GB490211A - Method of converting aliphatic polyhydric alcohols to alcohols of lower molecular weight - Google Patents
Method of converting aliphatic polyhydric alcohols to alcohols of lower molecular weightInfo
- Publication number
- GB490211A GB490211A GB3458/37A GB345837A GB490211A GB 490211 A GB490211 A GB 490211A GB 3458/37 A GB3458/37 A GB 3458/37A GB 345837 A GB345837 A GB 345837A GB 490211 A GB490211 A GB 490211A
- Authority
- GB
- United Kingdom
- Prior art keywords
- hydrogen
- alcohols
- moles
- sucrose
- dextrose
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/09—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis
- C07C29/10—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis of ethers, including cyclic ethers, e.g. oxiranes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Aliphatic polyhydric alcohols containing three or more carbon atoms and three or more hydroxyl groups are converted to alcohols of fewer carbon atoms by catalytic hydrogenation in the presence of an initially added substantially anhydrous mono- or di-hydric aliphatic alcohol containing less than five carbon atoms as vehicle at a pressure not above 3000 lb./sq. in. and at a temperature above 150 DEG C. The initial alcohols include sucrose, dextrose, maltose, lactose, levulose, pentosans, starches, dextrins, cellulose, sorbitol, mannitol, and crude sugars or hydrolysis products of starch or cellulose. The products may be used as anti-freeze agents. The amount of hydrogen is controlled in accordance with the product desired. The best yield of anti-freeze is obtained with absorption of not more than 5 1/2 moles of hydrogen per mole of sucrose or 2,75 moles per mole of dextrose. Substantially less hydrogen results in unreacted sugar and sorbitol. More hydrogen gives large amounts of ethyl alcohol. In an example, sucrose mixed with methanol, and a copper-chromium-barium catalyst is treated with hydrogen at 250 DEG C. and 2000 lb./sq. in. or less until 5,1 moles have been introduced per mole of sucrose. The proportion of the product boiling above 125 DEG C., mainly propylene glycol and glycerine, is used as an anti-freeze. The portion volatile below 125 DEG C containing the original methanol and lower alcohols formed in the reaction may be used again as the vehicle in a further reaction. In another example dextrose is treated until 2,3 moles of hydrogen are absorbed. Reference has been directed by the Comptroller to Specification 430,576.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US490211XA | 1936-02-07 | 1936-02-07 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB490211A true GB490211A (en) | 1938-08-05 |
Family
ID=21957660
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB3458/37A Expired GB490211A (en) | 1936-02-07 | 1937-02-05 | Method of converting aliphatic polyhydric alcohols to alcohols of lower molecular weight |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB490211A (en) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4642394A (en) * | 1985-07-16 | 1987-02-10 | Celanese Corporation | Production of propanediols |
WO2005095536A3 (en) * | 2004-03-25 | 2006-03-16 | Galen J Suppes | Method of producing lower alcohols from glycerol |
US7663004B2 (en) | 2002-04-22 | 2010-02-16 | The Curators Of The University Of Missouri | Method of producing lower alcohols from glycerol |
US8017816B2 (en) | 2002-04-22 | 2011-09-13 | The Curators Of The University Of Missouri | Method of producing lower alcohols from glycerol |
US8252961B2 (en) | 2002-04-22 | 2012-08-28 | The Curators Of The University Of Missouri | Method of producing lower alcohols from glycerol |
-
1937
- 1937-02-05 GB GB3458/37A patent/GB490211A/en not_active Expired
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4642394A (en) * | 1985-07-16 | 1987-02-10 | Celanese Corporation | Production of propanediols |
US7663004B2 (en) | 2002-04-22 | 2010-02-16 | The Curators Of The University Of Missouri | Method of producing lower alcohols from glycerol |
US7816567B2 (en) | 2002-04-22 | 2010-10-19 | The Curators Of The University Of Missouri | Method of producing lower alcohols from glycerol |
US7943805B2 (en) | 2002-04-22 | 2011-05-17 | The Curators Of The University Of Missouri | Method of producing lower alcohols from glycerol |
US8017816B2 (en) | 2002-04-22 | 2011-09-13 | The Curators Of The University Of Missouri | Method of producing lower alcohols from glycerol |
US8252961B2 (en) | 2002-04-22 | 2012-08-28 | The Curators Of The University Of Missouri | Method of producing lower alcohols from glycerol |
US8563783B2 (en) | 2002-04-22 | 2013-10-22 | The Curators Of The University Of Missouri | Method of producing lower alcohols from glycerol |
US9404027B2 (en) | 2002-04-22 | 2016-08-02 | The Curators Of The University Of Missouri | Method of producing lower alcohols from glycerol |
WO2005095536A3 (en) * | 2004-03-25 | 2006-03-16 | Galen J Suppes | Method of producing lower alcohols from glycerol |
EP2298721A3 (en) * | 2004-03-25 | 2011-07-27 | Galen J. Suppes | Process for producing an antifreeze composition containing lower alcohols and glycerol via alcoholysis of a glyceride |
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