GB456082A - Improvements in or relating to the electrolytic deposition of lead peroxide - Google Patents

Improvements in or relating to the electrolytic deposition of lead peroxide

Info

Publication number
GB456082A
GB456082A GB30244/35A GB3024435A GB456082A GB 456082 A GB456082 A GB 456082A GB 30244/35 A GB30244/35 A GB 30244/35A GB 3024435 A GB3024435 A GB 3024435A GB 456082 A GB456082 A GB 456082A
Authority
GB
United Kingdom
Prior art keywords
anode
peroxide
thickness
lead
lead peroxide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB30244/35A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Publication of GB456082A publication Critical patent/GB456082A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D9/00Electrolytic coating other than with metals
    • C25D9/04Electrolytic coating other than with metals with inorganic materials
    • C25D9/06Electrolytic coating other than with metals with inorganic materials by anodic processes
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/04Electrodes; Manufacture thereof not otherwise provided for characterised by the material
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/04Electrodes; Manufacture thereof not otherwise provided for characterised by the material
    • C25B11/051Electrodes formed of electrocatalysts on a substrate or carrier
    • C25B11/054Electrodes comprising electrocatalysts supported on a carrier

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)

Abstract

456,082. Electrolytic deposition of lead peroxide. KATO, Y., 1220, Togoshimachi, Ebara-ku, Tokio. Nov. 1, 1935, Nos. 30244 and 30245. Convention dates, Dec. 20, 1934 and April 4, 1935. [Class 41] A compact and adherent layer of lead peroxide is deposited on the concave surface of a base body connected as anode. In order that the base may be of sufficient strength to resist expansion forces called into play during deposition the product of its thickness in millimeters and the tensile strength of the material in kilograms per square millimeter should be greater than 1. Alternatively the base may be wound with wires or otherwise reinforced. In an example deposition is effected on the inside of a hollow cylindrical nickel or nickelplated anode of internal diameter 3 dcm. and thickness 0À25 dcm., with a carbon cathode disposed within the anode. The electrolyte consists of 18 kgms. of lead nitrate dissolved in 40 litres of water with the addition of 20 gms. of a hydrophile colloid such as gelatine or glue. A layer of peroxide 2 mm. in thickness may be deposited. The coated bases may be used as anodes in the electrolytic production of chlorine and hypochlorites from brine, and of perchlorates from chlorates. In an example a 40 per cent solution of sodium chlorate containing 1 per cent of sodium bichromate is electrolyzed at 20‹ C., with an anode having a lead peroxide layer and a cathode of iron. The sodium bichromate may be omitted if a chromium plated cathode is employed.
GB30244/35A 1934-12-20 1935-11-01 Improvements in or relating to the electrolytic deposition of lead peroxide Expired GB456082A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP456082X 1934-12-20

Publications (1)

Publication Number Publication Date
GB456082A true GB456082A (en) 1936-11-03

Family

ID=12724061

Family Applications (1)

Application Number Title Priority Date Filing Date
GB30244/35A Expired GB456082A (en) 1934-12-20 1935-11-01 Improvements in or relating to the electrolytic deposition of lead peroxide

Country Status (1)

Country Link
GB (1) GB456082A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2492206A (en) * 1943-01-19 1949-12-27 Joseph C White Lead perchloric acid primary cell
US2945791A (en) * 1958-03-05 1960-07-19 Jr Fred D Gibson Inert lead dioxide anode and process of production
US2945790A (en) * 1955-12-14 1960-07-19 Pennsalt Chemicals Corp Method of electroplating lead dioxide

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2492206A (en) * 1943-01-19 1949-12-27 Joseph C White Lead perchloric acid primary cell
US2945790A (en) * 1955-12-14 1960-07-19 Pennsalt Chemicals Corp Method of electroplating lead dioxide
US2945791A (en) * 1958-03-05 1960-07-19 Jr Fred D Gibson Inert lead dioxide anode and process of production
DE1182211B (en) * 1958-03-05 1964-11-26 Fred D Gibson Jun Process for the electrolytic deposition of a lead dioxide coating on a graphite anode

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