GB563885A - Improvements in the hydration of olefines - Google Patents
Improvements in the hydration of olefinesInfo
- Publication number
- GB563885A GB563885A GB1213940A GB1213940A GB563885A GB 563885 A GB563885 A GB 563885A GB 1213940 A GB1213940 A GB 1213940A GB 1213940 A GB1213940 A GB 1213940A GB 563885 A GB563885 A GB 563885A
- Authority
- GB
- United Kingdom
- Prior art keywords
- ethylene
- propylene
- absorption
- acid
- liquor
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/03—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by addition of hydroxy groups to unsaturated carbon-to-carbon bonds, e.g. with the aid of H2O2
- C07C29/04—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by addition of hydroxy groups to unsaturated carbon-to-carbon bonds, e.g. with the aid of H2O2 by hydration of carbon-to-carbon double bonds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
The hydration of ethylene and propylene is effected by absorbing ethylene substantially free from higher olefines in a highly concentrated acid, such as sulphuric or phosphoric acid, diluting the absorption liquor, absorbing propylene in the diluted liquor and finally recovering the oxygen - containing products. The absorption may be facilitated by the addition of a catalyst, such as silver or silver and copper compounds, and the absorption of ethylene is preferably stopped when about 0.8 molecule of ethylene per molecule of acid has been absorbed, and, using sulphuric acid of 92-98 per cent, water may be added equal to 7-10 per cent of the liquor for the absorption of propylene. The ethylene for the first treatment may be obtained from cracking gases by washing with liquid hydrocarbon to remove higher olefines, and the gas recovered from the liquid hydrocarbon may be used as the source of propylene, residual gas being used as ethylene.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB1213940A GB563885A (en) | 1940-07-25 | 1940-07-25 | Improvements in the hydration of olefines |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB1213940A GB563885A (en) | 1940-07-25 | 1940-07-25 | Improvements in the hydration of olefines |
Publications (1)
Publication Number | Publication Date |
---|---|
GB563885A true GB563885A (en) | 1944-09-04 |
Family
ID=9999052
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB1213940A Expired GB563885A (en) | 1940-07-25 | 1940-07-25 | Improvements in the hydration of olefines |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB563885A (en) |
-
1940
- 1940-07-25 GB GB1213940A patent/GB563885A/en not_active Expired
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