound C1=C(N(C)C)C=C2SC3=CC(N(C)C)=CC=C3NC2=C1 QTWZICCBKBYHDM-UHFFFAOYSA-N 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 abstract 1
- 239000012188 paraffin wax Substances 0.000 abstract 1
- 239000005871 repellent Substances 0.000 abstract 1
- 230000002940 repellent Effects 0.000 abstract 1
- 235000011121 sodium hydroxide Nutrition 0.000 abstract 1
- NZYOAGBNMCVQIV-UHFFFAOYSA-N sodium;chloro-(4-methylphenyl)sulfonylazanide;trihydrate Chemical compound O.O.O.[Na+].CC1=CC=C(S(=O)(=O)[N-]Cl)C=C1 NZYOAGBNMCVQIV-UHFFFAOYSA-N 0.000 abstract 1
- 239000007787 solid Substances 0.000 abstract 1
- 239000008117 stearic acid Substances 0.000 abstract 1
- 229950011008 tetrachloroethylene Drugs 0.000 abstract 1
- 239000000984 vat dye Substances 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/38—Oxides or hydroxides of elements of Groups 1 or 11 of the Periodic Table
- D06M11/385—Saponification of cellulose-acetate
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/0096—Multicolour dyeing
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/34—Material containing ester groups
- D06P3/40—Cellulose acetate
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/22—Effecting variation of dye affinity on textile material by chemical means that react with the fibre
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Coloring (AREA)
Abstract
Textile fabrics consisting of or containin cellulose ester fibres are saponified substantially on one side only so that they may be dyed to produce fabrics of which the two sides are coloured differently. The saponifying agent, which may be an aqueous solution of an alkali metal hydroxide or carbonate thickened with water-soluble gums such as gum tragacanth, and/or water-insoluble inorganic substances such as french chalk, fuller's earth, and kaolin, is applied to one side of the fabric, and saponification is assisted, if desired, by heating the material. Preferably, a mechanical or chemical resist is previously applied to the side of the material to remain substantially unsaponified. Suitable resists are water-soluble gums, such as gum gatto, fats or waxes, or a solid water-insoluble acid, particularly a higher fatty acid such as stearic or palmitic acid. The acid may be used in conjunction with a water repellent wax such as paraffin wax, and it may be applied to the material as a solution in a volatile liquid such as a chlorinated hydrocarbon and the liquid subsequently removed by evaporation. Alternatively, the acid may be applied as its ammonium salt and the material heated to expel ammonia. The acid resist may be applied to both sides of the fabric. Treating with the resist and/or the saponifying agent may be local. After saponification, the fabric is treated with dilute hydrochloric acid or other aqueous acid to neutralize the saponifying agent, and finally washed. The treated fabric may then be dyed, printed or discharge printed with dyes having widely differing affinities for cellulose and the cellulose ester to produce a coloured effect on one side of the material differing from that on the other. The two types of dyestuffs, e.g. a direct cotton dye and a water-insoluble cellulose acetate dye may be applied together or separately. Alternatively, dyes or dye components may be applied together with the saponifying agent. Vat dyes in leuco form or as sulphuric esters of the leuco compound, e.g. Soledon Jade Green XS or Indigosol O may be applied to and converted on the saponified portion of the material. Enolic coupling components having affinity for cellulose, e.g. arylamides of 2 : 3-hydroxynapthoic acid or other orthohydroxy carboxylic acid or arylamides of aceto-acetic or other b -keto-carboxylic acid may be applied to and developed to azo dyes on the material, and, if desired, diazo compounds may be applied with the coupling component. In the examples, cellulose acetate fabric is padded in an aqueous solution of gum gatto or ammonium stearate or a solution of stearic acid in perchlorethylene and dried. The material is back-filled with a paste of gum tragacanth, caustic soda and french chalk, dried, treated with dilute hydrochloric acid, washed and dyed. The dye bath may contain a mixture of 2 : 4-dinitro-41-amino - diphenylamine, 1 - amino - 4 - hydroxy - anthraquinone, Durazol Fast Yellow B400 and Durazol Fast Blue 4G200 or a mixture of 2 : 4-dinitro - 41-amino - diphenylamine, 1 - amino - 4 - hydroxyanthraquinone, 1 - methylamino - 4 - (b -hydroxyethylamino) - anthraquinone, Durazol Fast Yellow B400, Chlorazol Brown MS and Chlorantine Fast Blue GLL200.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB15718/43A GB570880A (en) | 1943-09-24 | 1943-09-24 | Improvements in textile fabrics consisting of or containing cellulose ester fibres |
| US554149A US2475672A (en) | 1943-09-24 | 1944-09-14 | Process for producing a textile fabric having the two sides thereof in differing colors |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB15718/43A GB570880A (en) | 1943-09-24 | 1943-09-24 | Improvements in textile fabrics consisting of or containing cellulose ester fibres |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB570880A true GB570880A (en) | 1945-07-26 |
Family
ID=10064231
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB15718/43A Expired GB570880A (en) | 1943-09-24 | 1943-09-24 | Improvements in textile fabrics consisting of or containing cellulose ester fibres |
Country Status (2)
| Country | Link |
|---|---|
| US (1) | US2475672A (en) |
| GB (1) | GB570880A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2573705A (en) * | 1947-05-07 | 1951-11-06 | Royal Swan Inc | Method of dyeing only the cellulose acetate ends of a mixed fabric using a dye paste comprising a swelling agent for the cellulose acetate |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3847542A (en) * | 1973-06-01 | 1974-11-12 | Us Agriculture | Process for preparing frosted and multicolored cotton pile fabrics |
| ZA744836B (en) * | 1973-08-16 | 1975-08-27 | Hoechst Ag | Process for obtaining multicolor effects |
| US3934971A (en) * | 1974-06-04 | 1976-01-27 | The United States Of America As Represented By The Secretary Of Agriculture | Process for preparing multicolored cotton pile fabric |
| US3948597A (en) * | 1974-09-23 | 1976-04-06 | Hayashi Chemical Industry Co., Ltd. | Duplex multicolor printed cloth and method for the production of the same |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US646379A (en) * | 1899-03-15 | 1900-03-27 | Giovanni Tagliani | Process of dyeing fabrics. |
| US1266955A (en) * | 1913-11-22 | 1918-05-21 | Vera Chemical Company | Waterproof composition for coating paper. |
| GB346544A (en) * | 1930-03-13 | 1931-04-16 | Calico Printers Ass Ltd | Improvements relating to the decorative treatment of textile fabrics |
| US2020698A (en) * | 1933-10-24 | 1935-11-12 | Celanese Corp | Pile fabric and method of treating the same |
| US2068770A (en) * | 1934-11-14 | 1937-01-26 | Alfred M Schwarzschild | Printed textile fabric |
| GB463955A (en) * | 1935-10-05 | 1937-04-05 | British Celanese | Improvements in the treatment of cellulose ester threads, ribbons, films, fabrics and like materials |
| US2248048A (en) * | 1937-04-24 | 1941-07-08 | Celanese Corp | Thickener for decorating textiles of organic derivatives of cellulose |
-
1943
- 1943-09-24 GB GB15718/43A patent/GB570880A/en not_active Expired
-
1944
- 1944-09-14 US US554149A patent/US2475672A/en not_active Expired - Lifetime
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2573705A (en) * | 1947-05-07 | 1951-11-06 | Royal Swan Inc | Method of dyeing only the cellulose acetate ends of a mixed fabric using a dye paste comprising a swelling agent for the cellulose acetate |
Also Published As
| Publication number | Publication date |
|---|---|
| US2475672A (en) | 1949-07-12 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| GB570880A (en) | Improvements in textile fabrics consisting of or containing cellulose ester fibres | |
| US3042540A (en) | Water dispersible pigments and the production thereof | |
| DE2557554A1 (en) | METHOD OF PRINTING WITH DEVELOPMENT DYES | |
| DE1619662A1 (en) | Process for the production of prints on fiber material | |
| DE659493C (en) | Process for dyeing animal fibers or mixtures of animal fibers with natural and artificial cellulose fibers with non-indigoid dyes | |
| DE448909C (en) | Process for the production of dyes or colored bases | |
| DE728464C (en) | Process for upgrading cellulose or fiber mixtures containing cellulose | |
| DE738145C (en) | Process for increasing the colorability of fiber materials made of glass with basic dyes | |
| DE900325C (en) | Process for dyeing non-cellulose fibers with Kuepen dyes | |
| AT164006B (en) | Process for the etching of copper-containing colorations of substantive azo dyes | |
| US2192958A (en) | Coloration of textile materials | |
| US2445632A (en) | Indigosol composition comprising a naphthol sulfonate and method of applying same | |
| US2204932A (en) | Process for producing dyeings | |
| GB354300A (en) | Improvements in preparations for use in the treatment of textile materials with aqueous liquids | |
| CH288384A (en) | Resistant, water-soluble dye preparation. | |
| DE637872C (en) | Process for the local alteration of the color properties of textiles made of natural cellulose of any origin and pretreatment | |
| DE727698C (en) | Process for the production of azo dyes | |
| AT126753B (en) | Method for reserving vat colorations, particularly the indanthrene vat. | |
| DE679768C (en) | Process for the production of ice colors using the printing or padding process | |
| JPH03294576A (en) | Decolorant for pigment-colored textile and decolorization using the same | |
| GB454869A (en) | Dyeing and printing of textile materials and dye-preparations therefor | |
| GB457283A (en) | Improvements in or relating to the colouration of textile materials containing cellulose esters | |
| GB636501A (en) | Improvements in colouring textile materials | |
| GB641835A (en) | Improvements in the colouration of cellulose ester or ether textile materials | |
| GB403621A (en) | Colouration of textile materials |