GB559711A - Improvements in and relating to the production of substituted amines - Google Patents

Improvements in and relating to the production of substituted amines

Info

Publication number
GB559711A
GB559711A GB10354/42A GB1035442A GB559711A GB 559711 A GB559711 A GB 559711A GB 10354/42 A GB10354/42 A GB 10354/42A GB 1035442 A GB1035442 A GB 1035442A GB 559711 A GB559711 A GB 559711A
Authority
GB
United Kingdom
Prior art keywords
amine
urea
carbamidomethyl
dimethylaminomethyl
dimethyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB10354/42A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
EIDP Inc
Original Assignee
EI Du Pont de Nemours and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by EI Du Pont de Nemours and Co filed Critical EI Du Pont de Nemours and Co
Priority to GB10354/42A priority Critical patent/GB559711A/en
Publication of GB559711A publication Critical patent/GB559711A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C273/00—Preparation of urea or its derivatives, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups
    • C07C273/18—Preparation of urea or its derivatives, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups of substituted ureas
    • C07C273/1854—Preparation of urea or its derivatives, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups of substituted ureas by reactions not involving the formation of the N-C(O)-N- moiety
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/21—Urea; Derivatives thereof, e.g. biuret

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

559,711. Substituted amines. DU PONT DE NEMOURS & CO., E. I., and BURKE, W. J. July 24, 1942, No. 10354. [Class 2 (iii)] [Also in Group VI] Tertiary N-(monocarbamidomethyl) amines which are suitable for use as pesticides, drugs, textile modifying agents, stabilizers for halogenated resins, and as mould inhibitors in food products, and having the formula R<SP>1</SP> (NR<SP>2</SP>-CHR<SP>3</SP>-NR<SP>4</SP>-CON-#R<SP>5)</SP> R6) m, where R1NR2- is the non-proton portion of a secondary amine, R<SP>3</SP>CH- is the non-oxo portion of an aldehyde, R<SP>4</SP>, R<SP>5</SP>, and R<SP>6</SP> are hydrogen or monovalent hydrocarbon radicals, R<SP>1</SP>, R<SP>2</SP>, and R<SP>3</SP> are hydrocarbon radicals, which may have phenyl, hydroxy, dialkylamino, aromatic nitro, or alkoxy groups, and R<SP>1</SP> and R<SP>2</SP> may contain a thioether sulphur, m is 1 or 2, are prepared by reaction in any order of a secondary amine free from primary and tertiary amino groups, an aldehyde and an acyclic urea having at least one H attached to a urea N. Examples give the preparation of morpholinomethylurea from morpholine, formaldehyde and urea, 1, 3-dimethyl-1-(dimethylaminomethyl) urea, 1, 1-diethyl-3-butyl-3-(dimethylaminomethyl)urea 1-butyl-3-(dimethylaminomethyl) urea, 1-butyl- 1 - (dimethylaminomethyl) urea, 1 - methyl -3 - ethyl - 3 - (dimethylaminomethyl) urea, 1 - ethyl - 3 - methyl - 3 - (dimethylaminomethyl) urea, 1 - (carbamidomethyl) piperidine, di - # - hydroxyethyl (carbamidomethyl) amine, methylbutyl (carbamidomethyl) amine, methylphenyl (carbamidomethyl) amine, diphenyl (carbamidomethyl) amine, methylbenzyl (carbamidomethyl) amine, NN<SP>1</SP>-dimethyl-NN<SP>1</SP>-bis (carbamidomethyl) ethylenediamine, 1, 4-bis (carbamidomethyl) piperazine, dimethyl (1- carbamidoethyl) amine, dimethyl-(α-carbamidobenzyl) amine, dimethyl (1-carbamido-2-phenylethyl) amine, dimethyl (1-carbamidopenten- 4-yl-1) amine, N N N<SP>1</SP> N<SP>1</SP>-tetramethyl-1, 6- dicarbamido-1, 6-hexanediamine.
GB10354/42A 1942-07-24 1942-07-24 Improvements in and relating to the production of substituted amines Expired GB559711A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB10354/42A GB559711A (en) 1942-07-24 1942-07-24 Improvements in and relating to the production of substituted amines

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB10354/42A GB559711A (en) 1942-07-24 1942-07-24 Improvements in and relating to the production of substituted amines

Publications (1)

Publication Number Publication Date
GB559711A true GB559711A (en) 1944-03-02

Family

ID=9966299

Family Applications (1)

Application Number Title Priority Date Filing Date
GB10354/42A Expired GB559711A (en) 1942-07-24 1942-07-24 Improvements in and relating to the production of substituted amines

Country Status (1)

Country Link
GB (1) GB559711A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3061641A (en) * 1960-05-04 1962-10-30 American Cyanamid Co Anilinoalkyl-ureas
US4348536A (en) 1975-05-28 1982-09-07 Bayer Aktiengesellschaft Odorless catalysts for the synthesis of polyurethanes

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3061641A (en) * 1960-05-04 1962-10-30 American Cyanamid Co Anilinoalkyl-ureas
US4348536A (en) 1975-05-28 1982-09-07 Bayer Aktiengesellschaft Odorless catalysts for the synthesis of polyurethanes

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