GB489940A - Process for modifying the affinity of artificial fibrous and film-like materials - Google Patents

Process for modifying the affinity of artificial fibrous and film-like materials

Info

Publication number
GB489940A
GB489940A GB3049/37A GB304937A GB489940A GB 489940 A GB489940 A GB 489940A GB 3049/37 A GB3049/37 A GB 3049/37A GB 304937 A GB304937 A GB 304937A GB 489940 A GB489940 A GB 489940A
Authority
GB
United Kingdom
Prior art keywords
treated
epichlorhydrin
basic
hours
acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3049/37A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ACETA GmbH
Original Assignee
ACETA GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ACETA GmbH filed Critical ACETA GmbH
Publication of GB489940A publication Critical patent/GB489940A/en
Expired legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
    • D06P1/642—Compounds containing nitrogen
    • D06P1/6429—Compounds containing nitrogen bound to a six-membered aromatic carbocyclic ring
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/11—Compounds containing epoxy groups or precursors thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
    • D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
    • D06M13/252—Mercaptans, thiophenols, sulfides or polysulfides, e.g. mercapto acetic acid; Sulfonium compounds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/325—Amines
    • D06M13/328—Amines the amino group being bound to an acyclic or cycloaliphatic carbon atom
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
    • D06P1/651—Compounds without nitrogen
    • D06P1/65106—Oxygen-containing compounds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
    • D06P1/651—Compounds without nitrogen
    • D06P1/65168—Sulfur-containing compounds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/22—Effecting variation of dye affinity on textile material by chemical means that react with the fibre
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/22—Effecting variation of dye affinity on textile material by chemical means that react with the fibre
    • D06P5/225—Aminalization of cellulose; introducing aminogroups into cellulose

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

The affinity for acid or basic substances, especially dyestuffs, of artificial fibres, threads, films and the like consisting of or containing highly polymerized organic substances, free from protein but containing basic groups forming a part of such substances or of other components not removable by rinsing with water, is modified by treating the undyed material, in the absence of other alkylating agents or of dyestuffs, with a compound containing an alkylene oxide, sulphide or imine heterocyclic ring and reacting with splitting of the ring. Specified materials treated are (a) cellulose derivatives carrying basic residues in an ester or ether group, e.g. the reaction products of cellulose with halogen alkylamines, halogen oyxalkylamines, ethyleneimine or its derivatives or substituted aminopropenoxides, (b) polymerizates carrying basic groups, e.g. reaction products of a polyvinyl alcoholate with a halogen alkylamine or of polyacrylic acid methyl ester with an aliphatic polyamine such as b -diethylaminoethylamine, (c) basic aldehyde resins, e.g. those from halogenmethylarylsulphamides and formaldehyde (cf. Specification 455,602), (d) basic phenol-formaldehyde resins, (e) basic alkyd resins. Specified reagents containing an alkylene oxide, sulphide or imine heterocyclic ring are, in addition to those used in the examples below, 1 : 2-propylene oxide, 1 : 2-butylene oxide, 1 : 2-cyclohexylene oxide, phenoxypropenoxide, 3-dichloro-1 : 2-propylene oxide, ethylene imine, N-butylethylene imine, N - diethylethyleneiminium chloride, N-pentamethyleneethyleneiminium chloride and the biquaternary spirocyclic compound from di-g -chloro - b - hydroxypropylpiperazine (addition product from 1 mol. piperazine and 2 mols. epichlorhydrin). The reaction may be accelerated by catalytically acting substances, e.g. sodium or calcium chloride, tetramethylammonium chloride, dodecyltrimethylammonium chloride, bases, substances containing acid groups or acid-reacting salts. Such catalysts may be applied locally to the materials to obtain pattern effects in subsequent dyeing. In examples, (1) acetate artificial silk containing the basic resin from polyacrylic acid ethyl ester (1 mol.) and b -diethylaminoethylamine (1 mol.) (cf. Specification 450,692) is rinsed with dilute acetic acid, dried and treated for 15 hours with a moist atmosphere at 80 DEG C. containing epichlorhydrin vapour; (2) a viscose fabric, treated as described in Specification 465,105 with piperidopropenoxide and then washed successively with dilute hydrochloric acid and water, is treated for 14 hours with 1 : 2-propylene sulphide or butadiene dioxide at 70 DEG C.; (3) acetate artificial silk containing the basic resin obtainable by heating dimethylaminomethanol in alcohol with a novolak from phenol (10 mols.) and formaldehyde (7 mols.) is treated for 12 hours with a moist atmosphere at 80 DEG C. containing epichlorhydrin and ethylene oxide; (4) threads of acetylated diethylaminoethylcellulose are washed successively with dilute hydrochloric or thiocyanic acid and water and treated for 15 hours with epichlorhydrin or 1-chloro-2 : 3-propylene sulphide at 80 DEG C.; (5) copper artificial silk, pre-treated with ethylene imine (cf. Specification 460,590), is impregnated with a solution of 3 - cyclohexyliminodipropenoxide - 1 : 2 or of its methyl iodide or dimethyl sulphate addition product or of 2 : 3 : 5 : 6-tetramethylpiperazinodipropenoxide and heated at 90 DEG C.; simultaneously or finally the material may be caused to react with an alkylene oxide free from nitrogen; (6) viscose artificial silk, pre-treated with ethylene imine, is immersed in dilute hydrochloric acid, washed with water and treated for 16 hours with a moist atmosphere at 80 DEG C., containing epichlorhydrin; (7) a viscose fabric, pre-treated with 3-diethylamino - 1 : 2 - propenoxide, is treated for 16 hours in presence of formaldehyde or glyoxal, and preferably of urea or a like resinformer, with a moist atmosphere at 90 DEG C. containing epichlorhydrin. Specifications 463,043, 467,173, 469,457, 472,630, and 472,899 also are referred to. 3 - Cyclohexyliminodipropenoxide - 1 : 2 is obtained by reaction of cyclohexylamine (1 mol.) with epichlorhydrin (2 mols.). 2 : 3 : 5 : 6 - Tetramethylpiperazinodipropenoxide is obtained by reaction of 2 : 3 : 5 : 6-tetramethylpiperazino (1 mol.) with epichlorhydrin (2 mols.). 1 - Chloro - 2 : 3 - propylene sulphide is obtained by reaction of potassium thiocyanate or thiourea on epichlorhydrin.
GB3049/37A 1936-02-11 1937-02-02 Process for modifying the affinity of artificial fibrous and film-like materials Expired GB489940A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE489940X 1936-02-11

Publications (1)

Publication Number Publication Date
GB489940A true GB489940A (en) 1938-08-02

Family

ID=6544031

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3049/37A Expired GB489940A (en) 1936-02-11 1937-02-02 Process for modifying the affinity of artificial fibrous and film-like materials

Country Status (2)

Country Link
FR (1) FR817357A (en)
GB (1) GB489940A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2536893A (en) * 1948-04-22 1951-01-02 Alginate Ind Ltd Production of alkali-resistant alginate materials
US3506391A (en) * 1962-02-15 1970-04-14 Deering Milliken Res Corp Cross-linking cellulosics with epichlorohydrin vapors
GB2195665A (en) * 1986-08-19 1988-04-13 Nat Res Dev Dyeable cellulosic fibrous materials

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2219280A (en) * 1938-05-31 1940-10-29 Soc Of Chemical Ind Dyestuffs and process of making same

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2536893A (en) * 1948-04-22 1951-01-02 Alginate Ind Ltd Production of alkali-resistant alginate materials
US3506391A (en) * 1962-02-15 1970-04-14 Deering Milliken Res Corp Cross-linking cellulosics with epichlorohydrin vapors
GB2195665A (en) * 1986-08-19 1988-04-13 Nat Res Dev Dyeable cellulosic fibrous materials

Also Published As

Publication number Publication date
FR817357A (en) 1937-09-01

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